US3974104A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Denture bases of X-ray opaque polymers
Assignee: Amalgamated Dental Co Ltd
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Filing: 1973-03-14
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Granted: 1976-08-10
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Expires: 1993-03-14
Abstract
Abstract A radio opaque denture base formed of a copolymer of an ethylenically unsaturated monomer containing chemically bound tin together with at least one ethylenically unsaturated monomer, the ethylenically unsaturated monomer containing chemically bound tin being an ester of trialkyl tin and an ethylenically unsaturated acid such as tributyl tin ethacrylate. In a preferred embodiment the copolymer is a novel copolymer derived from two ethylenically unsaturated tin containing monomers one of which is trimethyl tin methacrylate and the other is a trialkyl tin methacrylate other than trimethyl tin methacrylate. In another preferred embodiment the copolymer is a novel copolymer derived from an ester of trialkyl tin and an ethylenically unsaturated carboxylic acid together with two or more other ethylenically unsaturated monomers, one of which is a long chain alkyl acrylate or methacrylate and another of which is a lower alkyl acrylate or methacrylate.
Inventors
- 👤 John Foster
- 👤 Vallabhbhai Bhanabhai Ahir
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 05:05
CPC Classifications
A; A61; A61K; A61K6/00; A61K6/80; A61K6/884; A61K6/887; Y; Y10; Y10S; Y10S528/00; Y10S528/92
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
68 words
A denture base formed of a copolymer of an ethylenically unsaturated monomer containing chemically bound tin together with at least one ethylenically unsaturated monomer which does not contain tin, the ethylenically unsaturated monomer containing chemically bound tin being an ester of trialkyl tin and an ethylenically unsaturated acid and the non-tin containing monomer comprising a major proportion by weight of a lower alkyl acrylate or lower alkyl methacrylate.
Claim 2
Dependent Claim
68 words
A denture base formed of a copolymer of an ethylenically unsaturated monomer containing chemically bound tin together with at least one ethylenically unsaturated monomer which does not contain tin, the ethylenically unsaturated monomer containing chemically bound tin being an ester of trialkyl tin and an ethylenically unsaturated acid and the non-tin containing monomer comprising a major proportion by weight of a lower alkyl acrylate or lower alkyl methacrylate.
Claim 3
Dependent Claim
19 words
A denture base according to claim 1 in which the ethylenically unsaturated acid is acrylic acid or methacrylic acid.
Claim 4
Dependent Claim
50 words
A denture base according to claim 2 in which the ethylenically unsaturated monomer containing chemically bound tin has the formula: CH.sub.2 = C(R.sup.1) -- COOSn(R).sub.3 in which R is a lower alkyl group containing from 1 to 6 carbon atoms and R 1 is a hydrogen atom or methyl group.
Claim 5
Dependent Claim
21 words
A denture base according to claim 1 in which the ethylenically unsaturated monomer containing chemically bound tin is tributyl tin methacrylate.
Claim 6
Dependent Claim
36 words
A denture base according to claim 1 in which the copolymer is derived from two different ethylenically unsaturated tin-containing monomers one of which is trimethyl tin methacrylate and the other is a second trialkyl tin methacrylate.
Claim 7
Dependent Claim
25 words
A denture base according to claim 5 in which the trimethyl tin methacrylate forms from 30 to 45 percent by weight of the tin-containing monomers.
Claim 8
Dependent Claim
21 words
A denture base according to claim 1 in which the copolymer contains from 2.5 to 10 percent by weight of tin.
Claim 9
Dependent Claim
25 words
A denture base according to claim 1 in which the non-tin containing monomers comprise a minor proportion by weight of a polyethylenically unsaturated cross-linking monomer.
Claim 10
Dependent Claim
23 words
A denture base according to claim 1 in which the copolymer includes the moiety of a long chain alkyl acrylate or methacrylate monomer.
Claim 11
Dependent Claim
57 words
A denture base according to claim 1 in which the copolymer includes the moiety of an ester of trialkyl tin and an ethylenically unsaturated carboxylic acid together with two or more other ethylenically unsaturated monomers, one of which is a long chain alkyl acrylate or methacrylate and another of which is a lower alkyl acrylate or methacrylate.
Claim 12
Dependent Claim
20 words
A denture base according to claim 10 in which the long chain acrylate contains from 8 to 20 carbon atoms.
Claim 13
Dependent Claim
33 words
A denture base according to claim 10 in which the copolymer includes the moieties of a mixture containing from 5 to 15 percent by weight of the long chain alkyl acrylate or methacrylate.
Claim 14
Dependent Claim
104 words
A process for preparing a denture base which comprises mixing a finely divided tin-containing copolymer which is a copolymer of an ethylenically unsaturated monomer containing chemically bound tin, said monomer containing chemically bound tin being an ester of trialkyl tin and an ethylenically unsaturated acid and at least one other ethylenically unsaturated non-tin containing monomer; said non-tin containing monomer comprising a major proportion by weight of a lower alkyl acrylate or lower alkyl methacrylate, with one or more liquid alkyl acrylate or methacrylates to form a dough, placing the resultant dough into a dental flask and then curing the dough in the dental flask.
Claim 15
Dependent Claim
104 words
A process for preparing a denture base which comprises mixing a finely divided tin-containing copolymer which is a copolymer of an ethylenically unsaturated monomer containing chemically bound tin, said monomer containing chemically bound tin being an ester of trialkyl tin and an ethylenically unsaturated acid and at least one other ethylenically unsaturated non-tin containing monomer; said non-tin containing monomer comprising a major proportion by weight of a lower alkyl acrylate or lower alkyl methacrylate, with one or more liquid alkyl acrylate or methacrylates to form a dough, placing the resultant dough into a dental flask and then curing the dough in the dental flask.
Claim 16
Dependent Claim
33 words
A tin-containing polymer which is a copolymer of trimethyl tin methacrylate, a trialkyl tin methacrylate having more than one carbon atom in the alkyl group, and at least one other ethylenically unsaturated monomer.
Claim 17
Dependent Claim
33 words
A tin-containing polymer which is a copolymer of trimethyl tin methacrylate, a trialkyl tin methacrylate having more than one carbon atom in the alkyl group, and at least one other ethylenically unsaturated monomer.
Claim 18
Dependent Claim
49 words
A copolymer derived from an ester of trialkyl tin and an ethylenically unsaturated carboxylic acid together with at least two other ethylenically unsaturated monomers, one of said other ethylenically unsaturated monomers being a long chain alkyl or methacrylate and another of which is a lower alkyl acrylate or methacrylate.
Claim 19
Dependent Claim
49 words
A copolymer derived from an ester of trialkyl tin and an ethylenically unsaturated carboxylic acid together with at least two other ethylenically unsaturated monomers, one of said other ethylenically unsaturated monomers being a long chain alkyl or methacrylate and another of which is a lower alkyl acrylate or methacrylate.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-08-10 | 1980-02-09 | 1980-08-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-08-10 | 1984-02-09 | 1984-08-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-08-10 | 1988-02-09 | 1988-08-10 | $7700.00 | Window Closed / Lapsed |