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US3974058A Expired / Lapsed US ⏱️ 0.0 years remaining

Ruthenium coated cathodes

Assignee: BASF Corp
•
Filing: 1974-09-16
•
Granted: 1976-08-10
•
Expires: 1994-09-16
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Abstract

Abstract Composite cathodes comprising a metal substrate having thereon an intermediate coating of cobalt and an overcoating of ruthenium for use in electrolytic cells for the electrolysis of aqueous alkali metal halide solutions reduces the cell voltage requirements in comparison to the conventional ferrous metal cathodes traditionally used in such cells.

Inventors

  • 👤 Sudarshan D. Gokhale

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 11:45
CPC Classifications
C; C25; C25B; C25B11/00; C25B11/04; C25B11/051; C25B11/073; C25B11/091

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 55 words
In an electrolytic cell for the production of halogen and caustic from alkali metal halide solutions wherein the cell is equipped with anodes, cathodes, and means separating said anodes from said cathodes, the improvement which comprises a composite cathode comprising a metal substrate having thereon an intermediate coating of cobalt and an overcoating of ruthenium.
Claim 2
Dependent Claim 55 words
In an electrolytic cell for the production of halogen and caustic from alkali metal halide solutions wherein the cell is equipped with anodes, cathodes, and means separating said anodes from said cathodes, the improvement which comprises a composite cathode comprising a metal substrate having thereon an intermediate coating of cobalt and an overcoating of ruthenium.
Claim 3
Dependent Claim 16 words
The electrolytic cell of claim 1 wherein the coatings are on one side of the cathode.
Claim 4
Dependent Claim 16 words
The electrolytic cell of claim 1 wherein the coatings are on both sides of the cathode.
Claim 5
Dependent Claim 34 words
The electrolytic cell of claim 1 wherein there is a secondary coating between the intermediate coating of cobalt and the said metal substrate selected from the group consisting of nickel, platinum, palladium and rhodium.
Claim 6
Dependent Claim 12 words
The electrolytic cell of claim 4 wherein the secondary coating is nickel.
Claim 7
Dependent Claim 16 words
The electrolytic cell of claim 4 wherein the ruthenium coating is applied as two separate layers.
Claim 8
Dependent Claim 23 words
The electrolytic cell of claim 6 wherein the cathode is heat treated before and after the deposition of the first layer of ruthenium.
Claim 9
Dependent Claim 21 words
The electrolytic cell of claim 4 wherein the intermediate layer has a nonuniform thickness so as to increase the surface area.
Claim 10
Dependent Claim 19 words
The electrolytic cell of claim 1 wherein said means for separating said anodes from said cathode is a diaphragm.
Claim 11
Dependent Claim 19 words
The electrolytic cell of claim 1 wherein said means for separating said anode from said cathode is a membrane.

References Cited (Backward Citations)

US1427171A Cited
US2719797A Cited
US2967807A Cited
US3219563A Cited
US3282808A Cited
US3441495A Cited
US3849281A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-08-10 1980-02-09 1980-08-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-08-10 1984-02-09 1984-08-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-08-10 1988-02-09 1988-08-10 $7700.00 Window Closed / Lapsed

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