US3973968A
Expired / Lapsed
US
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Photographic acyl acetanilide color couplers with 2,5-dioxo-1-imidazolidinyl coupling off groups
Assignee: Konica Minolta Inc
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Filing: 1972-04-06
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Granted: 1976-08-10
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Expires: 1992-04-06
Abstract
Abstract An imagewise-exposed, light-sensitive silver halide color photographic material is developed, by use of developer, in the presence of a compound of the general formula: ##EQU1## wherein A is a residue formed by removing one of the hydrogen atoms of the active methylene group of an active methylene group-containing yellow image-forming coupler of the acyl acetanilide type; X is a hydrogen atom, or an alkyl, acyl, carboxymethyl, alkoxycarbonylmethyl, carbamylmethyl, aryl, aralkyl, nitro or amino group; and Y and Z are individually a hydrogen atom, or an alkyl, ureido, aryl, aralkyl, benzylidene, styryl, or anilino group.
Inventors
- 👤 Mitsuto Fujiwhara
- 👤 Syunji Matsuo
- 👤 Tamotsu Kojima
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 09:00
CPC Classifications
C; C07; C07D; C07D233/00; C07D233/54; C07D233/66; C07D233/72; G; G03; G03C; G03C7/00; G03C7/30; G03C7/305; G03C7/30511; G03C7/30517; G03C7/30535
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
109 words
A process for forming yellow-dye image of light-sensitive color photographic materials, characterized in developing an imagewise-exposed, light-sensitive silver halide color photographic material, by use of a developer, in the presence of at least one compound of the general formula: ##STR18## wherein A is a residue formed by removing one of the hydrogen atoms of the active methylene group of an active methylene group-containing yellow image-forming coupler of the acyl acetanilide type; X is a hydrogen atom, or an alkyl, acyl, carboxymethyl, alkoxycarbonylmethyl, carbamylmethyl, aryl, aralkyl, nitro or amino group; and Y and Z are individually a hydrogen atom, or an alkyl, ureido, aryl, aralkyl, benzylidene, styryl or anilino group.
Claim 2
Dependent Claim
109 words
A process for forming yellow-dye image of light-sensitive color photographic materials, characterized in developing an imagewise-exposed, light-sensitive silver halide color photographic material, by use of a developer, in the presence of at least one compound of the general formula: ##STR18## wherein A is a residue formed by removing one of the hydrogen atoms of the active methylene group of an active methylene group-containing yellow image-forming coupler of the acyl acetanilide type; X is a hydrogen atom, or an alkyl, acyl, carboxymethyl, alkoxycarbonylmethyl, carbamylmethyl, aryl, aralkyl, nitro or amino group; and Y and Z are individually a hydrogen atom, or an alkyl, ureido, aryl, aralkyl, benzylidene, styryl or anilino group.
Claim 3
Dependent Claim
51 words
A process for forming yellow-dye images of light-sensitive color photographic materials as claimed in claim 1, wherein said compound is at least one member selected from the group consisting of α-(2,5-dioxo-1-imidazolidinyl)-α-pivalyl-acetanilide, α-(2,5-dioxo-1-imidazolidinyl)-α-(p-octadecyloxybenzoyl)-2-methoxyacetanilide, α-(2,5-dioxo-1-imidazolidinyl)-α-pivalyl-2-chloro-5γ(2,4-di-t-amylphenoxy)-butyramidoacetanilide, α-[3-(2-ethylhexyl)-2,5-dioxo-1-imidazolidinyl]-α-pivalyl-2,5-dichloroacetanilide, α-(3-phenyl-2,5-dioxo-1-imidazolidinyl)-α{3-(2,4-di-t-amylphenoxy)butyramido]-benzoyl}-2-methoxy-acetanilide, α-(3-phenyl-2,5-dioxo-1-imidazolidinyl)-α-pivalyl-2-chloro-5-[γ-(2,4-di-t-amylphenoxy)-butyramidoacetanilide, α-(3-benzyl-2,5-dioxo-1-imidazolidinyl)-α-pivalyl-acetanilide, α-(3-methyl-2,5-dioxo-1-imidazolidinyl)-α-pivalyl-acetanilide, α-(3-acetyl-2,5-dioxo-1-imidazolidinyl)-α-benzolyl-2-chloro-5-[1-(n-dodecyloxycarbonyl)ethoxycarbonyl]-acetanilide, α-[3-p-chlorophenyl)-4,4-dimethyl-2,5-dioxo-1-imidazolidinyl]-.alpha.-pivalyl-2,5-dichloroacetanilide, α-[4-(p-methylbenzyl)-2,5-dioxo-1-imidazolidinyl]-α-(p-octadecyloxybenzoyl)-3,5-dicarboxyacetanilide dipotassium salt, α-[3-(p-ethoxyphenyl)-4-phenyl-2,5-dioxo-1-imidazolidinyl]-α-pivalyl-acetanilide, α,α'-(2,4,2',4'-tetraoxo-1,5'-biimidazolidine-3,3'-diyl)-bis-(α-pivalyl-2,5-dichloroacetanilide), α-(4-ureido-2,5-dioxo-1-imidazolidinyl)-α-pivalyl-acetanilide, α-(3-methyl-2,5-dioxo-1-imidazolidinyl)-α-pivalyl-2-chloro-5-[γ-(2,4-di-t-amylphenoxy)-butylamido]-acetanilide and α-(4-methyl-3-ethoxycarbonylmethyl-2,5-dioxo-1-imidazolidinyl)-.alpha.-(o-methoxybenzoyl)-3,5-dicarboxyacetanilide dipotassium salt.
Claim 4
Dependent Claim
96 words
A light-sensitive silver halide color photographic material which comprises a support and carried thereon an yellow color image-forming layer comprising a compound of the general formula ##EQU2## wherein A is a residue formed by removing one of the hydrogen atoms of the active methylene group of an active methylene group-containing yellow image-forming coupler of the acyl acetanilide type; X is a hydrogen atom, or an alkyl, acyl, carboxymethyl, alkoxycarbonylmethyl, carbamylmethyl, aryl, aralkyl, nitro or amino group; and Y and Z are individually a hydrogen atom, or an alkyl, ureido, aryl, aralkyl, benzylidene, styryl or anilino group.
Claim 5
Dependent Claim
96 words
A light-sensitive silver halide color photographic material which comprises a support and carried thereon an yellow color image-forming layer comprising a compound of the general formula ##EQU2## wherein A is a residue formed by removing one of the hydrogen atoms of the active methylene group of an active methylene group-containing yellow image-forming coupler of the acyl acetanilide type; X is a hydrogen atom, or an alkyl, acyl, carboxymethyl, alkoxycarbonylmethyl, carbamylmethyl, aryl, aralkyl, nitro or amino group; and Y and Z are individually a hydrogen atom, or an alkyl, ureido, aryl, aralkyl, benzylidene, styryl or anilino group.
Claim 6
Dependent Claim
93 words
A developer for light-sensitive silver halide color photographic materials which comprises a p-phenylenediamine type developing agent and a compound of the general formula ##STR19## wherein A is a residue formed by removing one of the hydrogen atoms of the active methylene group of an active methylene group-containing yellow image-forming coupler of the acyl acetanilide type; X is a hydrogen atom, or an alkyl, acyl, carboxymethyl, alkoxycarbonylmethyl, carbamylmethyl, aryl, aralkyl, nitro or amino group; and Y and Z are individually a hydrogen atom, or an alkyl, ureido, aryl, aralkyl, benzylidene, styryl or anilino group.
Claim 7
Dependent Claim
93 words
A developer for light-sensitive silver halide color photographic materials which comprises a p-phenylenediamine type developing agent and a compound of the general formula ##STR19## wherein A is a residue formed by removing one of the hydrogen atoms of the active methylene group of an active methylene group-containing yellow image-forming coupler of the acyl acetanilide type; X is a hydrogen atom, or an alkyl, acyl, carboxymethyl, alkoxycarbonylmethyl, carbamylmethyl, aryl, aralkyl, nitro or amino group; and Y and Z are individually a hydrogen atom, or an alkyl, ureido, aryl, aralkyl, benzylidene, styryl or anilino group.
Claim 8
Dependent Claim
26 words
A process for forming yellow-dye image of light-sensitive color photographic materials according to claim 1, wherein said compound is incorporated into the light-sensitive color photographic material.
Claim 9
Dependent Claim
23 words
A process for forming yellow-dye image of light-sensitive color photographic materials according to claim 1, wherein said compound is incorporated into the developer.
Claim 10
Independent Claim
90 words
A method for forming dye images comprising processing an exposed silver halide photographic emulsion with an aqueous alkaline solution containing an aromatic primary amine developing agent in the presence of a yellow forming coupler having the following general formula ##STR20## wherein R 1 is tertiary butyl; R 2 is an aryl group; X is a hydrogen atom, or an alkyl, acyl, carboxymethyl, alkoxycarbonylmethyl, carbamylmethyl, aryl, aralkyl, nitro or amino group; and Y and Z are individually a hydrogen atom, or an alkyl, ureido, aryl, aralkyl, benzylidene, styryl or anilino group.
Claim 11
Independent Claim
90 words
A method for forming dye images comprising processing an exposed silver halide photographic emulsion with an aqueous alkaline solution containing an aromatic primary amine developing agent in the presence of a yellow forming coupler having the following general formula ##STR20## wherein R 1 is tertiary butyl; R 2 is an aryl group; X is a hydrogen atom, or an alkyl, acyl, carboxymethyl, alkoxycarbonylmethyl, carbamylmethyl, aryl, aralkyl, nitro or amino group; and Y and Z are individually a hydrogen atom, or an alkyl, ureido, aryl, aralkyl, benzylidene, styryl or anilino group.
Claim 12
Independent Claim
90 words
A method for forming dye images comprising processing an exposed silver halide photographic emulsion with an aqueous alkaline solution containing an aromatic primary amino developing agent in the presence of a yellow forming coupler having the following formula ##STR21## wherein R 1 is an aryl group; R 2 is an aryl group; X is a hydrogen atom, or an alkyl, acyl, carboxymethyl, alkoxycarbamylmethyl, carbamylmethyl, aryl, aralkyl, nitro or amino group; and Y and Z are individually a hydrogen atom, or an alkyl, ureido, aryl, aralkyl, benzylidene, styryl or anilino group.
Claim 13
Independent Claim
90 words
A method for forming dye images comprising processing an exposed silver halide photographic emulsion with an aqueous alkaline solution containing an aromatic primary amino developing agent in the presence of a yellow forming coupler having the following formula ##STR21## wherein R 1 is an aryl group; R 2 is an aryl group; X is a hydrogen atom, or an alkyl, acyl, carboxymethyl, alkoxycarbamylmethyl, carbamylmethyl, aryl, aralkyl, nitro or amino group; and Y and Z are individually a hydrogen atom, or an alkyl, ureido, aryl, aralkyl, benzylidene, styryl or anilino group.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-08-10 | 1980-02-09 | 1980-08-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-08-10 | 1984-02-09 | 1984-08-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-08-10 | 1988-02-09 | 1988-08-10 | $7700.00 | Window Closed / Lapsed |