US3972787A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Palladium electrolyte baths utilizing quaternized pyridine compounds as brighteners
Assignee: Shipley Co Inc
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Filing: 1975-06-13
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Granted: 1976-08-03
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Expires: 1995-06-13
Abstract
Abstract Water soluble quarternized pyridine salts are used in amounts from about 0.001 g/l up to their solubility limit of about 10 g/l in aqueous palladium electrolyte plating baths to greatly enhance brightness even to the point of brilliance.
Inventors
- 👤 Fred I. Nobel
- 👤 John McCaskie
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 09:47
CPC Classifications
C; C25; C25D; C25D3/00; C25D3/02; C25D3/50; C25D3/52
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
161 words
An aqueous electrolytic palladium plating bath having a pH of between about 4 and 14 and containing a palladium compound capable of being electrolytically plated and a water soluble quarternized pyridinium brightening agent in an amount of about 0.001 g/l up to their solubility limit of about 10 g/l which in said bath provides a cation of the formula ##SPC2## in which R is a benzyl radical, a saturated or unsaturated straight, branched or cyclic C 1 -C 6 aliphatic or hydroxyaliphatic radical or a polyalkylene oxide radical and R 1 , R 2 , R 3 , R 4 and R 5 each is a hydrogen atom or a halogen atom or a lower alkyl, lower alkenyl, hydroxyl, carboxyl, amino, lower alkylol, lower alkylcarboxyl, lower alkylamine, lower alkylol amino group or a group resulting from the reaction of the hydroxyl, carboxyl, amino, lower alkylol, lower alkylcarboxyl or lower alkylamine group with an alkyl sultone, an alkyl lactone or an epoxide.
Claim 2
Dependent Claim
161 words
An aqueous electrolytic palladium plating bath having a pH of between about 4 and 14 and containing a palladium compound capable of being electrolytically plated and a water soluble quarternized pyridinium brightening agent in an amount of about 0.001 g/l up to their solubility limit of about 10 g/l which in said bath provides a cation of the formula ##SPC2## in which R is a benzyl radical, a saturated or unsaturated straight, branched or cyclic C 1 -C 6 aliphatic or hydroxyaliphatic radical or a polyalkylene oxide radical and R 1 , R 2 , R 3 , R 4 and R 5 each is a hydrogen atom or a halogen atom or a lower alkyl, lower alkenyl, hydroxyl, carboxyl, amino, lower alkylol, lower alkylcarboxyl, lower alkylamine, lower alkylol amino group or a group resulting from the reaction of the hydroxyl, carboxyl, amino, lower alkylol, lower alkylcarboxyl or lower alkylamine group with an alkyl sultone, an alkyl lactone or an epoxide.
Claim 3
Dependent Claim
33 words
The palladium plating bath of claim 1 in which said brightener in solution in said bath provides an anion which is a halogen atom or a tosylate, a mesylate, or a benzene sulfonate.
Claim 4
Dependent Claim
14 words
The palladium plating bath of claim 2 in which said brightener is N-benzyl-3-carboxypyridinium chloride.
Claim 5
Dependent Claim
14 words
The palladium plating bath of claim 2 in which said brightener is N-methyl-3-carboxypyridinium chloride.
Claim 6
Dependent Claim
14 words
The palladium plating bath of claim 2 in which said brightener is N-allyl-3-carboxypyridinium chloride.
Claim 7
Dependent Claim
14 words
The palladium plating bath of claim 2 in which said brightener is N-benzyl-3-carboxamidopyridinium chloride.
Claim 8
Dependent Claim
14 words
The palladium plating bath of claim 2 in which said brightener is N-allyl-2-methyl-5-vinylpyridinium bromide.
Claim 9
Dependent Claim
14 words
The palladium plating bath of claim 2 in which said brightener is N-methyl-3-carboxypyridinium tosylate.
Claim 10
Dependent Claim
14 words
The palladium plating bath of claim 2 in which said brightener is N-methyl-2-methyl-5-ethylpyridinium mesylate.
Claim 11
Dependent Claim
15 words
The palladium plating bath of claim 2 in which said brightener is N-methyl-2-vinylpyridinium benzene sulfonate.
Claim 12
Dependent Claim
14 words
The palladium plating bath of claim 2 in which said brightener is N-allylpyridinium bromide.
Claim 13
Dependent Claim
14 words
The palladium plating bath of claim 2 in which said brightener is N-[poly(2-hydroxypropoxy)]-3-carboxypyridinium chloride.
Claim 14
Dependent Claim
14 words
The palladium plating bath of claim 2 in which said brightener is N-[poly(2-hydroxypropoxy)]-2-aminopyridinium chloride.
Claim 15
Dependent Claim
16 words
The palladium plating bath of claim 2 in which said brightener is N-[poly(2-hydroxypropoxy)]-2-polyhydroxypropoxy amino pyridinium chloride.
References Cited (Backward Citations)
US3458409A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-08-03 | 1980-02-02 | 1980-08-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-08-03 | 1984-02-02 | 1984-08-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-08-03 | 1988-02-02 | 1988-08-03 | $7700.00 | Window Closed / Lapsed |