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US3972787A Expired / Lapsed US ⏱️ 0.0 years remaining

Palladium electrolyte baths utilizing quaternized pyridine compounds as brighteners

Assignee: Shipley Co Inc
•
Filing: 1975-06-13
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Granted: 1976-08-03
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Expires: 1995-06-13
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Abstract

Abstract Water soluble quarternized pyridine salts are used in amounts from about 0.001 g/l up to their solubility limit of about 10 g/l in aqueous palladium electrolyte plating baths to greatly enhance brightness even to the point of brilliance.

Inventors

  • 👤 Fred I. Nobel
  • 👤 John McCaskie

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 09:47
CPC Classifications
C; C25; C25D; C25D3/00; C25D3/02; C25D3/50; C25D3/52

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 161 words
An aqueous electrolytic palladium plating bath having a pH of between about 4 and 14 and containing a palladium compound capable of being electrolytically plated and a water soluble quarternized pyridinium brightening agent in an amount of about 0.001 g/l up to their solubility limit of about 10 g/l which in said bath provides a cation of the formula ##SPC2## in which R is a benzyl radical, a saturated or unsaturated straight, branched or cyclic C 1 -C 6 aliphatic or hydroxyaliphatic radical or a polyalkylene oxide radical and R 1 , R 2 , R 3 , R 4 and R 5 each is a hydrogen atom or a halogen atom or a lower alkyl, lower alkenyl, hydroxyl, carboxyl, amino, lower alkylol, lower alkylcarboxyl, lower alkylamine, lower alkylol amino group or a group resulting from the reaction of the hydroxyl, carboxyl, amino, lower alkylol, lower alkylcarboxyl or lower alkylamine group with an alkyl sultone, an alkyl lactone or an epoxide.
Claim 2
Dependent Claim 161 words
An aqueous electrolytic palladium plating bath having a pH of between about 4 and 14 and containing a palladium compound capable of being electrolytically plated and a water soluble quarternized pyridinium brightening agent in an amount of about 0.001 g/l up to their solubility limit of about 10 g/l which in said bath provides a cation of the formula ##SPC2## in which R is a benzyl radical, a saturated or unsaturated straight, branched or cyclic C 1 -C 6 aliphatic or hydroxyaliphatic radical or a polyalkylene oxide radical and R 1 , R 2 , R 3 , R 4 and R 5 each is a hydrogen atom or a halogen atom or a lower alkyl, lower alkenyl, hydroxyl, carboxyl, amino, lower alkylol, lower alkylcarboxyl, lower alkylamine, lower alkylol amino group or a group resulting from the reaction of the hydroxyl, carboxyl, amino, lower alkylol, lower alkylcarboxyl or lower alkylamine group with an alkyl sultone, an alkyl lactone or an epoxide.
Claim 3
Dependent Claim 33 words
The palladium plating bath of claim 1 in which said brightener in solution in said bath provides an anion which is a halogen atom or a tosylate, a mesylate, or a benzene sulfonate.
Claim 4
Dependent Claim 14 words
The palladium plating bath of claim 2 in which said brightener is N-benzyl-3-carboxypyridinium chloride.
Claim 5
Dependent Claim 14 words
The palladium plating bath of claim 2 in which said brightener is N-methyl-3-carboxypyridinium chloride.
Claim 6
Dependent Claim 14 words
The palladium plating bath of claim 2 in which said brightener is N-allyl-3-carboxypyridinium chloride.
Claim 7
Dependent Claim 14 words
The palladium plating bath of claim 2 in which said brightener is N-benzyl-3-carboxamidopyridinium chloride.
Claim 8
Dependent Claim 14 words
The palladium plating bath of claim 2 in which said brightener is N-allyl-2-methyl-5-vinylpyridinium bromide.
Claim 9
Dependent Claim 14 words
The palladium plating bath of claim 2 in which said brightener is N-methyl-3-carboxypyridinium tosylate.
Claim 10
Dependent Claim 14 words
The palladium plating bath of claim 2 in which said brightener is N-methyl-2-methyl-5-ethylpyridinium mesylate.
Claim 11
Dependent Claim 15 words
The palladium plating bath of claim 2 in which said brightener is N-methyl-2-vinylpyridinium benzene sulfonate.
Claim 12
Dependent Claim 14 words
The palladium plating bath of claim 2 in which said brightener is N-allylpyridinium bromide.
Claim 13
Dependent Claim 14 words
The palladium plating bath of claim 2 in which said brightener is N-[poly(2-hydroxypropoxy)]-3-carboxypyridinium chloride.
Claim 14
Dependent Claim 14 words
The palladium plating bath of claim 2 in which said brightener is N-[poly(2-hydroxypropoxy)]-2-aminopyridinium chloride.
Claim 15
Dependent Claim 16 words
The palladium plating bath of claim 2 in which said brightener is N-[poly(2-hydroxypropoxy)]-2-polyhydroxypropoxy amino pyridinium chloride.

References Cited (Backward Citations)

US3458409A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-08-03 1980-02-02 1980-08-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-08-03 1984-02-02 1984-08-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-08-03 1988-02-02 1988-08-03 $7700.00 Window Closed / Lapsed

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