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US3972719A Expired / Lapsed US ⏱️ 0.0 years remaining

Photographic developer compositions

Assignee: Agfa Gevaert NV
•
Filing: 1975-07-14
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Granted: 1976-08-03
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Expires: 1995-07-14
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Abstract

Abstract This invention relates to the addition of a nitro-indazole and a polymer containing a plurality of alkylene oxide units and having a molecular weight of at least about 1500, to an aqueous lithographic developer system.

Inventors

  • 👤 Gerard Laurens Vanreusel
  • 👤 Raoul Jan Bortels

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 22:47
CPC Classifications
G; G03; G03C; G03C5/00; G03C5/26; G03C5/29; G03C5/305; C; C07; C07D; C07D231/00; C07D231/54; C07D231/56; Y; Y10; Y10S; Y10S430/00; Y10S430/15

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 198 words
An alkaline aqueous developer composition suited for producing halftone images showing the lith-gradation by development of silver halide recording materials in which the halide consists of at least about 50 mole % of chloride wherein said composition comprises: 1. a p-dihydroxybenzene developing agent in an amount of about 0.05-0.50 mole per liter, 2. a sulfite compound providing an amount of sulfite ions (SO 3 - - ) of at least about 5 grams per liter, 3. a sufficient amount of an alkaline compound to impart to said composition a pH of about 9.7-11.5, 4. a nitro-indazole corresponding to the following general formula: ##SPC5## wherein: R is hydrogen or a lower (C 1 -C 5 ) alkyl group, and the nitro-group is in the 5- or 6-position, 5. a polymer containing a plurality of alkylene oxide units and having a molecular weight of at least about 1500, said polymer being present in a concentration of at least 500 mg per liter, 6. bromide ions in a concentration of at least 0.2 g per liter, said composition containing not more than about 0.05 g/l of any auxiliary developing agent that shows a superadditive developing effect with said p-dihydroxybenzene developing agent.
Claim 2
Dependent Claim 198 words
An alkaline aqueous developer composition suited for producing halftone images showing the lith-gradation by development of silver halide recording materials in which the halide consists of at least about 50 mole % of chloride wherein said composition comprises: 1. a p-dihydroxybenzene developing agent in an amount of about 0.05-0.50 mole per liter, 2. a sulfite compound providing an amount of sulfite ions (SO 3 - - ) of at least about 5 grams per liter, 3. a sufficient amount of an alkaline compound to impart to said composition a pH of about 9.7-11.5, 4. a nitro-indazole corresponding to the following general formula: ##SPC5## wherein: R is hydrogen or a lower (C 1 -C 5 ) alkyl group, and the nitro-group is in the 5- or 6-position, 5. a polymer containing a plurality of alkylene oxide units and having a molecular weight of at least about 1500, said polymer being present in a concentration of at least 500 mg per liter, 6. bromide ions in a concentration of at least 0.2 g per liter, said composition containing not more than about 0.05 g/l of any auxiliary developing agent that shows a superadditive developing effect with said p-dihydroxybenzene developing agent.
Claim 3
Dependent Claim 31 words
A developer composition according to claim 1, wherein the polyoxyalkylene compound is present in the developer in an amount in the range of about 0.5 to about 2 g per liter.
Claim 4
Dependent Claim 30 words
A developer composition according to claim 1, wherein the polymeric compound containing a plurality of oxyalkylene units is a polyoxyethylene glycol with an average molecular weight of at least 1500.
Claim 5
Dependent Claim 13 words
A developer composition according to claim 1, wherein the nitro-indazole compound is 5-nitro-indazole.
Claim 6
Dependent Claim 23 words
A developer composition according to claim 1, wherein the nitro-indazole compound is present in an amount of 5 to 100 milligrams per liter.
Claim 7
Dependent Claim 13 words
A developer composition according to claim 1, wherein the composition contains formaldehyde bisulphite.
Claim 8
Dependent Claim 14 words
A developer composition according to claim 1, wherein the composition contains an onium compound.
Claim 9
Dependent Claim 16 words
A developer composition according to claim 1, wherein the composition contains 1,1'-[ethylene-tris(oxyalkylene)]-bis-(pyridinium p-toluene-sulphonate) as onium compound.
Claim 10
Dependent Claim 23 words
A developer composition according to claim 8, wherein the onium compound is present in an amount of 0.1 to 3.0 g per liter.
Claim 11
Dependent Claim 24 words
A developer composition according to claim 1, wherein the free bromide ions are present in an amount of 0.2 to 5.0 g per liter.
Claim 12
Dependent Claim 25 words
A developer composition according to claim 1, wherein the developing agent is hydroquinone present in an amount of 0.05 mole to 0.50 mole per liter.
Claim 13
Dependent Claim 24 words
A developer composition according to claim 1, wherein the sulphite ions are present in an amount of 5 g to 100 g per liter.
Claim 14
Dependent Claim 15 words
A developer composition according to claim 1, wherein said composition contains ascorbic acid as preservative.
Claim 15
Independent Claim 203 words
A method for developing a silver halide emulsion recording material in which the halide consists essentially of at least 50 mole % of chloride and which has been subjected to an exposure for producing an halftone print wherein the development of said material is carried out in a aqueous alkaline developing composition comprising: 1. a p-dihydroxybenzene developing agent in an amount of about 0.05-0.50 mole per liter, 2. a sulfite compound providing an amount of sulfite ions (SO 3 - - ) of at least about 5 grams per liter, 3. a sufficient amount of an alkaline compound to impart to said composition a pH of about 9.7-11.5, 4. a nitro-indazole corresponding to the following general formula: ##SPC6##wherein: R is hydrogen or a lower (C 1 -C 5 ) alkyl group, and the nitro group is in the 5- or 6-position, 5. a polymer containing a plurality of alkylene oxide units, said polymer being present in a concentration of at least 500 mg per liter, 6. bromide ions in a concentration of at least 0.2 g per liter, said composition containing not more than about 0.05 g/l of any auxiliary developing agent that shows a superadditive developing effect with said p-dihydroxybenzene developing agent.
Claim 16
Independent Claim 203 words
A method for developing a silver halide emulsion recording material in which the halide consists essentially of at least 50 mole % of chloride and which has been subjected to an exposure for producing an halftone print wherein the development of said material is carried out in a aqueous alkaline developing composition comprising: 1. a p-dihydroxybenzene developing agent in an amount of about 0.05-0.50 mole per liter, 2. a sulfite compound providing an amount of sulfite ions (SO 3 - - ) of at least about 5 grams per liter, 3. a sufficient amount of an alkaline compound to impart to said composition a pH of about 9.7-11.5, 4. a nitro-indazole corresponding to the following general formula: ##SPC6##wherein: R is hydrogen or a lower (C 1 -C 5 ) alkyl group, and the nitro group is in the 5- or 6-position, 5. a polymer containing a plurality of alkylene oxide units, said polymer being present in a concentration of at least 500 mg per liter, 6. bromide ions in a concentration of at least 0.2 g per liter, said composition containing not more than about 0.05 g/l of any auxiliary developing agent that shows a superadditive developing effect with said p-dihydroxybenzene developing agent.
Claim 17
Dependent Claim 25 words
A method according to claim 14, wherein the exposed light-sensitive silver halide material is developed by transporting it in continuous motion through said developing composition.

References Cited (Backward Citations)

US3158483A Cited
US3128180A Cited
US3129097A Cited
US3490906A Cited
US3490905A Cited
US3532499A Cited
US3573914A Cited
US3615488A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-08-03 1980-02-02 1980-08-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-08-03 1984-02-02 1984-08-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-08-03 1988-02-02 1988-08-03 $7700.00 Window Closed / Lapsed

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