US3972719A
Expired / Lapsed
US
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Photographic developer compositions
Assignee: Agfa Gevaert NV
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Filing: 1975-07-14
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Granted: 1976-08-03
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Expires: 1995-07-14
Abstract
Abstract This invention relates to the addition of a nitro-indazole and a polymer containing a plurality of alkylene oxide units and having a molecular weight of at least about 1500, to an aqueous lithographic developer system.
Inventors
- 👤 Gerard Laurens Vanreusel
- 👤 Raoul Jan Bortels
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 22:47
CPC Classifications
G; G03; G03C; G03C5/00; G03C5/26; G03C5/29; G03C5/305; C; C07; C07D; C07D231/00; C07D231/54; C07D231/56; Y; Y10; Y10S; Y10S430/00; Y10S430/15
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
198 words
An alkaline aqueous developer composition suited for producing halftone images showing the lith-gradation by development of silver halide recording materials in which the halide consists of at least about 50 mole % of chloride wherein said composition comprises: 1. a p-dihydroxybenzene developing agent in an amount of about 0.05-0.50 mole per liter, 2. a sulfite compound providing an amount of sulfite ions (SO 3 - - ) of at least about 5 grams per liter, 3. a sufficient amount of an alkaline compound to impart to said composition a pH of about 9.7-11.5, 4. a nitro-indazole corresponding to the following general formula: ##SPC5## wherein: R is hydrogen or a lower (C 1 -C 5 ) alkyl group, and the nitro-group is in the 5- or 6-position, 5. a polymer containing a plurality of alkylene oxide units and having a molecular weight of at least about 1500, said polymer being present in a concentration of at least 500 mg per liter, 6. bromide ions in a concentration of at least 0.2 g per liter, said composition containing not more than about 0.05 g/l of any auxiliary developing agent that shows a superadditive developing effect with said p-dihydroxybenzene developing agent.
Claim 2
Dependent Claim
198 words
An alkaline aqueous developer composition suited for producing halftone images showing the lith-gradation by development of silver halide recording materials in which the halide consists of at least about 50 mole % of chloride wherein said composition comprises: 1. a p-dihydroxybenzene developing agent in an amount of about 0.05-0.50 mole per liter, 2. a sulfite compound providing an amount of sulfite ions (SO 3 - - ) of at least about 5 grams per liter, 3. a sufficient amount of an alkaline compound to impart to said composition a pH of about 9.7-11.5, 4. a nitro-indazole corresponding to the following general formula: ##SPC5## wherein: R is hydrogen or a lower (C 1 -C 5 ) alkyl group, and the nitro-group is in the 5- or 6-position, 5. a polymer containing a plurality of alkylene oxide units and having a molecular weight of at least about 1500, said polymer being present in a concentration of at least 500 mg per liter, 6. bromide ions in a concentration of at least 0.2 g per liter, said composition containing not more than about 0.05 g/l of any auxiliary developing agent that shows a superadditive developing effect with said p-dihydroxybenzene developing agent.
Claim 3
Dependent Claim
31 words
A developer composition according to claim 1, wherein the polyoxyalkylene compound is present in the developer in an amount in the range of about 0.5 to about 2 g per liter.
Claim 4
Dependent Claim
30 words
A developer composition according to claim 1, wherein the polymeric compound containing a plurality of oxyalkylene units is a polyoxyethylene glycol with an average molecular weight of at least 1500.
Claim 5
Dependent Claim
13 words
A developer composition according to claim 1, wherein the nitro-indazole compound is 5-nitro-indazole.
Claim 6
Dependent Claim
23 words
A developer composition according to claim 1, wherein the nitro-indazole compound is present in an amount of 5 to 100 milligrams per liter.
Claim 7
Dependent Claim
13 words
A developer composition according to claim 1, wherein the composition contains formaldehyde bisulphite.
Claim 8
Dependent Claim
14 words
A developer composition according to claim 1, wherein the composition contains an onium compound.
Claim 9
Dependent Claim
16 words
A developer composition according to claim 1, wherein the composition contains 1,1'-[ethylene-tris(oxyalkylene)]-bis-(pyridinium p-toluene-sulphonate) as onium compound.
Claim 10
Dependent Claim
23 words
A developer composition according to claim 8, wherein the onium compound is present in an amount of 0.1 to 3.0 g per liter.
Claim 11
Dependent Claim
24 words
A developer composition according to claim 1, wherein the free bromide ions are present in an amount of 0.2 to 5.0 g per liter.
Claim 12
Dependent Claim
25 words
A developer composition according to claim 1, wherein the developing agent is hydroquinone present in an amount of 0.05 mole to 0.50 mole per liter.
Claim 13
Dependent Claim
24 words
A developer composition according to claim 1, wherein the sulphite ions are present in an amount of 5 g to 100 g per liter.
Claim 14
Dependent Claim
15 words
A developer composition according to claim 1, wherein said composition contains ascorbic acid as preservative.
Claim 15
Independent Claim
203 words
A method for developing a silver halide emulsion recording material in which the halide consists essentially of at least 50 mole % of chloride and which has been subjected to an exposure for producing an halftone print wherein the development of said material is carried out in a aqueous alkaline developing composition comprising: 1. a p-dihydroxybenzene developing agent in an amount of about 0.05-0.50 mole per liter, 2. a sulfite compound providing an amount of sulfite ions (SO 3 - - ) of at least about 5 grams per liter, 3. a sufficient amount of an alkaline compound to impart to said composition a pH of about 9.7-11.5, 4. a nitro-indazole corresponding to the following general formula: ##SPC6##wherein: R is hydrogen or a lower (C 1 -C 5 ) alkyl group, and the nitro group is in the 5- or 6-position, 5. a polymer containing a plurality of alkylene oxide units, said polymer being present in a concentration of at least 500 mg per liter, 6. bromide ions in a concentration of at least 0.2 g per liter, said composition containing not more than about 0.05 g/l of any auxiliary developing agent that shows a superadditive developing effect with said p-dihydroxybenzene developing agent.
Claim 16
Independent Claim
203 words
A method for developing a silver halide emulsion recording material in which the halide consists essentially of at least 50 mole % of chloride and which has been subjected to an exposure for producing an halftone print wherein the development of said material is carried out in a aqueous alkaline developing composition comprising: 1. a p-dihydroxybenzene developing agent in an amount of about 0.05-0.50 mole per liter, 2. a sulfite compound providing an amount of sulfite ions (SO 3 - - ) of at least about 5 grams per liter, 3. a sufficient amount of an alkaline compound to impart to said composition a pH of about 9.7-11.5, 4. a nitro-indazole corresponding to the following general formula: ##SPC6##wherein: R is hydrogen or a lower (C 1 -C 5 ) alkyl group, and the nitro group is in the 5- or 6-position, 5. a polymer containing a plurality of alkylene oxide units, said polymer being present in a concentration of at least 500 mg per liter, 6. bromide ions in a concentration of at least 0.2 g per liter, said composition containing not more than about 0.05 g/l of any auxiliary developing agent that shows a superadditive developing effect with said p-dihydroxybenzene developing agent.
Claim 17
Dependent Claim
25 words
A method according to claim 14, wherein the exposed light-sensitive silver halide material is developed by transporting it in continuous motion through said developing composition.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-08-03 | 1980-02-02 | 1980-08-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-08-03 | 1984-02-02 | 1984-08-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-08-03 | 1988-02-02 | 1988-08-03 | $7700.00 | Window Closed / Lapsed |