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US3971884A Expired / Lapsed US ⏱️ 0.0 years remaining

Ethylene-vinyl acetate silicone rubber adherent laminates and method of production

Assignee: Millennium Petrochemicals Inc
•
Filing: 1975-09-12
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Granted: 1976-07-27
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Expires: 1995-09-12
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Abstract

Abstract Crosslinkable ethylene-vinyl acetate copolymer resins are rendered amenable to forming adherent laminates with crosslinkable silicone rubber by coating the surface of the ethylene-vinyl acetate resin with a solution of a silane or a member of the class of compounds known as polyfunctional monomers prior to adhering the resin to the silicone rubber.

Inventors

  • 👤 Lawrence A. Meeks
  • 👤 James W. Biggs

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 01:43
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/46; B; B32; B32B; B32B25/00; B32B25/04; B32B25/08; B32B25/20; B32B27/00; B32B27/30; B32B27/306; C; C08; C08G; C08G77/00; C08G77/04; C09; C09J; C09J4/00; C09J5/00; C09J5/02; C09J5/06; H01B3/44; H01B3/448; B32B2307/00; B32B2307/20; B32B2307/206; C09J2431/00; C09J2431/008; C09J2483/00; C09J2483/008; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/294; Y10T428/2942; Y10T428/2947; Y10T428/2962; Y10T428/31504; Y10T428/31652; Y10T428/31667

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 79 words
A method of improving the bonding of crosslinkable ethylene-vinyl acetate with crosslinkable silicone rubber which comprises coating the surface of at least one of said ethylene-vinyl acetate and silicone rubber with a solution of a bonding agent in an inert solvent and evaporating the inert solvent from said surface prior to adhering the ethylene-vinyl acetate to the silicone rubber and crosslinking the resulting laminate, wherein said bonding agent is selected from the group consisting of silanes and polyfunctional monomers.
Claim 2
Independent Claim 79 words
A method of improving the bonding of crosslinkable ethylene-vinyl acetate with crosslinkable silicone rubber which comprises coating the surface of at least one of said ethylene-vinyl acetate and silicone rubber with a solution of a bonding agent in an inert solvent and evaporating the inert solvent from said surface prior to adhering the ethylene-vinyl acetate to the silicone rubber and crosslinking the resulting laminate, wherein said bonding agent is selected from the group consisting of silanes and polyfunctional monomers.
Claim 3
Dependent Claim 78 words
The method of claim 1 wherein said bonding agent is selected from the group consisting of vinyl-tris(beta methoxyethoxy)silane, gamma methacryloxypropyl trimethoxysilane, ##SPC2## (CH 3 O) 3 Si(CH 2 ) 3 Cl, triallyl cyanurate, triallyl isocyanurate, trimethylolpropane trimethacrylate, trimethylolpropane triacrylate, ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, 1,3-butylene glycol dimethacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, 1,4-butylene glycol diacrylate, allyl methacrylate, diallyl fumarate, divinyl benzene, and triallyl phosphate.
Claim 4
Dependent Claim 17 words
The method of claim 2 wherein said solution contains about 1-80 weight percent of said bonding agent.
Claim 5
Dependent Claim 17 words
The method of claim 3 wherein said solution contains about 1-50 weight percent of said bonding agent.
Claim 6
Dependent Claim 37 words
The method of claim 4 wherein said bonding agent is selected from the group consisting of triallyl isocyanurate, trimethylolpropane trimethacrylate, gamma methacryloxypropyl trimethoxysilane, triallyl cyanurate, 1,4-butylene glycol dimethacrylate, 1,3-butylene glycol dimethacrylate, 1,4-butylene glycol acrylate and divinyl benzene.
Claim 7
Dependent Claim 32 words
A laminate comprising a crosslinked ethylene-vinyl acetate copolymer ply adhered to a ply of crosslinked silicone rubber by a surface bonding agent selected from the group consisting of silane and polyfunctional monomers.
Claim 8
Dependent Claim 32 words
A laminate comprising a crosslinked ethylene-vinyl acetate copolymer ply adhered to a ply of crosslinked silicone rubber by a surface bonding agent selected from the group consisting of silane and polyfunctional monomers.
Claim 9
Dependent Claim 78 words
The laminate of claim 6 wherein said bonding agent is selected from the group consisting of vinyl-tris(beta methoxyethoxy)silane, gamma methacryloxypropyl trimethoxysilane, ##SPC3## (CH 3 O) 3 Si(CH 2 ) 3 Cl, triallyl cyanurate, triallyl isocyanurate, trimethylolpropane trimethacrylate, trimethylolpropane triacrylate, ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, 1,3-butylene glycol dimethacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, 1,4-butylene glycol diacrylate, allyl methacrylate, diallyl fumarate, divinyl benzene, and triallyl phosphate.
Claim 10
Dependent Claim 37 words
The laminate of claim 7 wherein said bonding agent is selected from the group consisting of triallyl isocyanurate, trimethylolpropane trimethacrylate, gamma methacryloxypropyl trimethoxysilane, triallyl cyanurate, 1,4-butylene glycol dimethacrylate, 1,3-butylene glycol dimethacrylate, 1,4-butylene glycol acrylate and divinyl benzene.
Claim 11
Dependent Claim 68 words
An insulated ignition wire comprising a central conductor, a first insulating material surrounding the central conductor and a second insulating material surrounding the first insulated material and bonded thereto by a surface bonding agent, wherein said first insulating material is a crosslinked ethylene-vinyl acetate copolymer, said second insulating material is crosslinked silicone rubber, and said bonding agent is selected from the group consisting of silane and polyfunctional monomers.
Claim 12
Dependent Claim 68 words
An insulated ignition wire comprising a central conductor, a first insulating material surrounding the central conductor and a second insulating material surrounding the first insulated material and bonded thereto by a surface bonding agent, wherein said first insulating material is a crosslinked ethylene-vinyl acetate copolymer, said second insulating material is crosslinked silicone rubber, and said bonding agent is selected from the group consisting of silane and polyfunctional monomers.
Claim 13
Dependent Claim 80 words
The insulated ignition wire of claim 9 wherein said bonding agent is selected from the group consisting of vinyl-tris(beta methoxyethoxy)silane, gamma methacryloxypropyl trimethoxysilane, ##SPC4## (CH 3 O) 3 Si(CH 2 ) 3 Cl, triallyl cyanurate, triallyl isocyanurate, trimethylolpropane trimethacrylate, trimethylolpropane triacrylate, ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, 1,3-butylene glycol dimethacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, 1,4-butylene glycol diacrylate, allyl methacrylate, diallyl fumarate, divinyl benzene, and triallyl phosphate.
Claim 14
Dependent Claim 13 words
The insulated ignition wire of claim 10 wherein said central conductor is copper.
Claim 15
Dependent Claim 39 words
The insulated ignition wire of claim 10 wherein said bonding agent is selected from the group consisting of triallyl isocyanurate, trimethylolpropane trimethacrylate, gamma methacryloxypropyl trimethoxysilane, triallyl cyanurate, 1,4-butylene glycol dimethacrylate, 1,3-butylene glycol dimethacrylate, 1,4-butylene glycol acrylate and divinyl benzene.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-07-27 1980-01-26 1980-07-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-07-27 1984-01-26 1984-07-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-07-27 1988-01-26 1988-07-27 $7700.00 Window Closed / Lapsed

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