US3971883A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Silicone rubber-ethylene vinyl acetate adhesive laminates and preparation thereof
Assignee: Millennium Petrochemicals Inc
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Filing: 1975-09-12
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Granted: 1976-07-27
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Expires: 1995-09-12
Abstract
Abstract Crosslinkable ethylene-vinyl acetate copolymer resins are rendered amenable to forming adherent laminates with cross-linkable silicone rubber by dusting the surface of either the resin or rubber, or both, with a bonding agent.
Inventors
- 👤 Lawrence A. Meeks
- 👤 James W. Biggs
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 06:21
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/46; B; B32; B32B; B32B25/00; B32B25/04; B32B25/08; B32B25/20; B32B27/00; B32B27/30; B32B27/306; C; C08; C08G; C08G77/00; C08G77/04; C08J; C08J5/00; C08J5/12; C09; C09J; C09J4/00; C09J5/00; C09J5/02; H01B3/44; H01B3/448; B32B2307/00; B32B2307/20; B32B2307/206; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/294; Y10T428/2942; Y10T428/2947; Y10T428/2962; Y10T428/31504; Y10T428/31652; Y10T428/31667
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
86 words
A method of improving the bonding of crosslinked ethylene-vinyl acetate to crosslinked silicone rubber which comprises coating the surface of at least one of said ethylene-vinyl acetate and silicone rubber with a powdery bonding agent in an amount of about 0.00001-0.001 gram per square inch of surface area prior to adhering the ethylene-vinyl acetate to the silicone rubber and crosslinking the resulting laminate, wherein said bonding agent is silica or an admixture of silica and a member selected from the group of silane and polyfunctional monomer.
Claim 2
Independent Claim
86 words
A method of improving the bonding of crosslinked ethylene-vinyl acetate to crosslinked silicone rubber which comprises coating the surface of at least one of said ethylene-vinyl acetate and silicone rubber with a powdery bonding agent in an amount of about 0.00001-0.001 gram per square inch of surface area prior to adhering the ethylene-vinyl acetate to the silicone rubber and crosslinking the resulting laminate, wherein said bonding agent is silica or an admixture of silica and a member selected from the group of silane and polyfunctional monomer.
Claim 3
Dependent Claim
93 words
The method of claim 1 wherein said member is selected from the group consisting of vinyl-tris(beta methoxyethoxy)silane, gamma methacryloxypropyl trimethoxysilane, ##SPC2## (CH 3 O) 3 Si(CH 2 ) 3 NHCH 2 CH 2 NH 2 , ##EQU2## (CH 3 O) 3 Si(CH 2 ) 3 Cl, triallyl cyanurate, triallyl isocyanurate, trimethylolpropane trimethacrylate, trimethylolpropane triacrylate, ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, 1,3-butylene glycol dimethacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, 1,4-butylene glycol diacrylate, allyl methacrylate, diallyl fumarate, divinyl benzene and triallyl phosphate.
Claim 4
Dependent Claim
22 words
The method of claim 2 wherein said surface is coated in an amount of about 0.00005-0.0005 gram per square inch of surface.
Claim 5
Dependent Claim
22 words
The method of claim 3 wherein said surface is coated in an amount of about 0.0001 gram per square inch of surface.
Claim 6
Dependent Claim
14 words
The method of claim 2 wherein said bonding agent is precipitated white amorphous silica.
Claim 7
Dependent Claim
20 words
The method of claim 2 wherein said bonding agent is an admixture of precipitated white amorphous silica and a silane.
Claim 8
Dependent Claim
66 words
A laminate comprising a crosslinked ethylene-vinyl acetate copolymer ply adhered to a ply of crosslinked silicone rubber, the interfacial surfaces of said plies being in contact with a powder bonding agent in an amount of 0.00001-0.001 gram per square inch of planar surface, said bonding agent being silica or an admixture of silica with a material selected from the group consisting of silane and polyfunctional monomer.
Claim 9
Dependent Claim
66 words
A laminate comprising a crosslinked ethylene-vinyl acetate copolymer ply adhered to a ply of crosslinked silicone rubber, the interfacial surfaces of said plies being in contact with a powder bonding agent in an amount of 0.00001-0.001 gram per square inch of planar surface, said bonding agent being silica or an admixture of silica with a material selected from the group consisting of silane and polyfunctional monomer.
Claim 10
Dependent Claim
93 words
The laminate of claim 7 wherein said material is selected from the group consisting of vinyl-tris(beta methoxyethoxy)silane, gamma methacryloxypropyl trimethoxysilane, ##SPC3## (CH 3 O) 3 Si(CH 2 ) 3 NHCH 2 CH 2 NH 2 , ##EQU3## (CH 3 O) 3 Si(CH 2 ) 3 Cl, triallyl cyanurate, triallyl isocyanurate, trimethylolpropane trimethacrylate, trimethylolpropane triacrylate, ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, 1,3-butylene glycol dimethacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, 1,4-butylene glycol diacrylate, allyl methacrylate, diallyl fumarate, divinyl benzene and triallyl phosphate.
Claim 11
Dependent Claim
18 words
The laminate of claim 8 wherein said amount is about 0.00005-0.0005 gram per square inch of planar surface.
Claim 12
Dependent Claim
18 words
The laminate of claim 9 wherein said amount is about 0.0001 gram per square inch of planar surface.
Claim 13
Dependent Claim
11 words
The laminate of claim 8 wherein said bonding agent is silica.
Claim 14
Dependent Claim
17 words
The laminate of claim 8 wherein said bonding agent is an admixture of silica and a silane.
Claim 15
Dependent Claim
100 words
An insulated ignition wire comprising a central conductor, a first insulating material surrounding the central conductor and a second insulating material surrounding the first insulating material and bonded thereto, wherein said first insulating material is crosslinked ethylene-vinyl acetate and said second insulating material is crosslinked silicone rubber and wherein the interfacial surfaces of said first and second insulating material are bonded by a powder bonding agent in an amount of 0.00001-0.001 gram per square inch of surface, said bonding agent being silica or a mixture of silica and a member of the group consisting of a silane and polyfunctional monomer.
Claim 16
Dependent Claim
100 words
An insulated ignition wire comprising a central conductor, a first insulating material surrounding the central conductor and a second insulating material surrounding the first insulating material and bonded thereto, wherein said first insulating material is crosslinked ethylene-vinyl acetate and said second insulating material is crosslinked silicone rubber and wherein the interfacial surfaces of said first and second insulating material are bonded by a powder bonding agent in an amount of 0.00001-0.001 gram per square inch of surface, said bonding agent being silica or a mixture of silica and a member of the group consisting of a silane and polyfunctional monomer.
Claim 17
Dependent Claim
96 words
The insulated ignition wire of claim 13 wherein said member is selected from the group consisting of vinyl-tris (beta methoxyethoxy)silane, gamma methacryloxypropyl trimethoxysilane, ##SPC4## (CH 3 O) 3 Si(CH 2 ) 3 NHCH 2 CH 2 NH 2 , ##EQU4## (CH 3 O) 3 Si(CH 2 ) 3 Cl, triallyl cyanurate, triallyl isocyanurate, trimethylolpropane trimethacrylate, trimethylolpropane triacrylate, ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, 1,3-butylene glycol dimethacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, 1,4-butylene glycol diacrylate, allyl methacrylate, diallyl fumarate, divinyl benzene and triallyl phosphate.
Claim 18
Dependent Claim
13 words
The insulated ignition wire of claim 14 wherein said central conductor is copper.
Claim 19
Dependent Claim
19 words
The insulated ignition wire of claim 15 wherein said amount is about 0.00005-0.0005 gram per square inch of surface.
Claim 20
Dependent Claim
19 words
The insulated ignition wire of claim 16 wherein said amount is about 0.0001 gram per square inch of surface.
Claim 21
Dependent Claim
13 words
The insulated ignition wire of claim 15 wherein said bonding agent is silica.
Claim 22
Dependent Claim
19 words
The insulated ignition wire of claim 15 wherein said bonding agent is an admixture of silica and a silane.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-07-27 | 1980-01-26 | 1980-07-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-07-27 | 1984-01-26 | 1984-07-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-07-27 | 1988-01-26 | 1988-07-27 | $7700.00 | Window Closed / Lapsed |