← Back to Patent Explorer
US3970632A Expired / Lapsed US ⏱️ 0.0 years remaining

Pigment containing polyolefin composition

Assignee: Mitsubishi Chemical Corp
•
Filing: 1974-11-27
•
Granted: 1976-07-20
•
Expires: 1994-11-27
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A polymer composition, which comprises a polymer containing a quinophthalone pigment having the formula WHEREIN THE QUINOLINE RING CAN HAVE A SUBSTITUENT SELECTED FROM THE GROUP CONSISTING OF HALOGEN, LOWER ALKYL, LOWER ALKOXY, AND CARBOXYL, AND THE RING A is a benzene ring or a naphthalene ring which can have a substituent selected from the group consisting of halogen, and -COW wherein W represents hydroxyl, lower alkoxyl or amino; and 0.005-5% by weight of a piperidine type or imidazolidine type ultraviolet absorbing agent.

Inventors

  • 👤 Hirohisa Yoshiura
  • 👤 Toshiharu Arai
  • 👤 Masao Miyake
  • 👤 Kiyoshi Enriki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 17:12
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3432; C08K5/3437

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 607 words
A polymer composition which comprises: a polyolefin polymer containing from 0.01-2 weight percent based on said polymer of a quinophthalone pigment having the formula ##SPC25## or ##SPC26## wherein X represents hydrogen or halogen, Y represents halogen, Z 1 represents hydrogen, halogen, lower alkyl or lower alkoxy, Z 2 represents hydrogen, or halogen and n represents 0 or an integer of 1-4; and 0.005-5% by weight of an ultraviolet light absorbing imidazolidine compound or an ultraviolet light absorbing piperidine compound selected from the group consisting of a piperidine compound having the formula: ##SPC27## wherein R 1 and R 2 are the same or different and each represents an alkyl group or both form a saturated alicyclic ring having 5-7 carbon atoms while sharing a common carbon atom, or form a ring having the formula ##SPC28## n' is an integer of 1, 2 or 3; and R 3 represents, when n' = 1, a monovalent acyl group, an N-substituted carbamoyl group, an N-substituted thiocarbamoyl group, a monovalent group formed by removing one hydroxyl from an oxyacid; alkyl, cycloalkyl, aralkyl, aryl or a group having the formula ##SPC29## wherein R 1 and R 2 are as defined above; R 3 represents, when n' = 2, a diacyl, a dicarbamoyl, a bisthiocarbamoyl, a carbonyl group, or a divalent group formed by removing two hydroxyl groups from an oxyacid; an alkylene, an arylene, or an arylenedialkylene group; or R 3 represents, when n' = 3, a triacyl group, a tricarbamoyl group, a tristhiocarbamoyl group, a trivalent group formed by removing three hydroxyl groups from an oxyacid; an alkanetolyl group, an arylinetolyl group or an arylinetolyl trialkylene group; piperidine-4-spiro-hydantoin derivatives having the formula: ##SPC30## wherein R 1 ' and R 2 ' are the same or different and each represent an alkyl group or both form a saturated alicyclic ring having 5-7 carbon atoms while sharing a common carbon atom, or form a ring having the formula ##SPC31## wherein R 5 and R 6 are the same or different and each represents an alkyl group or both form a saturated alicyclic ring having 5-7 carbon atoms while sharing a common carbon atom; R 3 ' and R 4 ' are the same or different and each represents hydrogen, an alkyl group, a cycloalkyl group or an aryl group and can have an oxirane oxygen; a piperidine derivative or organic acid salt thereof having the formula ##SPC32## wherein R 1 and R 2 are the same or different and each represents an alkyl group or both form a saturated alicyclic ring having 5-7 carbon atoms while sharing a common carbon atom, or form a ring having the formula ##SPC33## and R 3 " and R 4 ' are the same or different and each represents cyano, aryl, alkoxycarbonyl, acyl or carbamoyl; a piperidine derivative or organic acid salt thereof having the formula ##SPC34## wherein R 1 and R 2 are as defined in formula (3) and X' represents ##EQU2## and an iminopiperidine derivative or organic acid salt thereof having the formula: ##SPC35## wherein R 1 and R 2 are as defined in formula (3), n" represents an integer of 1 or 2, and R 3 '" represents, when n" = 1, alkyl, aralkyl, cycloalkyl, aryl, arylamino, ureido, thioureido, or a group having the formula: ##SPC36## wherein R 1 and R 2 are defined in formula (3), or R 3 '" represents, when n" = 2, a straight chain or a branched chain alkylene, cycloalkylene, arylene, or a group having the formula: ##SPC37## wherein X" represents --O--, --S--, --S--S--, --NH-- or --(CH 2 ) m -- and m represents 0 or an integer from 1-6.
Claim 2
Dependent Claim 607 words
A polymer composition which comprises: a polyolefin polymer containing from 0.01-2 weight percent based on said polymer of a quinophthalone pigment having the formula ##SPC25## or ##SPC26## wherein X represents hydrogen or halogen, Y represents halogen, Z 1 represents hydrogen, halogen, lower alkyl or lower alkoxy, Z 2 represents hydrogen, or halogen and n represents 0 or an integer of 1-4; and 0.005-5% by weight of an ultraviolet light absorbing imidazolidine compound or an ultraviolet light absorbing piperidine compound selected from the group consisting of a piperidine compound having the formula: ##SPC27## wherein R 1 and R 2 are the same or different and each represents an alkyl group or both form a saturated alicyclic ring having 5-7 carbon atoms while sharing a common carbon atom, or form a ring having the formula ##SPC28## n' is an integer of 1, 2 or 3; and R 3 represents, when n' = 1, a monovalent acyl group, an N-substituted carbamoyl group, an N-substituted thiocarbamoyl group, a monovalent group formed by removing one hydroxyl from an oxyacid; alkyl, cycloalkyl, aralkyl, aryl or a group having the formula ##SPC29## wherein R 1 and R 2 are as defined above; R 3 represents, when n' = 2, a diacyl, a dicarbamoyl, a bisthiocarbamoyl, a carbonyl group, or a divalent group formed by removing two hydroxyl groups from an oxyacid; an alkylene, an arylene, or an arylenedialkylene group; or R 3 represents, when n' = 3, a triacyl group, a tricarbamoyl group, a tristhiocarbamoyl group, a trivalent group formed by removing three hydroxyl groups from an oxyacid; an alkanetolyl group, an arylinetolyl group or an arylinetolyl trialkylene group; piperidine-4-spiro-hydantoin derivatives having the formula: ##SPC30## wherein R 1 ' and R 2 ' are the same or different and each represent an alkyl group or both form a saturated alicyclic ring having 5-7 carbon atoms while sharing a common carbon atom, or form a ring having the formula ##SPC31## wherein R 5 and R 6 are the same or different and each represents an alkyl group or both form a saturated alicyclic ring having 5-7 carbon atoms while sharing a common carbon atom; R 3 ' and R 4 ' are the same or different and each represents hydrogen, an alkyl group, a cycloalkyl group or an aryl group and can have an oxirane oxygen; a piperidine derivative or organic acid salt thereof having the formula ##SPC32## wherein R 1 and R 2 are the same or different and each represents an alkyl group or both form a saturated alicyclic ring having 5-7 carbon atoms while sharing a common carbon atom, or form a ring having the formula ##SPC33## and R 3 " and R 4 ' are the same or different and each represents cyano, aryl, alkoxycarbonyl, acyl or carbamoyl; a piperidine derivative or organic acid salt thereof having the formula ##SPC34## wherein R 1 and R 2 are as defined in formula (3) and X' represents ##EQU2## and an iminopiperidine derivative or organic acid salt thereof having the formula: ##SPC35## wherein R 1 and R 2 are as defined in formula (3), n" represents an integer of 1 or 2, and R 3 '" represents, when n" = 1, alkyl, aralkyl, cycloalkyl, aryl, arylamino, ureido, thioureido, or a group having the formula: ##SPC36## wherein R 1 and R 2 are defined in formula (3), or R 3 '" represents, when n" = 2, a straight chain or a branched chain alkylene, cycloalkylene, arylene, or a group having the formula: ##SPC37## wherein X" represents --O--, --S--, --S--S--, --NH-- or --(CH 2 ) m -- and m represents 0 or an integer from 1-6.
Claim 3
Dependent Claim 118 words
The polymer composition of claim 1, wherein the imidazolidine type ultraviolet absorbing agent is a compound having the formula ##SPC38## wherein X'" represents oxygen or sulfur and R" 1 and R" 2 are the same or different and each represents hydrogen, alkyl, cycloalkyl, aryl, or a heterocyclic ring, or R" 1 and R" 2 can form a saturated alicyclic ring having 5-7 carbon atoms while sharing a common carbon atom or a ring having the same formula ##SPC39## wherein R' 5 and R' 6 are the same or different and each represents an alkyl group and Y' represents hydrogen or oxygen radical, and R"" 3 , R" 4 are the same as R" 1 and R" 2 .
Claim 4
Dependent Claim 14 words
The polymer composition of claim 1, wherein said naphthalene ring is substituted with halogen.

References Cited (Backward Citations)

US3374238A Cited
US3793331A Cited
US3788810A Cited
US3840494A Cited
US3816431A Cited
US3859293A Cited
US3790525A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-07-20 1980-01-19 1980-07-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-07-20 1984-01-19 1984-07-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-07-20 1988-01-19 1988-07-20 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag