Catalytic process for preparing unsaturated nitriles from olefins, ammonia and oxygen

Claim 1

The process for the preparation of acrylonitrile or methacrylonitrile from propene or, respectively, isobutene, by reaction, in the gas phase, with ammonia and oxygen, in the presence of a solid catalyst system, at a temperature between 350° and 550°C, said process being characterized in that the catalyst system consists of the elements tellurium, cerium and molybdenum, and of at least one element selected from the group consisting of iron, chromium and aluminum, all of said elements being chemically combined with oxygen, and the various elements being present in the atomic ratios defined by the following empirical formula: A.sub.x C.sub.y Te.sub.v Mo.sub.12 O.sub.z where A is at least one element selected from the group consisting of iron, chromium and aluminum, wherein: x = 0.3 -4; y = 1-10; v = 1-10; and z is a number indicating the amount of oxygen bound to the other elements and corresponding to the oxidation state in which they exist in the catalyst, said catalyst being obtained by mixing compounds of Te, Ce and Mo and of at least one element selected from the group consisting of Fe, Cr and Al in an aqueous medium, and then drying the mixture and heating it in the presence of air at a temperature ranging from 450° to 700°C.