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US3969313A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermoplastic composite compositions

Assignee: Asahi Kasei Corp
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Filing: 1973-06-05
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Granted: 1976-07-13
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Expires: 1993-06-05
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Abstract

Abstract A thermoplastic composite composition comprising I. about 95 to about 30 percent by weight of a thermoplastic material and Ii. about 5 to about 70 percent by weight of a polyolefin composition comprising A. about 15 to about 60 percent by weight of a polyolefin and B. about 85 to about 40 percent by weight of at least one reactive inorganic filler, Said reactive inorganic filler having been prepared by effecting reaction between A. an inorganic material substantially comprising at least one compound selected from the group consisting of metal carbonates, metal hydroxides and metal oxides, said metal being selected from the group consisting of beryllium, magnesium, calcium, strontium, barium, zinc, cadmium and aluminum, said compound having a number average particle diameter of from about 0.01 μ. to about 50 μ. and a maximum particle diameter of about 100 μ., and B. at least one unsaturated aliphatic or aromatic carboxylic acid having from 3 to 11 carbon atoms, one or two ethylenic unsaturations, one or two carboxyl groups, the proportion of said unsaturated aliphatic or aromatic carboxylic acid being from about 0.05 to 20 percent by weight of the total weight of said inorganic material, With stirring in the absence of liquid-form water in the powder state of said inorganic material at a temperature up to the temperature at which said aliphatic or aromatic carboxylic acid begins to decompose.

Inventors

  • 👤 Itsuho Aishima
  • 👤 Yukichi Takashi
  • 👤 Yoshihiko Katayama
  • 👤 Kenji Arimoto
  • 👤 Koichi Matsumoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 16:02
CPC Classifications
C; C08; C08L; C08L101/00; C08L23/00

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 241 words
A thermoplastic composite composition comprising I. about 95 to about 30 percent by weight of a thermoplastic material selected from the group consisting of polyamide, polyester, polyacetal, polycarbonate, polyphenylene oxide, polyvinylchloride and polystyrene, and Ii. about 5 to about 70 percent by weight of a polyolefin composition comprising A. about 15 to about 60 percent by weight of a polyolefin and B. about 85 to about 40 percent by weight of at least one reactive inorganic filler, said reactive inorganic filler having been prepared by effecting reaction between a. an inorganic material substantially comprising at least one compound selected from the group consisting of metal carbonates, metal hydroxides and metal oxides, said metal being selected from the group consisting of beryllium, magnesium, calcium, strontium, barium, zinc, cadmium and aluminum, said compound having a number average particle diameter of from about 0.01μ to about 50μ and a maximum particle diameter of about 100μ, and b. at least one unsaturated aliphatic or aromatic carboxylic acid having from 3 to 11 carbon atoms, one or two ethylenic unsaturations, one or two carboxyl groups, the proportion of said unsaturated aliphatic or aromatic carboxylic acid being from about 0.05 to 20 percent by weight of the total weight of said inorganic material, with stirring and removal of the evolved water in the powder state of said inorganic material at a temperature up to the temperature at which said aliphatic or aromatic carboxylic acid begins to decompose.
Claim 2
Dependent Claim 241 words
A thermoplastic composite composition comprising I. about 95 to about 30 percent by weight of a thermoplastic material selected from the group consisting of polyamide, polyester, polyacetal, polycarbonate, polyphenylene oxide, polyvinylchloride and polystyrene, and Ii. about 5 to about 70 percent by weight of a polyolefin composition comprising A. about 15 to about 60 percent by weight of a polyolefin and B. about 85 to about 40 percent by weight of at least one reactive inorganic filler, said reactive inorganic filler having been prepared by effecting reaction between a. an inorganic material substantially comprising at least one compound selected from the group consisting of metal carbonates, metal hydroxides and metal oxides, said metal being selected from the group consisting of beryllium, magnesium, calcium, strontium, barium, zinc, cadmium and aluminum, said compound having a number average particle diameter of from about 0.01μ to about 50μ and a maximum particle diameter of about 100μ, and b. at least one unsaturated aliphatic or aromatic carboxylic acid having from 3 to 11 carbon atoms, one or two ethylenic unsaturations, one or two carboxyl groups, the proportion of said unsaturated aliphatic or aromatic carboxylic acid being from about 0.05 to 20 percent by weight of the total weight of said inorganic material, with stirring and removal of the evolved water in the powder state of said inorganic material at a temperature up to the temperature at which said aliphatic or aromatic carboxylic acid begins to decompose.
Claim 3
Dependent Claim 38 words
The composite composition of claim 1 wherein the amount of said thermoplastic material is from about 90 to about 50 weight percent and the amount of said polyolefin composition is from about 10 to about 50 weight percent.
Claim 4
Dependent Claim 12 words
The composition of claim 1 wherein said thermoplastic polyamide is polyhexamethylene adipamide.
Claim 5
Dependent Claim 11 words
The composite composition of claim 1 wherein said thermoplastic is polycaprolactam.
Claim 6
Dependent Claim 13 words
The composite composition of claim 1 wherein said thermoplastic material is polyoxymethylene homopolymer.
Claim 7
Dependent Claim 13 words
The composite composition of claim 1 wherein said thermoplastic material is polyethylene terephthalate.
Claim 8
Dependent Claim 14 words
The composite composition of claim 1 wherein said thermoplastic material is poly (2,6-dimethyl-1,4-phenylene) oxide.
Claim 9
Dependent Claim 13 words
The composite composition of claim 1 wherein said thermoplastic material is polyvinyl chloride.
Claim 10
Dependent Claim 16 words
The composite composition of claim 1 wherein said thermoplastic material is the polycarbamate of 2,2-bis(4-hydroxyphenyl) propane.
Claim 11
Dependent Claim 40 words
The composite composition of claim 1 wherein said polyolefin composition comprises from about 25 to about 50 percent by weight of a polyolefin and from about 75 to about 50 percent by weight of at least one reactive inorganic filler.
Claim 12
Dependent Claim 51 words
The composite composition of claim 1 wherein said inorganic material is selected from the group consisting of calcium carbonate, magnesium carbonate, strontium carbonate, barium carbonate, beryllium oxide, magnesium oxide, calcium oxide, strontium oxide, barium oxide, zinc oxide, cadmium oxide, aluminum oxide, aluminum oxide hydrate, magnesium hydroxide, calcium hydroxide and aluminum hydroxide.
Claim 13
Dependent Claim 13 words
The composite composition of claim 1 wherein said inorganic material is calcium carbonate.
Claim 14
Dependent Claim 13 words
The composite composition of claim 1 wherein said inorganic material is magnesium hydroxide.
Claim 15
Dependent Claim 45 words
The composite composition of claim 1 wherein said aliphatic or aromatic carboxylic acid is selected from the group consisting of acrylic acid, methacrylic acid, alpha-ethylacrylic acid, alpha-chloroacrylic acid, crotonic acid, sorbic acid, maleic acid, itaconic acid, vinylacetic acid, vinylglycolic acid, angelic acid and styrylacrylic acid.
Claim 16
Dependent Claim 13 words
The composite composition of claim 1 wherein said carboxylic acid is acrylic acid.
Claim 17
Dependent Claim 21 words
The composite composition of claim 1 wherein said polyolefin is selected from the group consisting of polyethylene, polypropylene and ethylene-propylene copolymer.
Claim 18
Dependent Claim 12 words
The composite composition of claim 1 wherein said thermoplastic material is polystyrene.

References Cited (Backward Citations)

US3304197A Cited
US3375219A Cited
US3471439A Cited
US3654219A Cited
US3694403A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-07-13 1980-01-12 1980-07-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-07-13 1984-01-12 1984-07-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-07-13 1988-01-12 1988-07-13 $7700.00 Window Closed / Lapsed

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