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US3968295A Expired / Lapsed US ⏱️ 0.0 years remaining

Preparation of rubberized cord fabric

Assignee: UG Licensing Services Inc
•
Filing: 1972-02-22
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Granted: 1976-07-06
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Expires: 1992-02-22
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Abstract

Abstract Deterioration of cord dip coating with resultant loss of adhesion of subsequently applied rubber to tire cords is avoided by using a cord dip composition including latex and an acrylic ester copolymer containing acrylic acid and methylol acrylamide.

Inventors

  • 👤 Thomas S. Solomon

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 21:23
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/04; C08J5/06; C08J2321/00; Y; Y10; Y10S; Y10S156/00; Y10S156/91; Y10T; Y10T442/00; Y10T442/60; Y10T442/643; Y10T442/646

Claims Analysis

Total Claims: 30
Claim 1
Independent Claim 100 words
A process for preparing rubberized fabric free from significant deterioration in the adhesive bond of rubber to the fabric, which process comprises 1. dipping the fabric in an aqueous dispersion containing an adhesive latex of a diene polymer and a dispersion of an acrylic copolymer having most of the links in the polymer chain of the configuration ##EQU1## in which R is H, methyl, ethyl, Cl or CN, and in which X in a majority of the links is 0-alkyl where the alkyl group has from 1 to 4 carbon atoms, X in a minority of links is OH, 2.
Claim 2
Dependent Claim 100 words
A process for preparing rubberized fabric free from significant deterioration in the adhesive bond of rubber to the fabric, which process comprises 1. dipping the fabric in an aqueous dispersion containing an adhesive latex of a diene polymer and a dispersion of an acrylic copolymer having most of the links in the polymer chain of the configuration ##EQU1## in which R is H, methyl, ethyl, Cl or CN, and in which X in a majority of the links is 0-alkyl where the alkyl group has from 1 to 4 carbon atoms, X in a minority of links is OH, 2.
Claim 3
Dependent Claim 4 words
drying the fabric, and
Claim 4
Dependent Claim 4 words
drying the fabric, and
Claim 5
Dependent Claim 22 words
subsequently rubberizing the fabric. 2. A process as in claim 1, in which the fabric is an array of parallel textile cords.
Claim 6
Dependent Claim 33 words
A process as in claim 1, in which the latex is in substantial part a dispersion of a polymer made predominantly from butadiene and to a minor extent from styrene and vinyl pyridine.
Claim 7
Dependent Claim 21 words
A process as in claim 1, in which the dip composition contains a heat setting resin reactive with the acrylic resin.
Claim 8
Dependent Claim 18 words
A process as in claim 4, in which the added heat setting resin is a resorcinol formaldehyde resin.
Claim 9
Dependent Claim 37 words
A process as in claim 1, in which the acrylic copolymer is made predominantly from methyl methacrylate and to a minor extent of a material producing polymer links of the designated configuration in which X is OH.
Claim 10
Dependent Claim 29 words
A process as in claim 6, in which some of the polymer links are of the designated configuration in which X is NH-Y where Y is H or alkylol.
Claim 11
Dependent Claim 16 words
A process as in claim 6, in which the dip composition contains a soluble resorcinol-formaldehyde resin.
Claim 12
Dependent Claim 43 words
A process as in claim 1, in which X in a majority of the acrylic copolymer links is O--CH 3 , X in a minority of the links is OH, and X in a further minority of the links is NH--CH 2 --OH.
Claim 13
Dependent Claim 41 words
A process as in claim 1, in which the acrylic copolymer is made predominantly from methyl methacrylate, to a minor extent from acrylic or methacrylic acid, and to an extent at least equivalent to that of the acid from N-methylol acrylamide.
Claim 14
Dependent Claim 33 words
A process as in claim 7, in which the latex is in substantial part a dispersion of a polymer made predominantly from butadiene and to a minor extent from styrene and vinyl pyridine.
Claim 15
Dependent Claim 16 words
A process as in claim 11, in which the dip composition contains a soluble resorcinol-formaldehyde resin.
Claim 16
Dependent Claim 15 words
A process as in claim 1, in which the dip composition contains emulsified paraffin wax.
Claim 17
Dependent Claim 15 words
A process as in claim 12, in which the dip composition contains emulsified paraffin wax.
Claim 18
Dependent Claim 17 words
A process as in claim 2, in which the dipping and drying are carried out under tension.
Claim 19
Dependent Claim 17 words
A process as in claim 11, in which the dipping and drying are carried out under tension.
Claim 20
Dependent Claim 27 words
A process as in claim 1 in which not less than about 5% of the polymer links are of the designated configuration in which X is OH.
Claim 21
Dependent Claim 27 words
A process as in claim 7 in which not less than about 5% of the polymer links are of the designated configuration in which X is OH.
Claim 22
Dependent Claim 121 words
A process for preparing rubberized cord fabric free from significant deterioration in the adhesive bond of rubber to the fabric, which process comprises 1. dipping an array of parallel cords under tension in an aqueous alkaline dispersion containing a. an adhesive latex of a diene polymer consisting in substantial part of a polymer made predominantly from butadiene and to a minor extent from styrene and vinyl pyridine, b. an alkali-soluble acrylic copolymer made predominantly from methyl methacrylate, to a minor extent from acrylic or methacrylic acid, and to an extent at least equivalent to that of the acid from N-methylol acrylamide, c. a soluble resorcinol-formaldehyde resin, and d. emulsified paraffin wax 2. drying under tension, and 3. subsequently rubberizing the fabric.
Claim 23
Dependent Claim 121 words
A process for preparing rubberized cord fabric free from significant deterioration in the adhesive bond of rubber to the fabric, which process comprises 1. dipping an array of parallel cords under tension in an aqueous alkaline dispersion containing a. an adhesive latex of a diene polymer consisting in substantial part of a polymer made predominantly from butadiene and to a minor extent from styrene and vinyl pyridine, b. an alkali-soluble acrylic copolymer made predominantly from methyl methacrylate, to a minor extent from acrylic or methacrylic acid, and to an extent at least equivalent to that of the acid from N-methylol acrylamide, c. a soluble resorcinol-formaldehyde resin, and d. emulsified paraffin wax 2. drying under tension, and 3. subsequently rubberizing the fabric.
Claim 24
Dependent Claim 28 words
A process as in claim 19 in which the acrylic copolymer is made to a minor extent but not less than about 5% from acrylic or methacrylic acid.
Claim 25
Dependent Claim 90 words
A rubberized fabric, consisting of textile material, which is coated with a thin film of a composition containing an adhesive diene polymer and an acrylic copolymer having most of the links in the polymer chain of the configuration ##EQU2## in which R is H, methyl, ethyl, Cl or CN, and in which X in a majority of the links is O-alkyl where the alkyl group has from 1 to 4 carbon atoms and X in a minority of the groups is OH, and the coated fabric is embedded in rubber.
Claim 26
Dependent Claim 90 words
A rubberized fabric, consisting of textile material, which is coated with a thin film of a composition containing an adhesive diene polymer and an acrylic copolymer having most of the links in the polymer chain of the configuration ##EQU2## in which R is H, methyl, ethyl, Cl or CN, and in which X in a majority of the links is O-alkyl where the alkyl group has from 1 to 4 carbon atoms and X in a minority of the groups is OH, and the coated fabric is embedded in rubber.
Claim 27
Dependent Claim 41 words
A rubberized fabric as in claim 21 in which the textile material is a fabric of parallel cords, and in which the diene polymer is a polymer made predominantly from butadiene and to a minor extent from styrene and vinyl pyridine.
Claim 28
Dependent Claim 17 words
A rubberized fabric as in claim 22 in which the coating composition contains a resorcinol formaldehyde resin.
Claim 29
Dependent Claim 28 words
A rubberized fabric as in claim 21 in which not less than about 5% of the polymer links are of the designated configuration in which X is OH.
Claim 30
Dependent Claim 28 words
A rubberized fabric as in claim 23 in which not less than about 5% of the polymer links are of the designated configuration in which X is OH.

References Cited (Backward Citations)

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US3284394A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-07-06 1980-01-05 1980-07-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-07-06 1984-01-05 1984-07-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-07-06 1988-01-05 1988-07-06 $7700.00 Window Closed / Lapsed

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