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US3968064A Expired / Lapsed US ⏱️ 0.0 years remaining

Smoke retardant vinyl chloride and vinylidene chloride polymer compositions

Assignee: Geon Co
•
Filing: 1976-01-15
•
Granted: 1976-07-06
•
Expires: 1996-01-15
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Abstract

Abstract Smoke retardant vinyl chloride and vinylidene chloride polymer compositions are obtained by including therein a synergistic mixture of (A) at least one nickel compound selected from the group consisting of NiCO 3 , NiO, Ni 2 Si, NiS, and nickel stearate, and (B) at least one vanadium compound selected from the group consisting of NH 4 VO 3 , Mg(VO 3 ) 2 , NaVO 3 , VOSO 4 , V 2 O 4 , V 2 O 5 and vanadium oxyacetylacetonate. Substantial smoke retardation is also obtained by including the above nickel compounds or vanadium compounds individually in the vinyl chloride or vinylidene chloride polymer compositions. Hydrates of the additive compounds may also be used.

Inventors

  • 👤 Elmer Douglas Dickens, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 12:26
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/0091; C08K3/00; C08K3/01; C08K3/016; C08K3/10; C08K3/11; C08K3/18; C08K3/20; C08K3/22; C08K3/24; C08K3/26; C08K3/30; C08K3/34; C08K5/04; C08K5/07; C08K5/09; C08K5/098

Claims Analysis

Total Claims: 27
Claim 1
Independent Claim 109 words
A smoke retardant composition comprising a vinyl chloride or vinylidene chloride polymer together with (A) at least one nickel compound selected from the group consisting of NiCO 3 , NiO, Ni 2 Si, and nickel stearate and (B) at least one vanadium compound selected from the group consisting of NH 4 VO 3 , Mg(VO 3 ) 2 , NaVO 3 , VOSO 4 , V 2 O 5 , and vanadium oxyacetylacetonate, said compounds (A) and (B) being compounds or hydrates thereof, and said compounds (A) and (B) being present in a total amount from about 0.25 to about 20 weight parts per 100 weight parts of polymer.
Claim 2
Dependent Claim 109 words
A smoke retardant composition comprising a vinyl chloride or vinylidene chloride polymer together with (A) at least one nickel compound selected from the group consisting of NiCO 3 , NiO, Ni 2 Si, and nickel stearate and (B) at least one vanadium compound selected from the group consisting of NH 4 VO 3 , Mg(VO 3 ) 2 , NaVO 3 , VOSO 4 , V 2 O 5 , and vanadium oxyacetylacetonate, said compounds (A) and (B) being compounds or hydrates thereof, and said compounds (A) and (B) being present in a total amount from about 0.25 to about 20 weight parts per 100 weight parts of polymer.
Claim 3
Dependent Claim 25 words
A composition of claim 1 wherein said polymer contains copolymerized therewith up to about 50% by weight of at least one other olefinically unsaturated monomer.
Claim 4
Dependent Claim 21 words
A composition of claim 2 wherein said polymer contains copolymerized therewith up to about 20% by weight of said other monomer.
Claim 5
Dependent Claim 46 words
A composition of claim 3 wherein said other monomer is selected from the group consisting of 1-olefins containing from 2 to 12 carbon atoms, vinyl esters, α,β-olefinically unsaturated carboxylic acids and esters thereof, amides of α,β-olefinically unsaturated carboxylic acids, and esters of fumaric and maleic acid.
Claim 6
Dependent Claim 20 words
A composition of claim 4 wherein said compound has an average particle size from about 0.1 to about 200 microns.
Claim 7
Dependent Claim 22 words
A composition of claim 4 wherein said compound (A) is NiCO 3 and said compound (B) is V 2 O 4 .
Claim 8
Dependent Claim 21 words
A composition of claim 4 wherein said compound (A) is NiO and said compound (B) is NH 4 VO 3 .
Claim 9
Dependent Claim 21 words
A composition of claim 4 wherein said compound (A) is NiO and said compound (B) is Mg(VO 3 ) 2 .
Claim 10
Dependent Claim 19 words
A composition of claim 4 wherein said compound (A) is NiO and said compound (B) is NaVO 3 .
Claim 11
Dependent Claim 21 words
A composition of claim 4 wherein said compound (A) is NiO and said compound (B) is VOSO 4 .2H 2 O.
Claim 12
Dependent Claim 21 words
A composition of claim 4 wherein said compound (A) is NiO and said compound (B) is V 2 O 4 .
Claim 13
Dependent Claim 21 words
A composition of claim 4 wherein said compound (A) is NiO and said compound (B) is V 2 O 5 .
Claim 14
Dependent Claim 18 words
A composition of claim 4 wherein said compound (A) is NiO and said compound (B) is vanadium oxyacetylacetonate.
Claim 15
Dependent Claim 21 words
A composition of claim 4 wherein said compound (A) is NiS and said compound (B) is Mg(VO 3 ) 2 .
Claim 16
Dependent Claim 23 words
A composition of claim 4 wherein said compound (A) is Ni 2 Si and said compound (B) is V 2 O 5 .
Claim 17
Dependent Claim 20 words
A composition of claim 4 wherein said compound (A) is nickel stearate and said compound (B) is NaVO 3 .
Claim 18
Dependent Claim 64 words
A smoke retardant composition comprising a vinyl chloride or vinylidene chloride polymer together with at least one compound selected from the group consisting of NH 4 VO 3 , Mg(VO 3 ) 2 , NaVO 3 , vanadium oxyacetylacetonate and hydrates thereof, said compound being present in a total amount from about 0.25 to about 20 weight parts per 100 weight parts of polymer.
Claim 19
Dependent Claim 64 words
A smoke retardant composition comprising a vinyl chloride or vinylidene chloride polymer together with at least one compound selected from the group consisting of NH 4 VO 3 , Mg(VO 3 ) 2 , NaVO 3 , vanadium oxyacetylacetonate and hydrates thereof, said compound being present in a total amount from about 0.25 to about 20 weight parts per 100 weight parts of polymer.
Claim 20
Dependent Claim 25 words
A composition of claim 17 wherein said polymer contains copolymerized therewith up to about 50% by weight of at least one other olefinically unsaturated monomer.
Claim 21
Dependent Claim 21 words
A composition of claim 18 wherein said polymer contains copolymerized therewith up to about 20% by weight of said other monomer.
Claim 22
Dependent Claim 46 words
A composition of claim 19 wherein said other monomer is selected from the group consisting of 1-olefins containing from 2 to 12 carbon atoms, vinyl esters, α,β-olefinically unsaturated carboxylic acids and esters thereof, amides of α,β-olefinically unsaturated carboxylic acids, and esters of fumaric and maleic acid.
Claim 23
Dependent Claim 20 words
A composition of claim 20 wherein said compound has an average particle size from about 0.1 to about 200 microns.
Claim 24
Dependent Claim 14 words
A composition of claim 20 wherein said compound is NH 4 VO 3 .
Claim 25
Dependent Claim 14 words
A composition of claim 20 wherein said compound is Mg(VO 3 ) 2 .
Claim 26
Dependent Claim 12 words
A composition of claim 20 wherein said compound is NaVO 3 .
Claim 27
Dependent Claim 11 words
A composition of claim 20 wherein said compound is vanadium oxyacetylacetonate.

References Cited (Backward Citations)

US3870679A Cited
US3929722A Cited
US3900441A Cited
US3903028A Cited
US3878167A Cited
US3883482A Cited
US3914201A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-07-06 1980-01-05 1980-07-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-07-06 1984-01-05 1984-07-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-07-06 1988-01-05 1988-07-06 $7700.00 Window Closed / Lapsed

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