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US3967982A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of doping a semiconductor layer

Assignee: Siemens AG
•
Filing: 1975-07-11
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Granted: 1976-07-06
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Expires: 1995-07-11
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Abstract

Abstract A semiconductor layer, such as an epitaxial layer on a suitable substrate is subjected to controlled bombardment by neutrons whereby the atoms of the semiconductor layer are converted via nuclear reaction into doping material atoms.

Inventors

  • 👤 Heinz-Herbert Arndt
  • 👤 Joachim Burtscher
  • 👤 Gustav Fischer
  • 👤 Ernst Haas
  • 👤 Joachim Martin
  • 👤 Gunter Raab
  • 👤 Manfred Schnoeller

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 13:31
CPC Classifications
H; H10; H10P; H10P76/00; H10P76/40; H10P34/00; H10P34/20; Y; Y10; Y10S; Y10S148/00; Y10S148/165

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 42 words
A method of doping a semiconductor layer arranged on a substrate with a dopant substance comprising: subjecting said semiconductor layer to controlled bombardment by neutrons so that atoms of said semiconductor layer are converted by a nuclear reaction into dopant substance atoms.
Claim 2
Independent Claim 42 words
A method of doping a semiconductor layer arranged on a substrate with a dopant substance comprising: subjecting said semiconductor layer to controlled bombardment by neutrons so that atoms of said semiconductor layer are converted by a nuclear reaction into dopant substance atoms.
Claim 3
Dependent Claim 41 words
A method as defined in claim 1 wherein said semiconductor layer is composed of silicon and said dopant substance is composed of phosphorus so that the nuclear reaction: .sub.14 Si.sup.30 + n → .sub.14 Si.sup.31 +γ→ .sub.15 P.sup.31 +β.sup.- takes place.
Claim 4
Dependent Claim 65 words
A method as defined in claim 1 wherein said semiconductor layer is composed of an A III B V compound and a nuclear reaction selected from the group consisting of: .sub.31 Ga.sup.69 + n → .sub.31 Ga.sup.70 → .sub.32 Ge.sup.70 β.sup.-; .sub.31 Ga.sup.71 + n → .sub.31 Ga.sup.72 → .sub.32 Ge.sup.72 +β.sup.-; .sub.33 As.sup.75 + n → .sub.33 As.sup.76 → .sub.34 Se.sup.76 +β.sup.- takes place.
Claim 5
Dependent Claim 47 words
A method as defined in claim 1 wherein said semiconductor layer is composed of gallium phosphide and the nuclear reactions: Ga.sup.69 + n → Ga.sup.70 → Ge.sup.70 +β.sup.-; Ga.sup.71 + n → Ga.sup.72 → Ge.sup.72 +β.sup.-; and P.sup.31 + n → P.sup.32 → S.sup.32 +β.sup.- take place.
Claim 6
Dependent Claim 41 words
A method as defined in claim 1 wherein said semiconductor layer is composed of Ge and said dopant substance is composed of As so that the nuclear reaction: .sub.32 Ge.sup.74 + n - .sub.32 Ge.sup.75 - .sub.33 As.sup.75 +β.sup.- takes place.
Claim 7
Dependent Claim 13 words
A method as defined in claim 1 wherein said neutrons are thermal neutrons.
Claim 8
Dependent Claim 23 words
A method as defined in claim 6 wherein said thermal neutrons have an energy in the range of about 0.025 to 0.3 eV.
Claim 9
Dependent Claim 17 words
A method as defined in claim 1 wherein said semiconductor layer is epitaxially deposited on a substrate.
Claim 10
Dependent Claim 14 words
A method as defined in claim 8 wherein said substrate is a silicon base.
Claim 11
Dependent Claim 32 words
A method as defined in claim 9 wherein said silicon base is composed of silicon doped with a material selected from the group consisting of Sb, As P, B and mixtures thereof.
Claim 12
Dependent Claim 20 words
A method as defined in claim 9 wherein said silicon base is composed of silicon doped with B 11 .
Claim 13
Dependent Claim 19 words
A method as defined in claim 8 wherein said substrate is a sapphire (Al 2 O 3 ) base.
Claim 14
Dependent Claim 19 words
A method as defined in claim 8 wherein said substrate is a spinel (MgAl 2 O 4 ) base.
Claim 15
Dependent Claim 54 words
A method as defined in claim 1 wherein a masking layer having at least one window therein is applied onto a free surface of said semiconductor layer prior to subjecting such layer to controlled bombardment by neutrons so that localized doping of the surface area of said semiconductor layer below said window takes place.
Claim 16
Dependent Claim 15 words
A method as defined in claim 14 wherein said masking layer is a cadmium foil.
Claim 17
Dependent Claim 16 words
A method as defined in claim 14 wherein said masking layer is a gadolinium lacquer layer.

References Cited (Backward Citations)

GB886232A Cited
US3733222A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-07-06 1980-01-05 1980-07-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-07-06 1984-01-05 1984-07-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-07-06 1988-01-05 1988-07-06 $7700.00 Window Closed / Lapsed

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