US3966879A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Removal of sulfur oxides and particulate matter from waste gas streams
Assignee: Shell USA Inc
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Filing: 1974-05-06
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Granted: 1976-06-29
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Expires: 1994-05-06
Abstract
Abstract A process for the removal of particulate matter and sulfur oxides from waste gases is disclosed which comprises cross-current contacting of the waste gas stream with a moving bed of supported, copper-containing acceptor in a first zone, thereby accepting the sulfur oxides and filtering out the particulate matter, removing in subsequent separate zones the particulate matter and the sulfur oxides from the acceptor and, optionally, reactivating the acceptor in a subsequent zone before introducing it back into the first zone for further removal of sulfur oxides and particulate matter. An apparatus suitable for carrying out the process is also described.
Inventors
- 👤 Willem Groenendaal
- 👤 Friedrich C. Taubert
- 👤 Jaap E. Naber
- 👤 Gijsbertus A. Bekker
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 20:08
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/50; B01D53/508
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
242 words
A process for removing sulfur oxides and particulate matter from waste gas streams containing sulfur oxides and particulate matter which comprises: A. contacting the waste gas stream under oxidative conditions in a sulfur oxide and particulate matter removal zone with a solid acceptor comprising copper or a copper compound or mixtures thereof supported on a particulate carrier, said contact being established by passing the waste gas at a temperature of from about 300° to 500°C. cross-currently through a moving bed of the solid acceptor, thereby accepting the sulfur oxide on said acceptor and filtering out the particulate matter to afford an acceptor loaded with sulfur oxides and particulate matter and a waste gas stream substantially free of both sulfur oxides and particulate matter; B. removing the particulate matter from the loaded acceptor in a first separation zone wherein the acceptor loaded with both sulfur oxides and particulate matter is stripped of particulate matter by transporting the loaded acceptor through a stream of an inert stripping gas; C. separating the sulfur oxides from the acceptor product of the first separation zone by contacting the acceptor with a reducing gas at a temperature between 300°-500°C in a second separation zone whereby the sulfur oxides bound to the acceptor are released as SO 2 gas and D. returning the acceptor product of the second separation zone into cross-current contact with said waste gases under oxidative conditions in the sulfur oxide and particulate matter removal zone.
Claim 2
Dependent Claim
242 words
A process for removing sulfur oxides and particulate matter from waste gas streams containing sulfur oxides and particulate matter which comprises: A. contacting the waste gas stream under oxidative conditions in a sulfur oxide and particulate matter removal zone with a solid acceptor comprising copper or a copper compound or mixtures thereof supported on a particulate carrier, said contact being established by passing the waste gas at a temperature of from about 300° to 500°C. cross-currently through a moving bed of the solid acceptor, thereby accepting the sulfur oxide on said acceptor and filtering out the particulate matter to afford an acceptor loaded with sulfur oxides and particulate matter and a waste gas stream substantially free of both sulfur oxides and particulate matter; B. removing the particulate matter from the loaded acceptor in a first separation zone wherein the acceptor loaded with both sulfur oxides and particulate matter is stripped of particulate matter by transporting the loaded acceptor through a stream of an inert stripping gas; C. separating the sulfur oxides from the acceptor product of the first separation zone by contacting the acceptor with a reducing gas at a temperature between 300°-500°C in a second separation zone whereby the sulfur oxides bound to the acceptor are released as SO 2 gas and D. returning the acceptor product of the second separation zone into cross-current contact with said waste gases under oxidative conditions in the sulfur oxide and particulate matter removal zone.
Claim 3
Dependent Claim
52 words
The process according to claim 1, wherein the removal of particulate matter from the loaded acceptor in the first separation zone is effected by transporting the acceptor in relatively thin layers over the perforated plates and by passing the inert gas through the acceptor layers via the perforations of the said plates.
Claim 4
Dependent Claim
29 words
The process according to claim 2 wherein the perforated plates are positioned under a slope from horizontal and the acceptor moves over the plate by means of gravitational forces.
Claim 5
Dependent Claim
42 words
The process according to claim 1 wherein the acceptor product of the second separation zone is reactivated by contacting it with an oxidizing agent in an activation zone prior to introducing said acceptor into the sulfur oxide and particulate matter removal zone.
Claim 6
Dependent Claim
15 words
The process according to claim 4 wherein the oxidizing agent employed is an oxygen-containing gas.
Claim 7
Dependent Claim
48 words
The process according to claim 1 wherein the thickness of the moving bed of acceptor particles in cross-current contact with the waste gas stream in the sulfur oxide and particulate matter removal zone is between about 25 and 100 cm taken in the direction of waste gas flow.
Claim 8
Dependent Claim
37 words
The process according to claim 6 wherein the velocities of the waste gas stream and the moving bed in cross-current contact are between about 1 and 7 m/sec and from about 0.4 to about 2.5 mm/sec, respectively.
Claim 9
Dependent Claim
44 words
The process according to claim 1 wherein the acceptor product of the second separation zone is stripped with an inert gas prior to being returned into cross-current contact with the waste gases under oxidative conditions in the sulfur oxide and particulate matter romoval zone.
Claim 10
Dependent Claim
51 words
The process according to claim 8 wherein the inert gas stripping of the acceptor product of the second separation zone is carried out by transporting the acceptor in relatively thin layers over perforated plates and by passing the inert gas through the acceptor layers via the perforations of the said plates.
Claim 11
Dependent Claim
29 words
The process according to claim 9 wherein the perforated plates are positioned under a slope from horizontal and the acceptor moves over the plate by means of gravitational force.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-06-29 | 1979-12-29 | 1980-06-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-06-29 | 1983-12-29 | 1984-06-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-06-29 | 1987-12-29 | 1988-06-29 | $7700.00 | Window Closed / Lapsed |