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US3966650A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyether urethane foam

Assignee: OSI Specialties Inc
•
Filing: 1974-10-07
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Granted: 1976-06-29
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Expires: 1994-10-07
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Abstract

Abstract A process for producing high resilience polyether urethane foam using a cyanoalkoxy-alkyl modified siloxane fluid; the foams derived therefrom; a solvent-solution of said siloxane; and cyanoalkoxy-alkyl modified siloxane fluids per se.

Inventors

  • 👤 Bela Prokai

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 19:37
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/0061; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/0834; C07F7/0838; C07F7/0872; C07F7/0876; C07F7/0878; C07F7/0879; C08G; C08G77/00; C08G77/04; C08G77/045; C08J2375/00; C08J2375/04; C08J2375/08; C08J2483/00; Y; Y10; Y10S; Y10S516/00; Y10S516/01

Claims Analysis

Total Claims: 28
Claim 1
Independent Claim 282 words
A process for producing high resilience polyether urethane foam, said process comprising foaming and reacting a mixture comprising: I. organic polyol selected from the group consisting of (A) a polyether triol containing at least 40 mole per cent primary hydroxyl groups and having a molecular weight from about 2,000 to about 8,000 and (B) a mixture of said polyether triol and another polyether having an average of at least two hydroxyl groups, said polyether triol of said mixture amounting to at least 40 weight per cent of the total polyol content; Ii. organic polyisocyanate, said organic polyol and said polyisocyanate being present in the mixture in a major amount and in the relative amount required to produce the urethane; Iii. blowing agent in a minor amount sufficient to foam the reaction mixture; Iv. a catalytic amount of catalyst for the production of the urethane; and V. a cyanoalkoxy-alkyl modified siloxane fluid having the average formula (X).sub.z R.sub.3-z SiO(R.sub.2 SiO).sub.x [(X) (R)SiO].sub.y SiR.sub.3-z X.sub.z wherein x has a value of 2 to 6 inclusive; y has a value of 0 to 6 inclusive; z has a value of 0 to 1 inclusive; R is a lower alkyl or phenyl radical; and X is a cyanoalkoxy-alkyl radical having the formula --(O) n R'OR"CN where n has a value of 0 or 1, R' is an alkylene radical having from 3 to 8 carbon atoms and R" is an alkylene radical having from 2 to 4 carbon atoms said siloxane containing at least one of said cyanoalkoxy-alkyl radicals and having an average molecular weight in the range of about 400 to about 2000, in an amount sufficient to stabilize the foam against voids and shrinkage.
Claim 2
Dependent Claim 282 words
A process for producing high resilience polyether urethane foam, said process comprising foaming and reacting a mixture comprising: I. organic polyol selected from the group consisting of (A) a polyether triol containing at least 40 mole per cent primary hydroxyl groups and having a molecular weight from about 2,000 to about 8,000 and (B) a mixture of said polyether triol and another polyether having an average of at least two hydroxyl groups, said polyether triol of said mixture amounting to at least 40 weight per cent of the total polyol content; Ii. organic polyisocyanate, said organic polyol and said polyisocyanate being present in the mixture in a major amount and in the relative amount required to produce the urethane; Iii. blowing agent in a minor amount sufficient to foam the reaction mixture; Iv. a catalytic amount of catalyst for the production of the urethane; and V. a cyanoalkoxy-alkyl modified siloxane fluid having the average formula (X).sub.z R.sub.3-z SiO(R.sub.2 SiO).sub.x [(X) (R)SiO].sub.y SiR.sub.3-z X.sub.z wherein x has a value of 2 to 6 inclusive; y has a value of 0 to 6 inclusive; z has a value of 0 to 1 inclusive; R is a lower alkyl or phenyl radical; and X is a cyanoalkoxy-alkyl radical having the formula --(O) n R'OR"CN where n has a value of 0 or 1, R' is an alkylene radical having from 3 to 8 carbon atoms and R" is an alkylene radical having from 2 to 4 carbon atoms said siloxane containing at least one of said cyanoalkoxy-alkyl radicals and having an average molecular weight in the range of about 400 to about 2000, in an amount sufficient to stabilize the foam against voids and shrinkage.
Claim 3
Dependent Claim 26 words
A process as defined in claim 1 wherein the catalyst is an amine catalyst, or a mixture of an organic metal catalyst and an amine catalyst.
Claim 4
Dependent Claim 25 words
A process as defined in claim 1 wherein the blowing agent is selected from the group consisting of water, a fluorocarbon compound, and mixtures thereof.
Claim 5
Dependent Claim 26 words
A process as defined in claim 1 wherein the polyisocyanate is selected from the group consisting of tolylene diisocyanate, polymethylene polyphenyl polymeric isocyanate, and mixtures thereof.
Claim 6
Dependent Claim 51 words
A process as defined in claim 1 wherein a minor amount of an additional ingredient selected from the group consisting of a flame retardant agent, an organic solvent for the amine catalyst, an organic solvent for the cyanoalkoxy-alkyl modified siloxane fluid, and mixtures thereof are also present in the reaction mixture.
Claim 7
Dependent Claim 24 words
A process as defined in claim 1 wherein the cyanoalkoxy-alkyl modified siloxane fluid is employed in the form of a siloxane fluid-organic solvent solution.
Claim 8
Dependent Claim 34 words
A process as defined in claim 6 wherein the organic solvent for the siloxane fluid is an organic polyether selected from the group consisting of monool, diol and triol hydroxy compounds, and mixtures thereof.
Claim 9
Dependent Claim 14 words
A process as defined in claim 7 wherein the organic solvent is polyether triol.
Claim 10
Dependent Claim 22 words
A process as defined in claim 6 wherein a catalyst is present as an additional ingredient in the siloxane fluid-organic solvent solution.
Claim 11
Dependent Claim 35 words
A process as defined in claim 1 wherein the organic polyol polyether triol contains from about 60 to 90 mole per cent primary hydroxyl groups and has a molecular weight from about 4,000 to 7,000.
Claim 12
Dependent Claim 49 words
A process as defined in claim 10 wherein the organic polyol is a mixture of said polyether triol and another polyether having an average of at least two hydroxyl groups said polyether triol of said mixture amounting to at least 40 weight per cent of the total polyol content.
Claim 13
Dependent Claim 16 words
A process as defined in claim 10 wherein the other polyether is a graft acrylonitrile/polyether triol.
Claim 14
Dependent Claim 56 words
A process as defined in claim 10 wherein the cyanoalkoxy-alkyl modified siloxane fluid has an average molecular weight of about 500 to 1000; wherein R is a lower alkyl radical, X has a value of 2 to 4 inclusive, y has a value of 1 to 4 inclusive, is n is 0 and z is 0.
Claim 15
Dependent Claim 11 words
A process as defined in claim 13 wherein R is methyl.
Claim 16
Dependent Claim 13 words
A process as defined in claim 14 wherein X is a 3-(2-cyanoethoxy)propyl radical.
Claim 17
Dependent Claim 46 words
A process as defined in claim 10 wherein the cyanoalkoxy-alkyl modified siloxane fluid has an average molecular weight of about 500 to 1000; wherein R is a lower alkyl radical, x has a value of 2 to 4 inclusive, n is 0 and z is 1.
Claim 18
Dependent Claim 13 words
A process as defined in claim 16 wherein R is a methyl radical.
Claim 19
Dependent Claim 232 words
A process for producing high resilience polyether urethane foam, said process comprising foaming and reacting a mixture comprising: I. an organic polyol mixture of a polyether triol, said triol containing 60 to 90 mole per cent primary hydroxyl groups and having a molecular weight from about 4,000 to 7,000 and another polyether having an average of at least two hydroxyl groups, and polyether triol of said mixture amounting to at least 40 weight per cent of the total polyol content; Ii. a polyisocyanate selected from the group consisting of tolylene diisocyanate, polymethylene polyphenyl polymeric isocyanate, and mixtures thereof, said isocyanate being present in an amount from 90 to 105 percent of the amount required to provide the stoichiometric amount of isocyanate groups required to react with the hydroxyl groups of the organic polyol mixture and any water present as a blowing agent; Iii. from 2 to 20 parts by weight per 100 parts by weight of the organic polyol mixture starting material of at least one blowing agent selected from the group consisting of water and fluorocarbon blowing agents; Iv. a catalytic amount of an amine catalyst or a mixture of an organic metal catalyst and an amine catalyst; and V. about 0.08 to about 0.6 parts by weight per 100 parts by weight of the organic polyol mixture starting material of a cyanoalkoxy-alkyl modified siloxane fluid as defined in claim 13.
Claim 20
Dependent Claim 13 words
A process as defined in claim 18 wherein R is a methyl radical.
Claim 21
Dependent Claim 13 words
A process as defined in claim 19 wherein X is a 3-(2-cyanoethoxy)propyl radical.
Claim 22
Dependent Claim 24 words
A process as defined in claim 18 wherein the cyanoalkoxy-alkyl modified siloxane fluid has the average formula ##EQU2## wherein Me is a methyl radical.
Claim 23
Dependent Claim 24 words
A process as defined in claim 18 wherein the cyanoalkoxy-alkyl modified siloxane fluid has the average formula ##EQU3## wherein Me is a methyl radical.
Claim 24
Dependent Claim 24 words
A process as defined in claim 18 wherein the cyanoalkoxy-alkyl modified siloxane fluid has the average formula ##EQU4## wherein Me is a methyl radical.
Claim 25
Dependent Claim 24 words
A process as defined in claim 18 wherein the cyanoalkoxy-alkyl modified siloxane fluid is used in the form of a siloxane fluid-organic solvent solution.
Claim 26
Dependent Claim 34 words
A process as defined in claim 24 wherein the organic solvent for the siloxane fluid is an organic polyether selected from the group consisting of mono-ol, diol and triol hydroxy compounds, and mixtures thereof.
Claim 27
Dependent Claim 14 words
A process as defined in claim 25 wherein the organic solvent is polyether triol.
Claim 28
Dependent Claim 22 words
A process as defined in claim 24 wherein a catalyst is present as an additional ingredient in the siloxane fluid-organic solvent solution.

References Cited (Backward Citations)

US2872435A Cited
US3564037A Cited
US3790612A Cited
US3741917A Cited
US3846462A Cited
BE809978A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-29 1979-12-29 1980-06-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-29 1983-12-29 1984-06-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-29 1987-12-29 1988-06-29 $7700.00 Window Closed / Lapsed

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