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US3966641A Expired / Lapsed US ⏱️ 0.0 years remaining

Sorpitional carrier materials and a process for the preparation thereof

Assignee: Orszagos Erc- Es Asvanybanyak
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Filing: 1975-02-27
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Granted: 1976-06-29
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Expires: 1995-02-27
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Abstract

Abstract The invention relates to a porous carrier rock-based sorptional carrier containing at least one porous carrier rock in an amount not exceeding 95 % by weight, and 5 to 30 % by weight of montmorillonite and optionally illite and/or kaolinite and/or a co-mineral of the latter, with the proviso that a montmorillonite content of at least 5 % by weight is provided for. These carriers have a multiple sorptional pore space, possess a sorption capacity of at least 50 %, and are quasi-spherical in shape. The above carriers can be prepared, in accordance with the invention, as follows: at least one porous carrier rock is suspended in water either directly or after pre-crushing, then, if not contained originally in the carrier rock in the appropriate amount and ratio, 5 to 30 % by weight, calculated for the amount of the carrier rock, of montmorillonite and optionally illite and/or kaolinite and/or a co-mineral of the latter is added to the suspension as plastic clay mineral also capable of binding in wet state, with the proviso that a montmorillonite content of at least 5 % by weight is provided for the carrier rock, thereafter the total dry material content of the suspension is adjusted to at least 30 % by weight, the suspension is homogenized, is subjected to spray-drying, and, if desired, the obtained particles are fired at 900° to 1300°C. The carriers according to the invention can be used to great advantages in combination with biologically active substances, such as herbicidal, pesticidal, etc. agents.

Inventors

  • 👤 Kalman Csatar
  • 👤 Istvan Soha

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 16:33
CPC Classifications
A; A01; A01N; A01N25/00; A01N25/08; B; B01; B01J; B01J20/00; B01J20/02; B01J20/10

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 114 words
A porous carrier rock-based sorptional carrier consisting of at least one porous carrier rock selected from the group which consists of silicic earth, pumices, tuffs, bubble-porous lava rocks, expanded perlite, vermiculite, chalks, other porous biogeneous limes, and porous sand rocks in an amount not exceeding 95% by weight and 5 to 30% by weight of a clay mineral in a particle size of about 0.1 to 1μ and selected from the group which consists of montmorillonite, illite, kaolinite, and co-minerals thereof provided that montmorillonite is present in an amount of at least 5% by weight, having a multiple sorptional pore space, possessing a sorption capacity of at least 50%, and being quasi-spherical in shape.
Claim 2
Dependent Claim 114 words
A porous carrier rock-based sorptional carrier consisting of at least one porous carrier rock selected from the group which consists of silicic earth, pumices, tuffs, bubble-porous lava rocks, expanded perlite, vermiculite, chalks, other porous biogeneous limes, and porous sand rocks in an amount not exceeding 95% by weight and 5 to 30% by weight of a clay mineral in a particle size of about 0.1 to 1μ and selected from the group which consists of montmorillonite, illite, kaolinite, and co-minerals thereof provided that montmorillonite is present in an amount of at least 5% by weight, having a multiple sorptional pore space, possessing a sorption capacity of at least 50%, and being quasi-spherical in shape.
Claim 3
Dependent Claim 13 words
A carrier as defined in claim 1, containing silicic earth as carrier rock.
Claim 4
Dependent Claim 25 words
A carrier as defined in claim 1, containing at least 5 % by weight of montmorillonite and 10 to 25 % by weight of illite.
Claim 5
Dependent Claim 192 words
A process for the preparation of a sorptional carrier for biologically active material comprising the steps of: wet-grinding at least one porous carrier rock selected from the group which consists of silicic earth, pumices, tuffs, bubble-porous lava rocks, expanded perlite vermiculite, chalks, other porous biogeneous limes, and porous sand rocks, and suspending same in water with a quantity of a plastic clay mineral of about 5 to 30% by weight of the carrier rock, said porous clay mineral being present in a particle size of 0.1 to 1 micron and being selected from the group which consists of montmorillonite, illite and kaolinite and cominerals thereof such that montmorillonite is present in an amount of at least 5% by weight of the carrier rock; adjusting said suspension so that the dry solids thereof are present in said suspension in an amount of at least 30% by weight; intensely stirring said suspension to homogenize the same; and spray-drying the homogenized suspension though a nozzle having an orifice of 0.8 to 2.5 mm diameter in a gas stream having a temperature of at least 400°C to produce particles of 0.1 to 1.5 mm in diameter.
Claim 6
Dependent Claim 192 words
A process for the preparation of a sorptional carrier for biologically active material comprising the steps of: wet-grinding at least one porous carrier rock selected from the group which consists of silicic earth, pumices, tuffs, bubble-porous lava rocks, expanded perlite vermiculite, chalks, other porous biogeneous limes, and porous sand rocks, and suspending same in water with a quantity of a plastic clay mineral of about 5 to 30% by weight of the carrier rock, said porous clay mineral being present in a particle size of 0.1 to 1 micron and being selected from the group which consists of montmorillonite, illite and kaolinite and cominerals thereof such that montmorillonite is present in an amount of at least 5% by weight of the carrier rock; adjusting said suspension so that the dry solids thereof are present in said suspension in an amount of at least 30% by weight; intensely stirring said suspension to homogenize the same; and spray-drying the homogenized suspension though a nozzle having an orifice of 0.8 to 2.5 mm diameter in a gas stream having a temperature of at least 400°C to produce particles of 0.1 to 1.5 mm in diameter.
Claim 7
Dependent Claim 25 words
The process defined in claim 4 wherein the particles of 0.1 to 1.5 mm in diameter are fired at a temperature of 900° to 1300°C.
Claim 8
Dependent Claim 39 words
The process defined in claim 5 wherein said clay mineral is present in an amount of 8 to 20% by weight of the carrier rock and the firing is carried out for a period of 3 to 6 seconds.

References Cited (Backward Citations)

US1985526A Cited
US2691598A Cited
US2698815A Cited
US2967154A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-29 1979-12-29 1980-06-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-29 1983-12-29 1984-06-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-29 1987-12-29 1988-06-29 $7700.00 Window Closed / Lapsed

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