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US3963853A Expired / Lapsed US ⏱️ 0.0 years remaining

Pressure sensitive transfer sheet

Assignee: Wiggins Teape UK PLC
•
Filing: 1972-12-27
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Granted: 1976-06-15
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Expires: 1992-12-27
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Abstract

Abstract A coated transfer sheet for pressure-sensitive copying systems which comprises an organic colorless color former containing two or more potential chromophoric systems each of which is capable of being activated substantially immediately when the compound is brought into contact with one or more activating substances.

Inventors

  • 👤 Nigel Hughes
  • 👤 Andrew Hunter Morris Renfrew

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 11:32
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/124; B41M5/132; B41M5/136; C; C09; C09B; C09B11/00; C09B11/02; C09B11/04; C09B11/10; C09B11/24; Y; Y10; Y10S; Y10S428/00; Y10S428/914; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31801; Y10T428/31804; Y10T428/31808; Y10T428/31812

Claims Analysis

Total Claims: 27
Claim 1
Independent Claim 248 words
A transfer sheet, for use in a pressure-sensitive copying system, comprising a support material having on one surface thereof a coating composition containing at least one colourless colour former, wherein said colourless colour former comprises a single organic compound having the structural formula: ##EQU3## wherein Y represents a phenylene or naphthylene or substituted phenylene or naphthylene radical, Z represents a 1,2-phenylene or substituted 1,2-phenylene radical, W represents oxygen or a group of the formula -NR 6 - wherein R 6 is selected from the group consisting of hydrogen, lower alkyl, aryl, substituted lower alkyl, and substituted aryl radicals, A and B each independently represents a 1,4-phenylene residue, R 1 , R 2 , R 3 and R 4 , each is selected from the group consisting of lower alkyl, substituted lower alkyl, aralkyl, substituted aralkyl, cycloalkyl and substituted cycloalkyl radical or forms part of a divalent organic chain which together with the attached nitrogen atom constitutes a heterocyclic ring, R 7 and R 8 each independently represents a lower alkyl or substituted lower alkyl radical, and the -NH- group is either attached to Y or is attached as one substituent or the sole substituent of R 6 when said R 6 is a substituted aryl radical, said organic compound thus containing within the same molecule at least two potential chromophoric systems, each of said potential chromophoric systems being capable of being activated substantially immediately when the compound is brought into contact with one or more acidic activating substances.
Claim 2
Dependent Claim 248 words
A transfer sheet, for use in a pressure-sensitive copying system, comprising a support material having on one surface thereof a coating composition containing at least one colourless colour former, wherein said colourless colour former comprises a single organic compound having the structural formula: ##EQU3## wherein Y represents a phenylene or naphthylene or substituted phenylene or naphthylene radical, Z represents a 1,2-phenylene or substituted 1,2-phenylene radical, W represents oxygen or a group of the formula -NR 6 - wherein R 6 is selected from the group consisting of hydrogen, lower alkyl, aryl, substituted lower alkyl, and substituted aryl radicals, A and B each independently represents a 1,4-phenylene residue, R 1 , R 2 , R 3 and R 4 , each is selected from the group consisting of lower alkyl, substituted lower alkyl, aralkyl, substituted aralkyl, cycloalkyl and substituted cycloalkyl radical or forms part of a divalent organic chain which together with the attached nitrogen atom constitutes a heterocyclic ring, R 7 and R 8 each independently represents a lower alkyl or substituted lower alkyl radical, and the -NH- group is either attached to Y or is attached as one substituent or the sole substituent of R 6 when said R 6 is a substituted aryl radical, said organic compound thus containing within the same molecule at least two potential chromophoric systems, each of said potential chromophoric systems being capable of being activated substantially immediately when the compound is brought into contact with one or more acidic activating substances.
Claim 3
Dependent Claim 42 words
The transfer sheet of claim 1, wherein each of R 1 , R 2 , R 3 , R 4 , R 6 , R 7 and R 8 is selected from the group consisting of ethyl, propyl, butyl, β-hydroxyethyl, and β-chloroethyl.
Claim 4
Dependent Claim 30 words
The transfer sheet of claim 1, wherein R 1 , R 2 , R 3 , R 4 , R 6 , R 7 and R 8 are each methyl.
Claim 5
Dependent Claim 30 words
The transfer sheet of claim 1, wherein each of R 1 , R 2 , R 3 and R 4 is selected from the group consisting of 4-methoxybenzyl and 2-methylbenzyl.
Claim 6
Dependent Claim 21 words
The transfer sheet of claim 1, wherein R 1 , R 2 , R 3 and R 4 are each benzyl.
Claim 7
Dependent Claim 31 words
The transfer sheet of claim 1, wherein each of R 1 , R 2 , R 3 and R 4 is selected from the group consisting of 2-methylcyclohexyl, 4-methyl-cyclohexyl and cyclopentyl.
Claim 8
Dependent Claim 21 words
The transfer sheet of claim 1, wherein R 1 , R 2 , R 3 and R 4 each represent cyclohexyl.
Claim 9
Dependent Claim 22 words
The transfer sheet of claim 1, wherein R 6 is selected from the group consisting of 2-methylphenyl, 4-methylphenyl, 4-nitrophenyl, 3-chlorophenyl and naphth-2-yl.
Claim 10
Dependent Claim 11 words
The transfer sheet of claim 1, wherein R 6 represents phenyl.
Claim 11
Dependent Claim 41 words
The transfer sheet of claim 1, wherein R 1 and R 2 , or R 3 and R 4 are joined together to form a member selected from the group consisting of a piperidine, a N-methylpiperazine and a pyrrolidine heterocyclic ring.
Claim 12
Dependent Claim 24 words
The transfer sheet of claim 1, wherein each of either R 1 and R 2 or R 3 and R 4 form hydrocarbon chains.
Claim 13
Dependent Claim 12 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-7-[bis(4-N,N-dimethylaminophenyl)methyl-amino]-fluoran.
Claim 14
Dependent Claim 16 words
The transfer sheet of claim 1, wherein said organic compound is 3', 4', 5', 6'-tetrachloro-3-(N,N-dimethylamino)-7-[bis(4-N,N-dimethylaminophenyl)methylamino] fluoran.
Claim 15
Dependent Claim 13 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-5,6-benzo-7-[bis(4-pyrrolidin-1-ylphenyl)methyl-amino] fluoran.
Claim 16
Dependent Claim 13 words
The transfer sheet of claim 1, wherein said organic compound is 4'-amino-3-(N,N-di-2-chloroethylamino)-7-[bis(4-N,N-diethylaminophenyl)methylamino] fluoran.
Claim 17
Dependent Claim 15 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-6,8-dimethylxanthene-9-spiro-3'-{2'-[4-bis {4-N,N-dimethylaminophenyl} methylamino)phenyl} phthalimidine.
Claim 18
Dependent Claim 14 words
The transfer sheet of claim 1, wherein said organic compound is 5-carboxyethyl-3-(N,N-diethylamino-7-[bis(4-N,N-dimethylaminophenyl) methylamino] fluoran.
Claim 19
Dependent Claim 13 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)benzo xanthene-9-spiro-3'-{2'-[4-(bis{4-N,N-dimethylaminophenyl}methylamino)phenyl]}phthalimidine.
Claim 20
Dependent Claim 13 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-7-[bis(4-N-benzyl-N-methylaminophenyl) methylamino]fluoran.
Claim 21
Dependent Claim 14 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-7-[bis(4-N-cyclohexyl-N-methylaminophenyl) methylamino] fluoran.
Claim 22
Dependent Claim 14 words
The transfer sheet of claim 1, wherein said organic compound is 4'-chloro-3-(N,N-diethylamino)-7-[bis(4-N,N-dimethylaminophenyl) methylamino] fluoran.
Claim 23
Dependent Claim 13 words
The transfer sheet of claim 1, wherein said organic compound is 7-chloro-3-(N,N-diethylamino)benzo xanthene-9-spiro-3'-{2'-{4-(bis-{4-N,N-dimethylaminophenyl}methylamino)phenyl}phthalimidine.
Claim 24
Dependent Claim 14 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-7-[bis(4-N,N -dimethylaminophenyl)methylamino]-xanthene-9-spiro-3'-(2'-phenyl) phthalimidine.
Claim 25
Dependent Claim 13 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-7-[bis(4-N,N-dimethylaminophenyl)methylamino]xanthene-9-spiro-3'-[2'-(4-methylphenyl)] phthalimidine.
Claim 26
Dependent Claim 14 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-7-[bis(4-N,N-dimethylaminophenyl)methylamino] xanthene-9-spiro- 3'-phthalimidine.
Claim 27
Dependent Claim 12 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-6-methyl-7-[bis(4-N,N-dimethylaminophenyl)methylamino]xanthene-9-spiro-3'-(2'-ethyl)phthalimidine.

References Cited (Backward Citations)

US3432327A Cited
US3427180A Cited
US3637757A Cited
US3641011A Cited
US3764369A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-15 1979-12-15 1980-06-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-15 1983-12-15 1984-06-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-15 1987-12-15 1988-06-15 $7700.00 Window Closed / Lapsed

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