US3963853A
Expired / Lapsed
US
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Pressure sensitive transfer sheet
Assignee: Wiggins Teape UK PLC
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Filing: 1972-12-27
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Granted: 1976-06-15
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Expires: 1992-12-27
Abstract
Abstract A coated transfer sheet for pressure-sensitive copying systems which comprises an organic colorless color former containing two or more potential chromophoric systems each of which is capable of being activated substantially immediately when the compound is brought into contact with one or more activating substances.
Inventors
- 👤 Nigel Hughes
- 👤 Andrew Hunter Morris Renfrew
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 11:32
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/124; B41M5/132; B41M5/136; C; C09; C09B; C09B11/00; C09B11/02; C09B11/04; C09B11/10; C09B11/24; Y; Y10; Y10S; Y10S428/00; Y10S428/914; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31801; Y10T428/31804; Y10T428/31808; Y10T428/31812
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
248 words
A transfer sheet, for use in a pressure-sensitive copying system, comprising a support material having on one surface thereof a coating composition containing at least one colourless colour former, wherein said colourless colour former comprises a single organic compound having the structural formula: ##EQU3## wherein Y represents a phenylene or naphthylene or substituted phenylene or naphthylene radical, Z represents a 1,2-phenylene or substituted 1,2-phenylene radical, W represents oxygen or a group of the formula -NR 6 - wherein R 6 is selected from the group consisting of hydrogen, lower alkyl, aryl, substituted lower alkyl, and substituted aryl radicals, A and B each independently represents a 1,4-phenylene residue, R 1 , R 2 , R 3 and R 4 , each is selected from the group consisting of lower alkyl, substituted lower alkyl, aralkyl, substituted aralkyl, cycloalkyl and substituted cycloalkyl radical or forms part of a divalent organic chain which together with the attached nitrogen atom constitutes a heterocyclic ring, R 7 and R 8 each independently represents a lower alkyl or substituted lower alkyl radical, and the -NH- group is either attached to Y or is attached as one substituent or the sole substituent of R 6 when said R 6 is a substituted aryl radical, said organic compound thus containing within the same molecule at least two potential chromophoric systems, each of said potential chromophoric systems being capable of being activated substantially immediately when the compound is brought into contact with one or more acidic activating substances.
Claim 2
Dependent Claim
248 words
A transfer sheet, for use in a pressure-sensitive copying system, comprising a support material having on one surface thereof a coating composition containing at least one colourless colour former, wherein said colourless colour former comprises a single organic compound having the structural formula: ##EQU3## wherein Y represents a phenylene or naphthylene or substituted phenylene or naphthylene radical, Z represents a 1,2-phenylene or substituted 1,2-phenylene radical, W represents oxygen or a group of the formula -NR 6 - wherein R 6 is selected from the group consisting of hydrogen, lower alkyl, aryl, substituted lower alkyl, and substituted aryl radicals, A and B each independently represents a 1,4-phenylene residue, R 1 , R 2 , R 3 and R 4 , each is selected from the group consisting of lower alkyl, substituted lower alkyl, aralkyl, substituted aralkyl, cycloalkyl and substituted cycloalkyl radical or forms part of a divalent organic chain which together with the attached nitrogen atom constitutes a heterocyclic ring, R 7 and R 8 each independently represents a lower alkyl or substituted lower alkyl radical, and the -NH- group is either attached to Y or is attached as one substituent or the sole substituent of R 6 when said R 6 is a substituted aryl radical, said organic compound thus containing within the same molecule at least two potential chromophoric systems, each of said potential chromophoric systems being capable of being activated substantially immediately when the compound is brought into contact with one or more acidic activating substances.
Claim 3
Dependent Claim
42 words
The transfer sheet of claim 1, wherein each of R 1 , R 2 , R 3 , R 4 , R 6 , R 7 and R 8 is selected from the group consisting of ethyl, propyl, butyl, β-hydroxyethyl, and β-chloroethyl.
Claim 4
Dependent Claim
30 words
The transfer sheet of claim 1, wherein R 1 , R 2 , R 3 , R 4 , R 6 , R 7 and R 8 are each methyl.
Claim 5
Dependent Claim
30 words
The transfer sheet of claim 1, wherein each of R 1 , R 2 , R 3 and R 4 is selected from the group consisting of 4-methoxybenzyl and 2-methylbenzyl.
Claim 6
Dependent Claim
21 words
The transfer sheet of claim 1, wherein R 1 , R 2 , R 3 and R 4 are each benzyl.
Claim 7
Dependent Claim
31 words
The transfer sheet of claim 1, wherein each of R 1 , R 2 , R 3 and R 4 is selected from the group consisting of 2-methylcyclohexyl, 4-methyl-cyclohexyl and cyclopentyl.
Claim 8
Dependent Claim
21 words
The transfer sheet of claim 1, wherein R 1 , R 2 , R 3 and R 4 each represent cyclohexyl.
Claim 9
Dependent Claim
22 words
The transfer sheet of claim 1, wherein R 6 is selected from the group consisting of 2-methylphenyl, 4-methylphenyl, 4-nitrophenyl, 3-chlorophenyl and naphth-2-yl.
Claim 10
Dependent Claim
11 words
The transfer sheet of claim 1, wherein R 6 represents phenyl.
Claim 11
Dependent Claim
41 words
The transfer sheet of claim 1, wherein R 1 and R 2 , or R 3 and R 4 are joined together to form a member selected from the group consisting of a piperidine, a N-methylpiperazine and a pyrrolidine heterocyclic ring.
Claim 12
Dependent Claim
24 words
The transfer sheet of claim 1, wherein each of either R 1 and R 2 or R 3 and R 4 form hydrocarbon chains.
Claim 13
Dependent Claim
12 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-7-[bis(4-N,N-dimethylaminophenyl)methyl-amino]-fluoran.
Claim 14
Dependent Claim
16 words
The transfer sheet of claim 1, wherein said organic compound is 3', 4', 5', 6'-tetrachloro-3-(N,N-dimethylamino)-7-[bis(4-N,N-dimethylaminophenyl)methylamino] fluoran.
Claim 15
Dependent Claim
13 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-5,6-benzo-7-[bis(4-pyrrolidin-1-ylphenyl)methyl-amino] fluoran.
Claim 16
Dependent Claim
13 words
The transfer sheet of claim 1, wherein said organic compound is 4'-amino-3-(N,N-di-2-chloroethylamino)-7-[bis(4-N,N-diethylaminophenyl)methylamino] fluoran.
Claim 17
Dependent Claim
15 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-6,8-dimethylxanthene-9-spiro-3'-{2'-[4-bis {4-N,N-dimethylaminophenyl} methylamino)phenyl} phthalimidine.
Claim 18
Dependent Claim
14 words
The transfer sheet of claim 1, wherein said organic compound is 5-carboxyethyl-3-(N,N-diethylamino-7-[bis(4-N,N-dimethylaminophenyl) methylamino] fluoran.
Claim 19
Dependent Claim
13 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)benzo xanthene-9-spiro-3'-{2'-[4-(bis{4-N,N-dimethylaminophenyl}methylamino)phenyl]}phthalimidine.
Claim 20
Dependent Claim
13 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-7-[bis(4-N-benzyl-N-methylaminophenyl) methylamino]fluoran.
Claim 21
Dependent Claim
14 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-7-[bis(4-N-cyclohexyl-N-methylaminophenyl) methylamino] fluoran.
Claim 22
Dependent Claim
14 words
The transfer sheet of claim 1, wherein said organic compound is 4'-chloro-3-(N,N-diethylamino)-7-[bis(4-N,N-dimethylaminophenyl) methylamino] fluoran.
Claim 23
Dependent Claim
13 words
The transfer sheet of claim 1, wherein said organic compound is 7-chloro-3-(N,N-diethylamino)benzo xanthene-9-spiro-3'-{2'-{4-(bis-{4-N,N-dimethylaminophenyl}methylamino)phenyl}phthalimidine.
Claim 24
Dependent Claim
14 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-7-[bis(4-N,N -dimethylaminophenyl)methylamino]-xanthene-9-spiro-3'-(2'-phenyl) phthalimidine.
Claim 25
Dependent Claim
13 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-7-[bis(4-N,N-dimethylaminophenyl)methylamino]xanthene-9-spiro-3'-[2'-(4-methylphenyl)] phthalimidine.
Claim 26
Dependent Claim
14 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-7-[bis(4-N,N-dimethylaminophenyl)methylamino] xanthene-9-spiro- 3'-phthalimidine.
Claim 27
Dependent Claim
12 words
The transfer sheet of claim 1, wherein said organic compound is 3-(N,N-diethylamino)-6-methyl-7-[bis(4-N,N-dimethylaminophenyl)methylamino]xanthene-9-spiro-3'-(2'-ethyl)phthalimidine.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-06-15 | 1979-12-15 | 1980-06-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-06-15 | 1983-12-15 | 1984-06-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-06-15 | 1987-12-15 | 1988-06-15 | $7700.00 | Window Closed / Lapsed |