Storage-stable moulding compositions for the manufacture of light-stable, tracking-resistant plastics

Claim 2

Storage-stable moulding composition, characterized in that it contains a. an adduct, containing epoxide groups, of a triglycidyl compound of the formula I ##EQU5## wherein X denotes a divalent alkylene group required to form a 5-membered or 6-membered heterocyclic structure and R denotes hydrogen or an alkyl group with 1 to 4 carbon atoms, and an organic compound possessing two or more active hydrogen atoms, selected from the group consisting of an aromatic primary monoamine, an aliphatic primary monoamine with 2 to 10 carbon atoms, a cycloaliphatic primary monoamine, a cycloaliphaticaliphatic primary monoamine, a heterocyclic-aliphatic primary monoamine, a mononuclear or binuclear hydantoin, a mononuclear or binulcear dihydrouracil, a dialcohol, a mononuclear or polynuclear phenol with 2 hydroxyl groups or a dicarboxylic acid, as the resin, b. an adduct, containing amino groups, of a cycloaliphatic, aliphatic-cycloaliphatic, aromatic or heterocyclic polyamine and a polyglycidyl compound, as the curing agent, and c. a mineral or organic, pulverulent or fibrous filler, and that the resin adduct and the curing agent adduct soften at between 45° and 120°C and melt 5° to 30°C above the softening point.

Claim 3

Moulding composition according to claim 1, characterised in that it also contains a lubricant.

Claim 4

Moulding composition according to claim 1, characterized in that it contains, as the resin (a), an adduct, containing epoxide groups, of a triglycidyl compound of the formula II ##EQU6## wherein R denotes hydrogen or an alkyl group with 1 to 4 carbon atoms and R 1 and R 2 denote hydrogen, or each denotes an alkyl group with 1 to 4 carbon atoms, or R 1 and R 2 together denote the tetramethylene or pentamethylene group, and of a compound containing two or more active hydrogen atoms, selected from the group consisting of an aromatic primary monoamine, an aliphatic primary monoamine with 2 to 10 carbon atoms, a cycloaliphatic primary monoamine, a cycloaliphatic-aliphatic primary monoamine, a heterocyclic-aliphatic primary monoamine, a mononuclear or binuclear hydantoin, a mononuclear or binuclear dihydrouracil, a dialcohol, a mononuclear or polynuclear phenol with 2 hydroxyl groups or a dicarboxylic acid.

Claim 5

Moulding composition according to claim 3, characterised in that it contains, as the resin (a), an adduct of a compound of the formula II and a cycloaliphatic primary monoamine, such as cyclohexylamine, a hydantoin-diol, such as 1,1'-methylene-bis-[3-(2-hydroxy-ethyl)-5,5-dimethyl-hydantoin], a bisphenol A or a dicarboxylic acid.

Claim 6

Moulding composition according to claim 1, characterised in that it contains, as the curing agent (b), an adduct of a cycloaliphatic, heterocyclic or aromatic diamine and a diglycidyl compound.

Claim 7

Moulding composition according to claim 5, characterised in that the diglycidyl component of the curing agent adduct (b) is derived from a bisphenol A epoxide resin.

Claim 8

Moulding composition according to claim 6, characterised in that it contains, as the curing agent (b), an adduct of 4,4-diamino-3,3'-dimethyldicyclohexyl-methane or isophoronediamine and a bisphenol A epoxide resin with more than 5.0 epoxide group equivalents/kg or the diglycidyl ester of hexahydrophthalic acid.

Claim 9

Moulding composition according to claim 1, characterised in that it contains an adduct according to claim 4 as the resin (a) and an adduct according to claim 5 as the curing agent (b).

Claim 10

Moulding composition according to claim 1, characterised in that it contains as compound (a) a 1:2 adduct of cyclohexylamine and 3,3'-(2-glycidyloxy-propylene)-bis-(1-glycidyl-5,5-dimethylhydantoin and as compound (b) an adduct of 4,4'-diamino-3,3'-dimethyldicyclohexylmethane and a bisphenol A epoxide resin.

Claim 11

Moulding composition according to claim 1, characterised in that it contains as compound (a) a 1:2 adduct of cyclohexylamine and 3,3'-(2-glycidyloxy-propylene)-bis-(1-glycidyl-5,5-pentamethylene-hydantoin and as compound (b) an adduct of 4,4'-diamino-3,3'-dimethyl-dicyclohexylmethane and a bisphenol A epoxide resin.

Claim 12

Moulding composition according to claim 1, characterised in that it contains as compound (a) a 1:2 adduct of 1,1'-methylene-bis-[3-(hydroxyethyl)-5,5-dimethyl-hydantoin] and 3,3'-(2-glycidyloxy-propylene)-bis-(1-glycidyl-5,5-dimethyl-hydantoin and as compound (b) an adduct of 4,4'-diamino-diphenylmethane and a liquid bisphenol A epoxide resin.

Claim 13

Moulding composition according to claim 1, characterised in that it contains as compound (a) a 1:2 adduct of bisphenol A and 3,3'-(2-glycidyloxy-propyl)-bis-(1-glycidyl-5,5-dimethyl-hydantoin) and as compound (b) an adduct of 1,2-diaminocyclohexane and N,N-cyclohexylamine-diglycidol.

Claim 14

Moulding composition according to claim 1, characterised in that it contains as compound (a) a 1:2 adduct of 1,1'-methylene-bis-(5,5-dimethyl-hydantoin) and 3,3'-(2-glycidyloxy-propylene)-bis-(1-glycidyl-5,5-dimethyl-hydantoin) and as compound (b) an adduct of 1,2-diamino-cyclohexane and a bisphenol A epoxide resin.

Claim 15

Process for the manufacture of storage-stable moulding compositions, characterized in that a triglycidyl compound of the formula I ##EQU7## wherein X denotes a divalent alkylene group which is required to form a 5-membered or 6-membered heterocyclic structure, and R denotes hydrogen or an alkyl group with 1 to 4 carbon atoms, is reacted with an organic compound containing two or more active hydrogen atoms, selected from the group consisting of an aromatic primary monoamine, an aliphatic primary monoamine with 2 to 10 carbon atoms, a cycloaliphatic primary monoamine, a cycloaliphatic-aliphatic primary monoamine, a heterocyclicaliphatic primary monoamine, a mononuclear or binuclear hydantoin, a mononuclear or binuclear dihydrouracil, a dialcohol, a mononuclear or polynuclear phenol with 2 hydroxyl groups or a dicarboxylic acid at between 50° and 200°C to give an adduct containing epoxide groups, which softens at between 45° and 120°C and melts at 5° to 30°C above the softening point, that a cycloaliphatic, aliphatic-cycloaliphatic, aromatic or heterocyclic polyamine is reacted with a polyglycidyl compound at between 50° and 200°C to give an adduct (b), containing amino groups, which softens at between 45° and 120°C and melts at 5° to 30°C above the softening point and that the two adducts (a) and (b) are mixed, and comminuted, with mineral or organic pulverulent or fibrous fillers.

Claim 16

Process for the manufacture of storage-stable moulding compositions, characterized in that a triglycidyl compound of the formula I ##EQU7## wherein X denotes a divalent alkylene group which is required to form a 5-membered or 6-membered heterocyclic structure, and R denotes hydrogen or an alkyl group with 1 to 4 carbon atoms, is reacted with an organic compound containing two or more active hydrogen atoms, selected from the group consisting of an aromatic primary monoamine, an aliphatic primary monoamine with 2 to 10 carbon atoms, a cycloaliphatic primary monoamine, a cycloaliphatic-aliphatic primary monoamine, a heterocyclicaliphatic primary monoamine, a mononuclear or binuclear hydantoin, a mononuclear or binuclear dihydrouracil, a dialcohol, a mononuclear or polynuclear phenol with 2 hydroxyl groups or a dicarboxylic acid at between 50° and 200°C to give an adduct containing epoxide groups, which softens at between 45° and 120°C and melts at 5° to 30°C above the softening point, that a cycloaliphatic, aliphatic-cycloaliphatic, aromatic or heterocyclic polyamine is reacted with a polyglycidyl compound at between 50° and 200°C to give an adduct (b), containing amino groups, which softens at between 45° and 120°C and melts at 5° to 30°C above the softening point and that the two adducts (a) and (b) are mixed, and comminuted, with mineral or organic pulverulent or fibrous fillers.

Claim 17

Process according to claim 14, characterised in that the two adducts (a) and (b) are mixed with fillers and a lubricant.

Claim 18

Process according to claim 14, characterised in that the manufacture of the adduct (a) is carried out at between 80° and 160°C.

Claim 19

Process according to claim 14, characterised in that the manufacture of the adduct (b) is carried out at between 120° and 170°C.

Claim 20

Process according to claim 14, characterised in that the adduct (a) is manufactured from the two components in the presence of a catalyst, such as bases or salts.

Claim 21

Process according to claim 14, characterised in that approximately 1 mol of the triglycidyl compound per equivalent of active hydrogen is used for the manufacture of the adduct (a).

Claim 22

Process according to claim 14, characterised in that a triglycidyl compound of the formula II ##EQU8## wherein R denotes hydrogen or an alkyl group with 1 to 4 carbon atoms and R 1 and R 2 denote hydrogen, or each denotes an alkyl group with 1 to 4 carbon atoms, or R 1 and R 2 together denote the tetramethylene or pentamethylene group, is used for the manufacture of the adduct (a).

Claim 23

Process according to claim 20, characterised in that a triglycidyl compound of the formula II and a cycloaliphatic primary monoamine, such as cyclohexylamine, a hydantoin-diol, such as 1,1'-methylene-bis-[3-(2-hydroxy-ethyl)-5,5-dimethyl-hydantoin], or a bisphenol A or a dicarboxylic acid, is used for the manufacture of the adduct (a).

Claim 24

Process according to claim 14, characterised in that a cycloaliphatic, heterocyclic or aromatic diamine and a diglycidyl compound are used for the manufacture of the adduct (b).

Claim 25

Process according to claim 22, characterised in that a bisphenol A epoxide resin is used as the diglycidyl compound for the manufacture of the adduct (b).

Claim 26

Process according to claim 23, characterised in that the starting materials for the manufacture of the adduct (b) are a 4,4'-diamino-3,3'-dimethyl-dicyclohexyl-methane and a bisphenol A epoxide resin with more than 5.0 epoxide group equivalents/kg, or the diglycidyl ester of hexahydrophthalic acid.