Method for catalytically cracking a hydrocarbon fuel

Claim 1

An improved blow and run catalytic cracking process for the production, from gaseous and distillate hydrocarbon fuels, of a gaseous product which comprises mainly hydrogen, together with small amounts of carbon monoxide and water and traces of other byproducts, involving alternately making hydrogen and regenerating the catalyst bed which comprises the steps of: A. making hydrogen by catalytically cracking without the use of steam a gaseous or distillate hydrocarbon fuel to form gaseous hydrogen and solid carbon including the steps of (1) passing said hydrocarbon fuel through a catalytic reaction bed consisting of supported metal, ring catalyzed pellets consisting of substrates of ceramics which are essentially spherical and selected from the group consisting of zirconia, alumina and mixtures of zirconia and alumina, having diameters of between one-quarter of an inch and five-eighths of an inch with nickel deposited to a depth of between one mil and one-hundred mils from the surface thereof so as to provide catalyzed substrates having substantial uncatalyzed cores, wherein said catalyzed pellets comprise between 1/2% and 5% nickel by weight at the inlet end of said catalyst bed and said catalyzed pellets comprise between 15% and 50% by weight nickel at the outlet end of said bed; (2) maintaining the temperature of said catalytic reaction bed at between about 1500°F and 2000°F during at least step (1); (3) conducting the hydrogen produced in said bed away from said bed; and (4) shutting off the supply of said fuel to the bed; and B. regenerating the bed without supplying additional fuel thereto including the steps of (1) passing an oxygen containing gas through said bed; (2) burning said solid carbon from said bed; (3) removing the products of combustion from said bed; and (4) shutting off the supply of oxygen containing gas to said bed.