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US3962376A Expired / Lapsed US ⏱️ 0.0 years remaining

2,4,6-Trialkyl-3-hydroxyphenylalkane phosphonates and phosphinates

Assignee: Novartis Corp
•
Filing: 1974-07-22
•
Granted: 1976-06-08
•
Expires: 1994-07-22
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Abstract

Abstract The compounds are trialkylsubstituted hydroxyphenylalkanephosphinates and phosphonates having the formula ##SPC1## Wherein R, R 1 and R 2 are independently lower alkyl or cycloalkyl groups, R 3 is alkyl, alkyl substituted with one halogen atom, phenyl, phenyl substituted with alkyl groups, alkoxy, alkoxy substituted with one halogen groups, phenoxy, phenoxy substituted with alkyl groups, alkylthioethoxy, alkyloxalkylenoxy, R 4 is alkyl, alkyll substituted with one halogen atom, cycloalkyl, phenyl, phenyl substituted with alkyl groups, alkylthioethyl, thiobisalkylene, alkylene, polyvalent cyclic or acyclic hydrocarbon radical, A is lower alkylene and n is 1 to 4. These compounds are usually prepared by reacting the trialkylsubstituted hydroxybenzyl or hydroxyphenylalkyl halide with the appropriate trialkyl or triaryl phosphite or appropriate substituted phosphinite. The compounds are useful as stabilizers of organic materials subject to oxidative, thermal and UV light deterioration.

Inventors

  • 👤 John d. Spivack
  • 👤 Martin Dexter

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 21:18
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/49; C08K5/51; C08K5/53; C08K5/5317; C08K5/5333; C07; C07F; C07F9/00; C07F9/02; C07F9/28; C07F9/30; C07F9/32; C07F9/3205; C07F9/3241; C07F9/38; C07F9/40; C07F9/4003; C07F9/4056; C10; C10M; C10M2207/00; C10M2207/28; C10M2207/281; C10M2207/282; C10M2207/283; C10M2207/286; C10M2207/34; C10M2223/00; C10M2223/06; C10M2223/061; C10M2223/065; C10N; C10N2040/00; C10N2040/20; C10N2040/22

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 37 words
A compound of the formula ##SPC5## wherein R is alkyl of 4 to 8 carbon atoms, R 3 is alkoxy of 12 to 24 carbon atoms, and R 4 is alkyl of 12 to 24 carbon atoms.
Claim 2
Dependent Claim 37 words
A compound of the formula ##SPC5## wherein R is alkyl of 4 to 8 carbon atoms, R 3 is alkoxy of 12 to 24 carbon atoms, and R 4 is alkyl of 12 to 24 carbon atoms.
Claim 3
Dependent Claim 11 words
A compound of claim 1 wherein R is branched chain alkyl.
Claim 4
Dependent Claim 9 words
A compound of claim 2 wherein R is tert-alkyl.
Claim 5
Dependent Claim 7 words
The compound of claim 1, di-n-dodecyl 4-tert.-butyl-2,6-dimethyl-3-hydroxybenzylphosphonate.
Claim 6
Dependent Claim 7 words
The compound of claim 1, di-n-octadecyl 4-tert.-butyl-2,6-dimethyl-3-hydroxybenzylphosphonate.

References Cited (Backward Citations)

US3006945A Cited
US3281505A Cited
US3742096A Cited
US3790648A Cited
US3769372A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-08 1979-12-08 1980-06-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-08 1983-12-08 1984-06-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-08 1987-12-08 1988-06-08 $7700.00 Window Closed / Lapsed

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