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US3962255A Expired / Lapsed US ⏱️ 0.0 years remaining

1,4-diazaepine-5-ones

Assignee: Novartis Corp
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Filing: 1974-07-26
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Granted: 1976-06-08
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Expires: 1994-07-26
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Abstract

Abstract According to the present invention, there are provided compounds having the formula: ##SPC1## And salts thereof, wherein n is 1 or 2, X is O of NH, Y is O, hydrogen or a branched- or straight chain alkyl residue having from 1 to 4 carbons and R 1 is a hydrocarbyl residue having from 1 to 20 carbon atoms, which are useful as stabilisers for polymers.

Inventors

  • 👤 Alexander Michael Chalmers

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 07:57
CPC Classifications
C; C07; C07D; C07D243/00; C07D243/06; C07D243/08; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3442

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 232 words
A compound having the formula: ##SPC11## wherein n is 1 or 2, X is O or NH, Y is O, hydrogen or a branched or straight-chain alkyl having from 1 to 4 carbon atoms and R 1 is a hydrocarbyl having from 1 to 20 carbon atoms which is selected, when n is 1 from the group consisting of a branched- or straight-chain alkyl having from 1 to 20 carbon atoms, a branched- or straight-chain alkenyl having from 3 to 18 carbon atoms, an unsubstituted cycloalkyl having from 5 to 14 carbon atoms or said cycloalkyl substituted with an alkyl of 1 to 8 carbons unsubstituted aryl selected from phenyl and naphthyl or said aryl substituted with chloro, methoxy or phenyl, an alkaryl having from 7 to 18 carbon atoms said alkyl substituent having 1 to 12 carbons, and when n is 2, from the group consisting of a branched- or straight-chain alkylene having 2 to 20 carbon atoms, an alkenylene having 4 to 20 carbon atoms, an unsubstituted cycloalkylene having from 5 to 12 carbon atoms, a substituted or unsubstituted arylene having from 6 to 12 carbon atoms, or an alkarylene having from 7 to 8 carbon atoms, said aromatic substituents being halogen or lower alkoxy groups; and salts thereof said salts being in the form of a phosphate, carbonate, sulphate, chloride, acetate, stearate, maleate, citrate, tartrate, oxalate, benzoate or carbamate.
Claim 2
Dependent Claim 232 words
A compound having the formula: ##SPC11## wherein n is 1 or 2, X is O or NH, Y is O, hydrogen or a branched or straight-chain alkyl having from 1 to 4 carbon atoms and R 1 is a hydrocarbyl having from 1 to 20 carbon atoms which is selected, when n is 1 from the group consisting of a branched- or straight-chain alkyl having from 1 to 20 carbon atoms, a branched- or straight-chain alkenyl having from 3 to 18 carbon atoms, an unsubstituted cycloalkyl having from 5 to 14 carbon atoms or said cycloalkyl substituted with an alkyl of 1 to 8 carbons unsubstituted aryl selected from phenyl and naphthyl or said aryl substituted with chloro, methoxy or phenyl, an alkaryl having from 7 to 18 carbon atoms said alkyl substituent having 1 to 12 carbons, and when n is 2, from the group consisting of a branched- or straight-chain alkylene having 2 to 20 carbon atoms, an alkenylene having 4 to 20 carbon atoms, an unsubstituted cycloalkylene having from 5 to 12 carbon atoms, a substituted or unsubstituted arylene having from 6 to 12 carbon atoms, or an alkarylene having from 7 to 8 carbon atoms, said aromatic substituents being halogen or lower alkoxy groups; and salts thereof said salts being in the form of a phosphate, carbonate, sulphate, chloride, acetate, stearate, maleate, citrate, tartrate, oxalate, benzoate or carbamate.
Claim 3
Dependent Claim 9 words
A compound of claim 1 wherein X is --NH--.
Claim 4
Dependent Claim 11 words
A compound of claim 2 in the form of a salt.
Claim 5
Dependent Claim 13 words
A compound as claimed in claim 1 wherein Y is hydrogen or methyl.
Claim 6
Dependent Claim 34 words
A compound as claimed in claim 2 wherein n is 1 and R 2 is a methyl, ethyl, n-propyl, isopropyl, sec-butyl, 2-ethylhexyl, n-dodecyl, n-octadecyl, phenyl or alkaryl having from 7 to 12 carbon atoms.
Claim 7
Dependent Claim 43 words
A compound as claimed in claim 2 wherein n is 2 and R 2 is an alkylene having from 2 to 6 carbon atoms, a cycloalkylene having from 6 to 12 carbon atoms or an alkarylene having from 7 to 13 carbon atoms.
Claim 8
Dependent Claim 83 words
A compound as claimed in claim 1 and having the formula: ##SPC12## wherein Y and n are as defined in claim 1 and when n is 1, R 3 is a branched- or straight-chain alkyl having form 1 to 20 carbon atoms or an aralkyl having from 7 to 12 carbon atoms and being either unsubstituted or substituted with a halogen atom, an alkyl group having from 1 to 4 carbon atoms or an alkoxy group having from 1 to 4 carbon atoms.
Claim 9
Dependent Claim 11 words
A compound of claim 7 in the form of a salt.
Claim 10
Dependent Claim 34 words
A compound as claimed in clam 7 wherein when n is 2, R 3 is an alkylene having from 2 to 20 carbon atoms or an aralkylene having from 8 to 14 carbon atoms.
Claim 11
Dependent Claim 20 words
A compound as claimed in claim 7 wherein R 3 is an alkyl having from 1 to 10 carbon atoms.
Claim 12
Dependent Claim 20 words
A compound as claimed in claim 9 wherein R 3 is an alkylene having from 2 to 6 carbon atoms.

References Cited (Backward Citations)

US3040029A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-08 1979-12-08 1980-06-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-08 1983-12-08 1984-06-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-08 1987-12-08 1988-06-08 $7700.00 Window Closed / Lapsed

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