US3962174A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polyalkylene terephthalate polymer molding resins
Assignee: Celanese Corp
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Filing: 1974-08-12
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Granted: 1976-06-08
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Expires: 1994-08-12
Abstract
Abstract An improved thermoplastic molding resin comprising intimately blended polybutylene terephthalate polymers or polypropylene terephthalate polymers, and reinforcing agents in the presence of a thermoplastic phenoxy resin.
Inventors
- 👤 Frank M. Berardinelli
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 01:54
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/01; C08K3/013; Y; Y10; Y10S; Y10S525/00; Y10S525/93
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
87 words
An improved thermoplastic polyester molding resin comprising a polyalkylene terephthalate polymer selected from the group consisting of polybutylene terephthalate polymer and polypropylene terephthalate polymer, and having an intrinsic viscosity in the range of from 0.2 to about 1.2 deciliters per gram, reinforcing agents intimately mixed with said polymer and from about 0.1 to about 8 weight percent, based on the total thermoplastic polyester molding resin, of a thermoplastic phenoxy resin having a repeating structure ##SPC6## and an average molecular weight range from about 15,000 to about 75,000.
Claim 2
Dependent Claim
87 words
An improved thermoplastic polyester molding resin comprising a polyalkylene terephthalate polymer selected from the group consisting of polybutylene terephthalate polymer and polypropylene terephthalate polymer, and having an intrinsic viscosity in the range of from 0.2 to about 1.2 deciliters per gram, reinforcing agents intimately mixed with said polymer and from about 0.1 to about 8 weight percent, based on the total thermoplastic polyester molding resin, of a thermoplastic phenoxy resin having a repeating structure ##SPC6## and an average molecular weight range from about 15,000 to about 75,000.
Claim 3
Dependent Claim
26 words
The product of claim 1 wherein the amount of reinforcing agent ranges from about 5 to about 60 weight percent of the total thermoplastic molding resin.
Claim 4
Dependent Claim
12 words
The product of claim 2 wherein the reinforcing agents are glass fibers.
Claim 5
Dependent Claim
13 words
The product of claim 2 wherein the reinforcing agent is acicular calcium metasilicate.
Claim 6
Dependent Claim
29 words
The product of claim 3 wherein the polyalkylene terephthalate polymer is polybutylene terephthalate having an intrinsic viscosity in the range from about 0.5 to about 1.0 deciliters per gram.
Claim 7
Dependent Claim
42 words
The product of claim 2 wherein the amount of phenoxy resin ranges from about 0.5 to 3 weight percent of the total thermoplastic polyester molding resin and said phenoxy resin having an average molecular weight ranging from about 20,000 to about 50,000.
Claim 8
Dependent Claim
44 words
The product of claim 2 wherein the polyalkylene terephthalate polymer is a polybutylene terephthalate containing brominated aromatic compounds incorporated in the polymer in the presence of a metal containing compound wherein the metal selected from the group consisting of arsenic, antimony, bismuth and phosphorus.
Claim 9
Dependent Claim
24 words
The product of claim 2 wherein the polyalkylene terephthalate contains 2,2-bis(4-ethoxy, 3,5-dibromophenyl) propane incorporated in the structure and in the presence of antimony trioxide.
Claim 10
Dependent Claim
30 words
The product of claim 2 wherein the polyalkylene terephthalate is polybutylene terephthalate containing 2,2-bis(4-ethoxy, 3,5-dibromophenyl) propane incorporated in the structure and in the presence of antimony trioxide and glass fibers.
Claim 11
Dependent Claim
81 words
The product of claim 2 intimately mixed with flame retardant additives comprising an aromatic halide stable at temperatures necessary for melt processing of the polyalkylene terephthalate and capable of decomposing at combustion temperatures of the polyalkylene terephthalate and a metal containing compound, said metal selected from the group consisting of arsenic, antimony, bismuth and phosphorus, wherein the weight ratio of available halogen in the aromatic halide to the available metal in the metalcontaining compound ranges from about 0.3 to about 4.
Claim 12
Dependent Claim
98 words
A process for producing an improved thermoplastic polyester molding resin wherein a polyalkylene terephthalate polymer selected from the group of polybutylene terephthalate polymer and polypropylene terephthalate polymer and having an intrinsic viscosity in the range from about 0.2 to 1.2 is intimately mixed with about 5 to about 60 weight percent of the total molding resin of a reinforcing agent in the presence of about 0.1 to about 8 weight percent of the total molding resin of a thermoplastic phenoxy resin having a repeating structure: ##SPC7## and an average molecular weight range from about 15,000 to about 75,000.
Claim 13
Dependent Claim
98 words
A process for producing an improved thermoplastic polyester molding resin wherein a polyalkylene terephthalate polymer selected from the group of polybutylene terephthalate polymer and polypropylene terephthalate polymer and having an intrinsic viscosity in the range from about 0.2 to 1.2 is intimately mixed with about 5 to about 60 weight percent of the total molding resin of a reinforcing agent in the presence of about 0.1 to about 8 weight percent of the total molding resin of a thermoplastic phenoxy resin having a repeating structure: ##SPC7## and an average molecular weight range from about 15,000 to about 75,000.
Claim 14
Dependent Claim
12 words
The process of claim 11 wherein the reinforcing agent is glass fibers.
Claim 15
Dependent Claim
44 words
The process of claim 12 wherein the polyalkylene terephthalate is a polybutylene terephthalate containing a brominated aromatic compound incorporated in the polymer structure and also containing a metal containing compound wherein the metal is selected from the group consisting of arsenic, antimony and bismuth.
Claim 16
Dependent Claim
89 words
The process of claim 12 wherein flame retardant additives are intimately mixed in the molding resin, said additives comprising an aromatic halide stable at temperatures necessary for melt processing of the polyalkylene terephthalate and capable of decomposing at combustion temperatures of the polyalkylene terephthalate and a metal containing compound, said metal selected from the group consisting of arsenic, antimony, bismuth and phosphorus wherein the weight ratio of available halogen in the aromatic halide to the available metal in the metal containing compound ranges from about 0.3 to about 4.
Claim 17
Dependent Claim
25 words
The process of claim 11 wherein the thermoplastic phenoxy resin is incorporated on the reinforcing agent and then intimately blended with the polyalkylene terephthalate polymer.
Claim 18
Dependent Claim
102 words
The product of claim 2 intimately mixed with flame retardant additives comprising an aromatic halide present in a concentration of from about 3.3 to about 16 weight percent, based on the weight of the resin, calculated as halide, said aromatic halide compound stable at temperatures necessary for melt processing of the polyalkylene terephthalate and capable of decomposing at combustion temperatures of the polyalkylene terephthalate, and a metal containing compound, said metal selected from the group consisting of arsenic, antimony, bismuth and phosphorous, present in a concentration of from about 0.7 to about 10.0 weight percent, based on the weight of the resin.
References Cited (Backward Citations)
US3329740A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-06-08 | 1979-12-08 | 1980-06-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-06-08 | 1983-12-08 | 1984-06-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-06-08 | 1987-12-08 | 1988-06-08 | $7700.00 | Window Closed / Lapsed |