Treatment of optical brightening agents

Claim 2

In a process for preparing an aqueous slurry containing from 15% to 60% by weight, based on the total weight of the slurry, of a compound of the formula ##SPC6## wherein X 1 and Y 1 are the same or different and each is phenylamino, phenylamino mono- or di-substituted by alkyl radicals having 1 or 2 carbon atoms, morpholino, alkylamino having 1 to 4 carbon atoms, alkylamino having 1 to 4 carbon atoms substituted by hydroxyl radicals or alkoxy having 1 to 4 carbon atoms, and M is hydrogen or an alkali metal, a major portion of the particles of this compound having size of 5 - 20 microns, which comprises mixing the wet filter cake obtained during the preparation of this compound with an agent to form the slurry, the improvement wherein the agent is from 0.1% to 5% by weight, based on the weight of the wet filter cake, of an anionic, cationic or nonionic surface active agent as dispersing agent, such that the resultant slurry is thixotropic and will not settle out appreciably on static storage and will have a Brookfield viscosity of from 200 to 10,000 centipoises at 6 r.p.m. and up to 2,000 centipoises at 60 r.p.m.

Claim 3

A process according to claim 1 in which the slurry contains from 20% to 40% by weight based on the total weight of the slurry of said compound.

Claim 4

A process according to claim 1 in which the dispersing agent is the sodium salt of the condensation product of naphthalene sulphonic acid and formaldehyde.

Claim 5

A process according to claim 1 in which the amount of dispersing agent is from 0.5 to 2.0% by weight based on the weight of the wet filter cake.

Claim 6

A process according to claim 1 wherein the Brookfield Viscosity is from 300 to 5,000 centipoises at 6 r.p.m. and from 50 to 1,000 centipoises at 60 r.p.m.

Claim 7

A process according to claim 1 wherein a gelling agent is added to the slurry.

Claim 8

A process according to claim 6 wherein the gelling agent is highly beneficiated magnesium silicate.

Claim 9

A process according to claim 6 wherein the amount of gelling agent is from 0.1% to 2.0% by weight based on the weight of wet filter-cake.

Claim 10

A process according to claim 1, in which there is present in the slurry from 4% to 25% by weight of an electrolyte selected from the group consisting of sodium chloride, sodium sulphate, sodium carbonate, potassium chloride, potassium sulphate and potassium carbonate, based on the total weight of the slurry.

Claim 11

A process according to claim 9 wherein the electrolyte is sodium chloride.

Claim 12

In a process for preparing an aqueous slurry containing from 15% to 40% by weight, based on the total weight of the slurry, of a compound having the formula ##SPC7## wherein X 1 and Y 1 are the same or different and each is phenylamino, phenylamino mono- or di-substituted by alkyl radicals having 1 or 2 carbon atoms, morpholino, alkylamino having 1 to 4 carbon atoms, alkylamino having 1 to 4 carbon atoms substituted by hydroxyl radicals or alkoxy having 1 to 4 carbon atoms, and M is hydrogen or an alkali metal, a major portion of the particles of this compound having a size of 5 - 20 microns, which comprises mixing the wet filter cake obtained during the preparation of the compound containing at least 4% by weight of an electrolyte selected from the group consisting of sodium chloride, sodium sulphate, sodium carbonate, potassium chloride, potassium sulphate and potassium carbonate, based on the total weight of the slurry, with an agent to form the slurry and grinding the slurry, the improvement wherein the agent is from 0.1% to 5% by weight, based on the weight of the wet filter cake, of an anionic, cationic or nonionic surface active agent as dispersing agent.

Claim 13

In a process for preparing an aqueous slurry containing from 15% to 40% by weight, based on the total weight of the slurry, of a compound having the formula ##SPC7## wherein X 1 and Y 1 are the same or different and each is phenylamino, phenylamino mono- or di-substituted by alkyl radicals having 1 or 2 carbon atoms, morpholino, alkylamino having 1 to 4 carbon atoms, alkylamino having 1 to 4 carbon atoms substituted by hydroxyl radicals or alkoxy having 1 to 4 carbon atoms, and M is hydrogen or an alkali metal, a major portion of the particles of this compound having a size of 5 - 20 microns, which comprises mixing the wet filter cake obtained during the preparation of the compound containing at least 4% by weight of an electrolyte selected from the group consisting of sodium chloride, sodium sulphate, sodium carbonate, potassium chloride, potassium sulphate and potassium carbonate, based on the total weight of the slurry, with an agent to form the slurry and grinding the slurry, the improvement wherein the agent is from 0.1% to 5% by weight, based on the weight of the wet filter cake, of an anionic, cationic or nonionic surface active agent as dispersing agent.

Claim 14

A slurry prepared by the process in accordance with claim 11.

Claim 15

An aqueous thixotropic slurry characterized by a. a content of from 15% to 60% by weight, based on the total weight of the slurry, of an optical brightener of the formula ##SPC8## wherein X 1 and Y 1 are the same or different and each is phenylamino, phenylamino mono- or di-substituted by alkyl radicals having 1 or 2 carbon atoms, morpholino, alkylamino having 1 to 4 carbon atoms, alkylamino having 1 to 4 carbon atoms substituted by hydroxyl radicals or alkoxy having 1 to 4 carbon atoms, and M is hydrogen or an alkali metal, a major portion of the particles of this compound having a size of 5 - 20 microns, b. a content of from 0.1% to 5% by weight, based on the total weight of the wet filter cake obtained during preparation of the optical brightener, of an anionic, cationic or nonionic surface active agent as dispersing agent, which dispersing agent has been mixed directly with the wet filter cake in forming said slurry, and c. a Brookfield viscosity of from 200 to 10,000 centipoises at 6 r.p.m. and up to 2,000 centipoises at 60 r.p.m.

Claim 16

An aqueous thixotropic slurry characterized by a. a content of from 15% to 60% by weight, based on the total weight of the slurry, of an optical brightener of the formula ##SPC8## wherein X 1 and Y 1 are the same or different and each is phenylamino, phenylamino mono- or di-substituted by alkyl radicals having 1 or 2 carbon atoms, morpholino, alkylamino having 1 to 4 carbon atoms, alkylamino having 1 to 4 carbon atoms substituted by hydroxyl radicals or alkoxy having 1 to 4 carbon atoms, and M is hydrogen or an alkali metal, a major portion of the particles of this compound having a size of 5 - 20 microns, b. a content of from 0.1% to 5% by weight, based on the total weight of the wet filter cake obtained during preparation of the optical brightener, of an anionic, cationic or nonionic surface active agent as dispersing agent, which dispersing agent has been mixed directly with the wet filter cake in forming said slurry, and c. a Brookfield viscosity of from 200 to 10,000 centipoises at 6 r.p.m. and up to 2,000 centipoises at 60 r.p.m.

Claim 17

A thixotropic slurry according to claim 13 characterized by a content of from 20% to 40% by weight based on the total weight of the slurry of the optical brightener.

Claim 18

A thixotropic slurry according to claim 13 in which the dispersing agent is the sodium salt of the condensation product of naphthalene sulphonic acid and formaldehyde.

Claim 19

A thixotropic slurry according to claim 13 wherein the Brookfield viscosity is from 300 to 5,000 centipoises at 6 r.p.m. and from 50 to 1,000 centipoises at 60 r.p.m.

Claim 20

A thixotropic slurry according to claim 13 characterized by a content of from 0.1% to 2.0% by weight based on the total weight of the slurry of a gelling agent.

Claim 21

A thixotropic slurry according to claim 17 wherein the gelling agent is magnesium silicate.

Claim 22

An aqueous thixotropic slurry, characterized by a. a content of from 15% to 60% by weight, based on the total weight of the slurry, of an optical brightener of the formula ##SPC9## wherein X 2 and Y 2 are the same or different and each is phenylamino, morpholino, alkylamino having 1 to 4 carbon atoms, or alkylamino having 1 to 4 carbon atoms substituted by hydroxyl radicals, and M is hydrogen or an alkali metal, a major portion of the particles of this compound having a size of 5 - 20 microns, b. a content of from 0.1% to 5 l % by weight, based on the total weight of the wet filter cake obtained during preparation of the optical brightener, of an anionic, cationic or nonionic surface active agent as dispersing agent, which dispersing agent has been mixed directly with the wet filter cake in forming said slurry, and c. a Brookfield viscosity of from 200 to 10,000 centipoises at 6 r.p.m. and up to 2,000 centipoises at 60 r.p.m.

Claim 23

An aqueous thixotropic slurry, characterized by a. a content of from 15% to 60% by weight, based on the total weight of the slurry, of an optical brightener of the formula ##SPC9## wherein X 2 and Y 2 are the same or different and each is phenylamino, morpholino, alkylamino having 1 to 4 carbon atoms, or alkylamino having 1 to 4 carbon atoms substituted by hydroxyl radicals, and M is hydrogen or an alkali metal, a major portion of the particles of this compound having a size of 5 - 20 microns, b. a content of from 0.1% to 5 l % by weight, based on the total weight of the wet filter cake obtained during preparation of the optical brightener, of an anionic, cationic or nonionic surface active agent as dispersing agent, which dispersing agent has been mixed directly with the wet filter cake in forming said slurry, and c. a Brookfield viscosity of from 200 to 10,000 centipoises at 6 r.p.m. and up to 2,000 centipoises at 60 r.p.m.

Claim 24

An aqueous thixotropic slurry, characterized by a. a content of from 15% to 60% by weight, based on the total weight of the slurry, of an optical brightener of the formula ##SPC10## wherein X 3 and Y 3 are the same or different and each is phenylamino, morpholino or N-methyl-N-ethanol-amino, and M is hydrogen or an alkali metal, a major portion of the particles of this compound having a size of 5 - 20 microns, b. a content of from 0.1% to 5% by weight, based on the total weight of the wet filter cake obtained during preparation of the optical brightener, of an anionic, cationic or nonionic surface active agent as dispersing agent, which dispersing agent has been mixed directly with the wet filter cake in forming said slurry, and c. a Brookfield viscosity of from 200 to 10,000 centipoises at 6 r.p.m. and up to 2,000 centipoises at 60 r.p.m.

Claim 25

An aqueous thixotropic slurry, characterized by a. a content of from 15% to 60% by weight, based on the total weight of the slurry, of an optical brightener of the formula ##SPC10## wherein X 3 and Y 3 are the same or different and each is phenylamino, morpholino or N-methyl-N-ethanol-amino, and M is hydrogen or an alkali metal, a major portion of the particles of this compound having a size of 5 - 20 microns, b. a content of from 0.1% to 5% by weight, based on the total weight of the wet filter cake obtained during preparation of the optical brightener, of an anionic, cationic or nonionic surface active agent as dispersing agent, which dispersing agent has been mixed directly with the wet filter cake in forming said slurry, and c. a Brookfield viscosity of from 200 to 10,000 centipoises at 6 r.p.m. and up to 2,000 centipoises at 60 r.p.m.

Claim 26

An aqueous thixotropic slurry, characterized by a. a content of from 15% to 60% by weight, based on the total weight of the slurry, of an optical brightener of the formula ##SPC11## wherein X 4 and Y 4 are the same or different and each is morpholino or N-methyl-N-ethanolamino, and M is hydrogen or an alkali metal, a major portion of the particles of this compound having a size of 5 - 20 microns, b. a content of from 0.1% to 5% by weight, based on the total weight of the wet filter cake obtained during preparation of the optical brightener, of an anionic, cationic or nonionic surface active agent as dispersing agent, which dispersing agent has been mixed directly with the wet filter cake in forming said slurry, c. a content of from 4% to 25% by weight, based on the total weight of the slurry, of an electrolyte selected from the group consisting of sodium chloride, sodium sulphate, sodium carbonate, potassium chloride, potassium sulphate and potassium carbonate, and d. a Brookfield viscosity of from 200 to 10,000 centipoises at 6 r.p.m. and up to 2,000 centipoises at 60 r.p.m.

Claim 27

An aqueous thixotropic slurry, characterized by a. a content of from 15% to 60% by weight, based on the total weight of the slurry, of an optical brightener of the formula ##SPC11## wherein X 4 and Y 4 are the same or different and each is morpholino or N-methyl-N-ethanolamino, and M is hydrogen or an alkali metal, a major portion of the particles of this compound having a size of 5 - 20 microns, b. a content of from 0.1% to 5% by weight, based on the total weight of the wet filter cake obtained during preparation of the optical brightener, of an anionic, cationic or nonionic surface active agent as dispersing agent, which dispersing agent has been mixed directly with the wet filter cake in forming said slurry, c. a content of from 4% to 25% by weight, based on the total weight of the slurry, of an electrolyte selected from the group consisting of sodium chloride, sodium sulphate, sodium carbonate, potassium chloride, potassium sulphate and potassium carbonate, and d. a Brookfield viscosity of from 200 to 10,000 centipoises at 6 r.p.m. and up to 2,000 centipoises at 60 r.p.m.

Claim 28

A thixotropic slurry according to claim 21 wherein the electrolyte is sodium chloride.

Claim 29

An aqueous thixotropic slurry, characterized by a. a content of from 15% to 60% by weight, based on the total weight of the slurry, of an optical brightener of the formula ##SPC12## where M is hydrogen or an alkali metal, a maajor portion of the particles of this compound having a size of 5 - 20 microns, b. a content of from 0.1% to 5% by weight, based on the total weight of the wet filter cake obtained during preparation of the optical brightener, of an anionic, cationic or nonionic surface active agent as dispersing agent, which dispersing agent has been mixed directly with the wet filter cake in forming said slurry, c. a content of from 4% to 25% by weight, based on the total weight of the slurry, of an electrolyte selected from the group consisting of sodium chloride, sodium sulphate, sodium carbonate, potassium chloride, potassium sulphate and potassium carbonate, and d. a Brookfield viscosity of from 200 to 10,000 centipoises at 6 r.p.m. and up to 2,000 centipoises at 60 r.p.m.

Claim 30

An aqueous thixotropic slurry, characterized by a. a content of from 15% to 60% by weight, based on the total weight of the slurry, of an optical brightener of the formula ##SPC12## where M is hydrogen or an alkali metal, a maajor portion of the particles of this compound having a size of 5 - 20 microns, b. a content of from 0.1% to 5% by weight, based on the total weight of the wet filter cake obtained during preparation of the optical brightener, of an anionic, cationic or nonionic surface active agent as dispersing agent, which dispersing agent has been mixed directly with the wet filter cake in forming said slurry, c. a content of from 4% to 25% by weight, based on the total weight of the slurry, of an electrolyte selected from the group consisting of sodium chloride, sodium sulphate, sodium carbonate, potassium chloride, potassium sulphate and potassium carbonate, and d. a Brookfield viscosity of from 200 to 10,000 centipoises at 6 r.p.m. and up to 2,000 centipoises at 60 r.p.m.