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US3961040A Expired / Lapsed US ⏱️ 0.0 years remaining

Insecticidal evaporator having a diffusion layer of olefin polymerizate

Assignee: Reckitt and Colman North America Inc
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Filing: 1974-03-13
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Granted: 1976-06-01
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Expires: 1994-03-13
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Abstract

Abstract An insecticidal evaporator is described which comprises I a liquid composition containing A. 40 to 90% by weight approximately calculated on the total weight of the composition of a volatile insecticidal ester of phosphoric acid the vapor pressure of which is at least 10.sup. -3 Torr at 20°C; b. at least one first additional organic liquid compound having a vapor pressure less than or equal to that of the volatile insecticidal ester; C. at least a second additional organic compound miscible or soluble in the mixture of the volatile insecticidal ester and of the first additional compound; Ii. a fibrous mass absorbent for the said composition I, and impregnated by the same; and Iii a diffusion layer covering at least a part of the surface of the said fibrous mass, the remainder of the surface of the fibrous mass being covered by an envelope impermeable to the said composition.

Inventors

  • 👤 Bernard Rabussier
  • 👤 Jean-Pierre Mandon

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 16:44
CPC Classifications
A; A01; A01N; A01N25/00; A01N25/18

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 293 words
In an insecticidal evaporator comprising I an absorbent fibrous mass substrate impregnated with a liquid composition comprising a. from about 40 to 90% by weight of the total liquid composition of 2,2-dichlorovinyldimethylphosphate b. an epoxidised organic liquid compound having a maximum vapor pressure no greater than the vapor pressure of 2,2-dichlorovinyldimethylphosphate; and c. an organic compound which is miscible with or soluble in the mixture of 2,2-dichlorovinyldimethylphosphate and said epoxidised organic compound; and Ii a non-porous, olefin polymer diffusion layer covering at least part of said impregnated fibrous mass, the remaining surface of said fibrous mass being covered by an envelope impermeable to said liquid composition; said epoxidised organic compound promoting the exudation of 2,2-dichlorovinyldimethylphosphate at the exterior surface of said diffusion layer, the improvement comprising a method of reducing exudation of 2,2-dichlorovinyldimethylphosphate at the exterior surface position, by incorporating into the liquid composition as the organic compound (c), from about 1 to about 40% by weight of said composition, of an exudation-reducing agent selected from the group consisting of (1) a compound of the formula ##SPC2## in which X 1 represents hydrogen, X 2 represents hydrogen or one of the substituents defined for (R) n , or X 1 and X 2 jointly represent a divalent bridge of the formula --CH=CH--CH=CH-- and (R) n represents substitution on the nucleus of members selected from the group consisting of (α) 2 or 3 hydroxyl groups, (β) from 1 to 3 alkyl groups each having from 1 to 4 carbon atoms, (γ) 1 or 2 alkyl groups each having from 1 to 4 carbon atoms, conjointly with a hydroxyl group, and (δ) an alkoxy group having from 1 to 4 carbon atoms, one of which members may occupy the X 2 position, and (2) di-(2-chloroethoxy)-methane.
Claim 2
Dependent Claim 293 words
In an insecticidal evaporator comprising I an absorbent fibrous mass substrate impregnated with a liquid composition comprising a. from about 40 to 90% by weight of the total liquid composition of 2,2-dichlorovinyldimethylphosphate b. an epoxidised organic liquid compound having a maximum vapor pressure no greater than the vapor pressure of 2,2-dichlorovinyldimethylphosphate; and c. an organic compound which is miscible with or soluble in the mixture of 2,2-dichlorovinyldimethylphosphate and said epoxidised organic compound; and Ii a non-porous, olefin polymer diffusion layer covering at least part of said impregnated fibrous mass, the remaining surface of said fibrous mass being covered by an envelope impermeable to said liquid composition; said epoxidised organic compound promoting the exudation of 2,2-dichlorovinyldimethylphosphate at the exterior surface of said diffusion layer, the improvement comprising a method of reducing exudation of 2,2-dichlorovinyldimethylphosphate at the exterior surface position, by incorporating into the liquid composition as the organic compound (c), from about 1 to about 40% by weight of said composition, of an exudation-reducing agent selected from the group consisting of (1) a compound of the formula ##SPC2## in which X 1 represents hydrogen, X 2 represents hydrogen or one of the substituents defined for (R) n , or X 1 and X 2 jointly represent a divalent bridge of the formula --CH=CH--CH=CH-- and (R) n represents substitution on the nucleus of members selected from the group consisting of (α) 2 or 3 hydroxyl groups, (β) from 1 to 3 alkyl groups each having from 1 to 4 carbon atoms, (γ) 1 or 2 alkyl groups each having from 1 to 4 carbon atoms, conjointly with a hydroxyl group, and (δ) an alkoxy group having from 1 to 4 carbon atoms, one of which members may occupy the X 2 position, and (2) di-(2-chloroethoxy)-methane.
Claim 3
Dependent Claim 55 words
The improvement of claim 1 in which the epoxidised organic liquid compound is selected from the group consisting of an epoxidised unsaturated vegetable oil, a glycidyl ether of an aliphatic monoalcohol, a glycidyl ether of a diol and an epoxidised ester of a mono- or dicarboxylic aliphatic acid having from 6 to 24 carbon atoms.
Claim 4
Dependent Claim 12 words
The improvement of claim 1 wherein the exudation reducing agent is di-(2-chloroethoxy)-methane.
Claim 5
Dependent Claim 13 words
The improvement of claim 1 in which the exudation reducing agent is 2-ethoxynaphthalene.
Claim 6
Dependent Claim 13 words
The improvement of claim 1 in which the exudation reducing agent is 2-methoxynaphthalene.
Claim 7
Dependent Claim 13 words
The improvement of claim 1 in which the exudation reducing agent is hydroquinone.
Claim 8
Dependent Claim 13 words
The improvement of claim 1 in which the exudation reducing agent is resorcinol.
Claim 9
Dependent Claim 32 words
The improvement of claim 1 in which the exudation reducing agent is present in an amount ranging from 3 to 10% by weight calculated on the total weight of the composition (I).

References Cited (Backward Citations)

US3781428A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-01 1979-12-01 1980-06-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-01 1983-12-01 1984-06-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-01 1987-12-01 1988-06-01 $7700.00 Window Closed / Lapsed

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