US3961021A
Expired / Lapsed
US
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Method for removing sulfur dioxide from combustion exhaust gas
Assignee: Kureha Corp
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Filing: 1974-09-17
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Granted: 1976-06-01
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Expires: 1994-09-17
Abstract
Abstract Sulfur dioxide can be removed from a combustion exhaust gas and converted to gypsum by first scrubbing a sulfur dioxide-containing combustion exhaust gas with an aqueous alkali sulfite solution to form an alkali bisulfite-containing aqueous solution and then treating, within a closed system, the thus formed aqueous bisulfite solution with a calcium compound. The efficiency of the sulfur dioxide removal can be increased greatly by adding a portion of alkali sulfite aqueous solution circulating in the system to at least a portion of filtrate from the gypsum separation process to precipitate metallic ionic impurities contained in the filtrate in the form of salts and separate these salts by filtration, and then recirculating the filtrate from the salt separation process to the absorption system.
Inventors
- 👤 Tomijiro Morita
- 👤 Akio Kobayashi
- 👤 Isao Funahashi
- 👤 Toshiharu Matsuda
- 👤 Makoto Naoki
- 👤 Naoyuki Kawamata
- 👤 Jun Fukui
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 19:57
CPC Classifications
C; C01; C01F; C01F11/00; C01F11/46; C01F11/464; B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/50; B01D53/501
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
193 words
A method for removing sulfur dioxide from combustion exhaust gas and converting the sulfur dioxide to gypsum, said process comprising: contacting the sulfur dioxide containing combustion exhaust gas with an aqueous solution containing an alkali sulfite to absorb the SO 2 as bisulfite; reacting said alkali bisulfite in solution with a calcium compound containing metallic impurities to form a mixture of calcium sulfite, metallic sulfite impurities, and an aqueous solution containing alkali sulfite; separating at least a portion of the alkali sulfite solution from said mixture and returning said portion to the sulfur dioxide contacting step, thereby forming a sulfite circulation loop; forming an aqueous slurry of said calcium sulfite and metallic sulfites; oxidizing said slurry to form gypsum and an aqueous solution containing the metallic impurities dissolved in the form of sulfates; separating said gypsum from solution to leave a first effluent containing the dissolved metallic sulfate impurities; mixing at least a portion of said first effluent with alkali sulfite for reaction to form a precipitate of metallic sulfites and soluble alkali sulfate; and separating said precipitate of metallic sulfites from solution and returning the remaining solution to the sulfite circulation loop.
Claim 2
Independent Claim
193 words
A method for removing sulfur dioxide from combustion exhaust gas and converting the sulfur dioxide to gypsum, said process comprising: contacting the sulfur dioxide containing combustion exhaust gas with an aqueous solution containing an alkali sulfite to absorb the SO 2 as bisulfite; reacting said alkali bisulfite in solution with a calcium compound containing metallic impurities to form a mixture of calcium sulfite, metallic sulfite impurities, and an aqueous solution containing alkali sulfite; separating at least a portion of the alkali sulfite solution from said mixture and returning said portion to the sulfur dioxide contacting step, thereby forming a sulfite circulation loop; forming an aqueous slurry of said calcium sulfite and metallic sulfites; oxidizing said slurry to form gypsum and an aqueous solution containing the metallic impurities dissolved in the form of sulfates; separating said gypsum from solution to leave a first effluent containing the dissolved metallic sulfate impurities; mixing at least a portion of said first effluent with alkali sulfite for reaction to form a precipitate of metallic sulfites and soluble alkali sulfate; and separating said precipitate of metallic sulfites from solution and returning the remaining solution to the sulfite circulation loop.
Claim 3
Dependent Claim
65 words
The process of claim 1 additionally comprising: reacting at least a portion of said bisulfite solution, said bisulfite solution containing dissolved alkali sulfate, with at least a portion of said calcium sulfite and sulfur dioxide or sulfuric acid to form a second bisulfite solution and calcium sulfate; and separating said calcium sulfate from solution and recirculating said second bisulfite solution to said sulfite circulation loop.
Claim 4
Dependent Claim
36 words
The process of claim 2 wherein said sulfur dioxide is formed by heating at least a portion of one of said bisulfite solutions to strip off sulfur dioxide gas, leaving a second effluent containing alkali sulfite.
Claim 5
Dependent Claim
21 words
The process of claim 3 wherein at least a portion of said second effluent is returned to the sulfite circulation loop.
Claim 6
Dependent Claim
29 words
The process of claim 3 wherein at least a portion of said second effluent is mixed with said first effluent for reaction to form the precipitate of metallic sulfites.
Claim 7
Dependent Claim
34 words
The method of claim 1 wherein the solution in the sulfite circulation loop contains more than 3% by weight sodium sulfite and has a Na 2 SO 3 -converted concentration of more than 10%.
Claim 8
Dependent Claim
39 words
The process of claim 1 wherein said first effluent is mixed with alkali sulfite at 40°-90° C. and the pH of the resultant solution is adjusted to a value within the range of 5-9 to precipitate the metallic sulfites.
Claim 9
Dependent Claim
23 words
The process of claim 1 wherein said portion of said first effluent is reacted with a solution diverted from the sulfite circulation loop.
Claim 10
Independent Claim
216 words
A method for removing sulfur dioxide from combustion exhaust gas and converting the sulfur dioxide to gypsum, said process comprising: contacting the sulfur dioxide containing combustion gas with an aqueous solution containing an alkali sulfite to absorb the SO 2 as bisulfite, thus forming a bisulfite-enriched solution; reacting said bisulfite-enriched solution with a calcium compound containing metallic impurities to form a mixture of calcium sulfite, sulfites of metallic impurities, and an aqueous solution containing alkali sulfite; separating at least a portion of the alkali sulfite solution from said mixture and returning said portion to the sulfur dioxide contacting step, thereby forming a sulfite circulation loop; forming an aqueous slurry of said calcium sulfite and metallic sulfites; oxidizing said slurry to form gypsum and an aqueous solution containing the metallic impurities dissolved in the form of sulfates; separating said gypsum from solution to leave a first effluent containing the dissolved metallic sulfates; mixing at least a portion of said first effluent with alkali sulfite for reaction to form a precipitate of double salts of said alkali and said metallic impurities; separating said precipitate from solution; hydrolyzing said precipitate of double salts to form a precipitate of metallic sulfites; and separating said precipitate of metallic sulfites from solution and returning the remaining solution to the sulfite circulation loop.
Claim 11
Independent Claim
216 words
A method for removing sulfur dioxide from combustion exhaust gas and converting the sulfur dioxide to gypsum, said process comprising: contacting the sulfur dioxide containing combustion gas with an aqueous solution containing an alkali sulfite to absorb the SO 2 as bisulfite, thus forming a bisulfite-enriched solution; reacting said bisulfite-enriched solution with a calcium compound containing metallic impurities to form a mixture of calcium sulfite, sulfites of metallic impurities, and an aqueous solution containing alkali sulfite; separating at least a portion of the alkali sulfite solution from said mixture and returning said portion to the sulfur dioxide contacting step, thereby forming a sulfite circulation loop; forming an aqueous slurry of said calcium sulfite and metallic sulfites; oxidizing said slurry to form gypsum and an aqueous solution containing the metallic impurities dissolved in the form of sulfates; separating said gypsum from solution to leave a first effluent containing the dissolved metallic sulfates; mixing at least a portion of said first effluent with alkali sulfite for reaction to form a precipitate of double salts of said alkali and said metallic impurities; separating said precipitate from solution; hydrolyzing said precipitate of double salts to form a precipitate of metallic sulfites; and separating said precipitate of metallic sulfites from solution and returning the remaining solution to the sulfite circulation loop.
Claim 12
Dependent Claim
66 words
The process of claim 9 additionally comprising: reacting at least a portion of said bisulfite-enriched solution, said bisulfite solution containing dissolved alkali sulfate, with at least a portion of said calcium sulfite and with sulfur dioxide or sulfuric acid to form a second bisulfite solution and calcium sulfate; and separating said calcium sulfate from solution and recirculating said second bisulfite solution to said sulfite circulation loop.
Claim 13
Dependent Claim
36 words
The process of claim 10 wherein said sulfur dioxide is formed by heating at least a portion of one of said bisulfite solutions to strip off sulfur dioxide gas, leaving a second effluent containing alkali sulfite.
Claim 14
Dependent Claim
21 words
The process of claim 11 wherein at least a portion of said second effluent is returned to the sulfite circulation loop.
Claim 15
Dependent Claim
29 words
The process of claim 11 wherein at least a portion of said second effluent is mixed with said first effluent for reaction to form the precipitate of metallic sulfites.
Claim 16
Dependent Claim
34 words
The method of claim 9 wherein the solution in the sulfite circulation loop contains more than 3% by weight sodium sulfite and has a Na 2 SO 3 -converted concentration of more than 10%.
Claim 17
Dependent Claim
39 words
The process of claim 9 wherein said first effluent is mixed with alkali sulfite at 40°-90° C. and the pH of the resultant solution is adjusted to a value within the range of 5-9 to precipitate the metallic sulfites.
Claim 18
Dependent Claim
23 words
The process of claim 9 wherein said portion of said first effluent is reacted with a solution diverted from the sulfite circulation loop.
Claim 19
Dependent Claim
34 words
The method of claim 1 wherein said combustion exhaust gas contains metallic impurities and wherein said impurities include ions of at least one metal selected from the group consisting of magnesium, nickel and iron.
Claim 20
Dependent Claim
35 words
The method of claim 9 wherein said combustion exhaust gas contains metallic impurities and wherein said metallic impurities include ions of at least one metal selected from the group consisting of magnesium, nickel and iron.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-06-01 | 1979-12-01 | 1980-06-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-06-01 | 1983-12-01 | 1984-06-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-06-01 | 1987-12-01 | 1988-06-01 | $7700.00 | Window Closed / Lapsed |