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US3960928A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the manufacture of condensation products from phenols and polyacetoacetic acid esters

Assignee: Hoechst AG
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Filing: 1975-03-07
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Granted: 1976-06-01
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Expires: 1995-03-07
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Abstract

Abstract Polyphenol-carboxylic acid esters are prepared from definite phenols and polyacetoacetic acid esters by condensing the components in the presence of hydrogen chloride at a temperature of from -10° to +15°C, using ethyl mercaptan as catalyst; the obtained esters are useful as fungicides or bactericides as well as for stabilizing plastic resins and manufacture of varnishing resins.

Inventors

  • 👤 Otto Mauz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 14:03
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/13; C08K5/10; C08K5/101; C08K5/105

Claims Analysis

Total Claims: 2
Claim 1
Independent Claim 129 words
In a process for the manufacture of a polyphenol-carboxylic acid ester from phenols of general formula I ##SPC2## and polyacetoacetic acid esters of general formula II ##EQU2## in which formulae R 1 and R 2 each stand for hydrogen atoms, identical or different alkyl radicals having 1 to 4 carbon atoms, R 3 represents a saturated, straight chain or branched aliphatic, cycloaliphatic hydrocarbon radical having from 2 to 12 carbon atoms or R 3 is p-phenylene, m-phenylene, or a naphthylene and n is 2 to 4, the improvement of which comprises condensing the reaction components I and II at a temperature of from -10° to +15°C in the presence of gaseous hydrogen chloride and 0.05 to 0.5 % by weight of ethyl mercaptan, calculated on the polyacetoacetic acid ester.
Claim 2
Dependent Claim 129 words
In a process for the manufacture of a polyphenol-carboxylic acid ester from phenols of general formula I ##SPC2## and polyacetoacetic acid esters of general formula II ##EQU2## in which formulae R 1 and R 2 each stand for hydrogen atoms, identical or different alkyl radicals having 1 to 4 carbon atoms, R 3 represents a saturated, straight chain or branched aliphatic, cycloaliphatic hydrocarbon radical having from 2 to 12 carbon atoms or R 3 is p-phenylene, m-phenylene, or a naphthylene and n is 2 to 4, the improvement of which comprises condensing the reaction components I and II at a temperature of from -10° to +15°C in the presence of gaseous hydrogen chloride and 0.05 to 0.5 % by weight of ethyl mercaptan, calculated on the polyacetoacetic acid ester.

References Cited (Backward Citations)

US3639447A Cited
US3450746A Cited
US3577384A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-01 1979-12-01 1980-06-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-01 1983-12-01 1984-06-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-01 1987-12-01 1988-06-01 $7700.00 Window Closed / Lapsed

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