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US3960688A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for electrodepositing coatings on metal

Assignee: Wyeth Holdings LLC
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Filing: 1974-10-04
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Granted: 1976-06-01
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Expires: 1994-10-04
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Abstract

Abstract A process for electrodepositing on an electroconductive metal by immersing said metal in an aqueous dispersion of a blend of certain aminoplast cross-linking agents and certain non-gelled polymeric materials catalyzed with certain aromatic sulfonic acid compounds in stated proportions and then subjecting the aqueous dispersion to electrophoresis in order to deposit the catalyzed mixture on the metal as an adherent film.

Inventors

  • 👤 Leonard Joseph Calbo, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 10:56
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/44; C09D5/4484

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 244 words
A process for electrodepositing films on electroconductive metal comprising immersing said metal in an aqueous dispersion of a mixture of from about 5% to about 40%, by weight, of (A) a substantially water-insoluble, substantially fully etherified, substantially fully methylolated melamine; a substantially water-insoluble, substantially fully etherified, substantially fully methylolated guanamine or a substantially water-insoluble, substantially fully butylated urea-formaldehyde reaction product and correspondingly from about 95% to about 60%, by weight, of (B) a water dispersible non-gelled polymeric material carrying an ionic charge which polymeric material contains at least one class of reactive groups selected from the group consisting of carboxyl groups, alcoholic hydroxy groups, amine groups and amide groups, wherein the amount of said groups is at least 3%, by weight, and not more than about 30%, by weight, based on the total weight of said polymeric material; wherein said groups are heat reactive with (A); and as a curing catalyst for (A) and (B) from about 0.2% to about 10%, by weight, of (C) an aromatic sulfonic acid compound having an equivalent weight of at least 250 and subjecting the aqueous dispersion to electrophoresis in order to deposit the catalyzed mixture of (A) and (B) on the metal as an adherent film; wherein the percentages of (A) and (B), by weight, total 100% and are based on the total solids weight of (A) and (B) and the percentage weight of (C) is also based on the total solids weight of (A) and (B).
Claim 2
Dependent Claim 244 words
A process for electrodepositing films on electroconductive metal comprising immersing said metal in an aqueous dispersion of a mixture of from about 5% to about 40%, by weight, of (A) a substantially water-insoluble, substantially fully etherified, substantially fully methylolated melamine; a substantially water-insoluble, substantially fully etherified, substantially fully methylolated guanamine or a substantially water-insoluble, substantially fully butylated urea-formaldehyde reaction product and correspondingly from about 95% to about 60%, by weight, of (B) a water dispersible non-gelled polymeric material carrying an ionic charge which polymeric material contains at least one class of reactive groups selected from the group consisting of carboxyl groups, alcoholic hydroxy groups, amine groups and amide groups, wherein the amount of said groups is at least 3%, by weight, and not more than about 30%, by weight, based on the total weight of said polymeric material; wherein said groups are heat reactive with (A); and as a curing catalyst for (A) and (B) from about 0.2% to about 10%, by weight, of (C) an aromatic sulfonic acid compound having an equivalent weight of at least 250 and subjecting the aqueous dispersion to electrophoresis in order to deposit the catalyzed mixture of (A) and (B) on the metal as an adherent film; wherein the percentages of (A) and (B), by weight, total 100% and are based on the total solids weight of (A) and (B) and the percentage weight of (C) is also based on the total solids weight of (A) and (B).
Claim 3
Dependent Claim 25 words
The process according to claim 1 in which the coated metal is rinsed with deionized water, the film baked to produce a hard cross-linked coating.
Claim 4
Dependent Claim 18 words
The process according to claim 1 in which the aromatic sulfonic acid compound is a naphthalene disulfonic acid.
Claim 5
Dependent Claim 15 words
The process according to claim 3 in which the naphthalene disulfonic acid is 2,6-dinonyl-naphthalene-4,8-disulfonic acid.
Claim 6
Dependent Claim 17 words
The process according to claim 1 in which the aromatic sulfonic acid compound is p-dodecylbenzene sulfonic acid.
Claim 7
Dependent Claim 17 words
The process according to claim 1 in which the aromatic sulfonic acid compound is 2,4-dinitro-1-hydroxy-7-naphthalene sulfonic acid.
Claim 8
Dependent Claim 18 words
The process according to claim 1 in which the aromatic sulfonic acid compound is 2-hydroxy, 4-methoxy, 5-sulfonic acid-benzophenone.
Claim 9
Dependent Claim 37 words
The process according to claim 1 in which the aromatic sulfonic acid compound is present in an amount between about 0.5 percent and 2.0 percent, by weight, based on the total solids weight of (A) and (B).
Claim 10
Dependent Claim 19 words
The process according to claim 1 in which the aromatic sulfonic acid compound is 2,4-dipropyl-naphthalene 8-sulfonic acid sodium salt.
Claim 11
Dependent Claim 19 words
The process according to claim 1 in which the (A) is the triethyl ether, trimethyl ether of hexamethylol melamine.

References Cited (Backward Citations)

US3378477A Cited
US3663485A Cited
US3663389A Cited
US3681224A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-01 1979-12-01 1980-06-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-01 1983-12-01 1984-06-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-01 1987-12-01 1988-06-01 $7700.00 Window Closed / Lapsed

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