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US3959539A Expired / Lapsed US ⏱️ 0.0 years remaining

Coating material of polymers and salts of fatty acids

Assignee: EIDP Inc
•
Filing: 1974-11-13
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Granted: 1976-05-25
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Expires: 1994-11-13
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Abstract

Abstract Powder coating materials which consist essentially of an ionic copolymer, or a copolymer or terpolymer base resin of the ionic copolymer, and 1 to 20% by weight, based on the weight of copolymer, of a monobasic fatty acid of 10 to 22 carbon atoms, a metal salt of a monobasic fatty acid of 10 to 22 carbon atoms, or mixtures thereof. The materials are useful for coating glass bottles.

Inventors

  • 👤 Marion Glen Waggoner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 05:42
CPC Classifications
C; C03; C03C; C03C17/00; C03C17/28; C03C17/32; C08; C08K; C08K5/00; C08K5/04; C08K5/09; C09; C09D; C09D123/00; C09D123/02; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/131; Y10T428/1317; Y10T428/1321; Y10T428/31504; Y10T428/31551; Y10T428/31645

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 234 words
Powder coating material for glass which consists essentially of a copolymer of α-olefins of the formula R--CH=CH 2 , where R is a radical selected from the class consisting of hydrogen and alkyl radicals having from 1 to 8 carbon atoms, and α,β-ethylenically unsaturated carboxylic acids having from 3 to 8 carbon atoms, said copolymer having from 0% to 90% of the carboxylic acid groups ionized by neutralization with uncomplexed metal ions, said metal ions having an ionized valence of from one to three inclusive when the unsaturated acid is a monocarboxylic acid and an ionized valence of one when the unsaturated acid is a dicarboxylic acid said copolymer being a copolymer of the α-olefins and the unsaturated carboxylic acid in which the carboxylic acid groups are randomly distributed over all molecules and in which 1 the α-olefin content of the copolymer is at least 50 mol percent, based on the α-olefin-acid copolymer, 2 the unsaturated carboxylic acid content of the copolymer is from 0.2 to 25 mol percent, based on the α-olefin-acid copolymer, and 3 any other monomer component optionally copolymerized in said copolymer is monoethylenically unsaturated, and 1 to 20% by weight, based on the weight of the copolymer, of an additive selected from the class consisting of monobasic fatty acids of 10 to 22 carbon atoms, metal salts of monobasic fatty acids of 10 to 22 carbon atoms, and mixtures thereof.
Claim 2
Dependent Claim 234 words
Powder coating material for glass which consists essentially of a copolymer of α-olefins of the formula R--CH=CH 2 , where R is a radical selected from the class consisting of hydrogen and alkyl radicals having from 1 to 8 carbon atoms, and α,β-ethylenically unsaturated carboxylic acids having from 3 to 8 carbon atoms, said copolymer having from 0% to 90% of the carboxylic acid groups ionized by neutralization with uncomplexed metal ions, said metal ions having an ionized valence of from one to three inclusive when the unsaturated acid is a monocarboxylic acid and an ionized valence of one when the unsaturated acid is a dicarboxylic acid said copolymer being a copolymer of the α-olefins and the unsaturated carboxylic acid in which the carboxylic acid groups are randomly distributed over all molecules and in which 1 the α-olefin content of the copolymer is at least 50 mol percent, based on the α-olefin-acid copolymer, 2 the unsaturated carboxylic acid content of the copolymer is from 0.2 to 25 mol percent, based on the α-olefin-acid copolymer, and 3 any other monomer component optionally copolymerized in said copolymer is monoethylenically unsaturated, and 1 to 20% by weight, based on the weight of the copolymer, of an additive selected from the class consisting of monobasic fatty acids of 10 to 22 carbon atoms, metal salts of monobasic fatty acids of 10 to 22 carbon atoms, and mixtures thereof.
Claim 3
Dependent Claim 21 words
A coating material according to claim 1 wherein the additive is a monobasic fatty acid of 10 to 22 carbon atoms.
Claim 4
Dependent Claim 14 words
A coating material according to claim 2 wherein the fatty acid is stearic acid.
Claim 5
Dependent Claim 14 words
A coating material according to claim 2 wherein the fatty acid is oleic acid.
Claim 6
Dependent Claim 24 words
A coating material according to claim 1 wherein the additive is a salt of a monobasic fatty acid of 10 to 22 carbon atoms.
Claim 7
Dependent Claim 17 words
A coating material according to claim 5 wherein the acid salt is the salt of stearic acid.
Claim 8
Dependent Claim 17 words
A coating material according to claim 5 wherein the acid salt is the salt of oleic acid.
Claim 9
Dependent Claim 16 words
A coating material according to claim 6 wherein the acid salt is an alkali metal stearate.
Claim 10
Dependent Claim 15 words
A coating material according to claim 8 wherein the stearic acid salt is sodium stearate.
Claim 11
Dependent Claim 15 words
A coating material according to claim 6 wherein the stearic acid salt is zinc stearate.
Claim 12
Dependent Claim 16 words
A coating material according to claim 7 wherein the acid salt is an alkali metal oleate.
Claim 13
Dependent Claim 15 words
A coating material according to claim 11 wherein the oleic acid salt is sodium oleate.
Claim 14
Dependent Claim 23 words
A coating material according to claim 1 wherein the additive is a mixture of monobasic fatty acids of 10 to 22 carbon atoms.
Claim 15
Dependent Claim 18 words
A coating material according to claim 13 wherein the additive is a mixture of arachidic and behenic acids.
Claim 16
Dependent Claim 31 words
A coating material according to claim 1 wherein the copolymer is an ionic copolymer having from 10 to 90% of the carboxylic acid groups ionized by uncomplexed neutralization with metal ions.
Claim 17
Dependent Claim 25 words
A coating material according to claim 15 wherein the metal ions are taken from the group consisting of Na + and Zn + 2 .
Claim 18
Dependent Claim 16 words
A coating material according to claim 15 wherein the copolymer is an ethylene/methacrylic acid ionic copolymer.
Claim 19
Dependent Claim 71 words
A coating material according to claim 1 wherein the copolymer is a copolymer of α-olefins of the formula R--CH=CH 2 , where R is a radical selected from the class consisting of hydrogen and alkyl radicals having from 1 to 8 carbon atoms, and α,β-ethylenically unsaturated carboxylic acids having from 3 to 8 carbon atoms, said copolymer having none of the carboxylic acid groups ionized by neutralization with uncomplexed metal ions.
Claim 20
Dependent Claim 13 words
A coating material according to claim 18 wherein the copolymer is ethylene/methacrylic acid.
Claim 21
Dependent Claim 9 words
Glass coated with a material according to claim 1.
Claim 22
Dependent Claim 10 words
Glass bottles coated with a material according to claim 1.

References Cited (Backward Citations)

US3264272A Cited
US3196134A Cited
US3267083A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-05-25 1979-11-24 1980-05-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-05-25 1983-11-24 1984-05-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-05-25 1987-11-24 1988-05-25 $7700.00 Window Closed / Lapsed

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