US3959321A
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US
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Stabilized fatty acids
Assignee: Kraft Inc
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Filing: 1974-05-13
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Granted: 1976-05-25
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Expires: 1994-05-13
Abstract
Abstract Fatty acids are stabilized by adding to the fatty acid an effective amount of an alkali metal salt of particular organic phosphate esters. The stabilizer contains from about 5 to 15 percent phosphorus and from about 10 to about 30 percent alkali metal, with the balance being derived from organic alcohols.
Inventors
- 👤 Arthur L. McKenna, III
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 19:35
CPC Classifications
C; C11; C11B; C11B5/00; C11B5/0071; C07; C07C; C07C51/00; C07C51/42; C07C51/50
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
80 words
A method for stabilizing fatty acids against oxidation comprising adding to fatty acids having a chain length of C 6 to C 24 an effective amount of a stabilizer, said stabilizer being an alkali metal salt of an organic phosphate ester, said ester being the condensation reaction product of an alcohol and a phosphorus compound, said phosphorus being in the pentavalent state during said condensation reaction, said alcohol being selected from the group consisting of poly-alkylene alcohols and hydrocarbyl polyols.
Claim 2
Independent Claim
80 words
A method for stabilizing fatty acids against oxidation comprising adding to fatty acids having a chain length of C 6 to C 24 an effective amount of a stabilizer, said stabilizer being an alkali metal salt of an organic phosphate ester, said ester being the condensation reaction product of an alcohol and a phosphorus compound, said phosphorus being in the pentavalent state during said condensation reaction, said alcohol being selected from the group consisting of poly-alkylene alcohols and hydrocarbyl polyols.
Claim 3
Dependent Claim
41 words
A method in accordance with claim 1 wherein said phosphorus compound is selected from the group consisting of polyphosphoric acid, phosphorus oxychloride, phosphorus pentoxide and inorganic phosphorus salts selected from the group consisting of potassium monohydrogen phosphate and potassium dihydrogen phosphate.
Claim 4
Dependent Claim
82 words
A method in accordance with claim 1 wherein said polyalkylene alcohol is selected from the group consisting of alcohol ethers which have the formula R.sub.1 --OR.sub.2 --.sub.X OH where R 1 is selected from the group consisting of hydrogen, C 1 to C 4 straight or branched chain alkyl, phenyl, cresyl, ethyl phenyl and mixtures thereof and R 2 is selected from the group consisting of ethylene, propylene, isopropylene, butylene and mixtures thereof and X is a number from 1 to 30.
Claim 5
Dependent Claim
16 words
A method in accordance with claim 3 wherein X is a number from 1 to 10.
Claim 6
Dependent Claim
16 words
A method in accordance with claim 3 wherein X is a number from 1 to 6.
Claim 7
Dependent Claim
58 words
A method in accordance with claim 1 wherein said polyalkylene alcohol is selected from the group consisting of di-, tri-, tetra- and penta-ethylene glycol mono-phenyl ether, di-, tri-, tetra- and penta-ethylene glycol mono-cresyl ether, di-, tri-, tetra- and penta-ethylene glycol mono-(ethyl-phenyl) ether, the propylene, isopropylene and butylene equivalents of the foregoing ethylene glycol phenyl ethers and mixtures thereof.
Claim 8
Dependent Claim
22 words
A method in accordance with claim 1 wherein said polyols have a carbon chain length of C 2 to C 6 .
Claim 9
Dependent Claim
44 words
A method in accordance with claim 1 wherein said polyols are selected from the group consisting of ethylene glycol, propylene glycol, glycerol, pentaerythritol, 1,5-pentanediol, 1,3-butanediol, 1,4-butanediol, 2,3,-butanediol, 1,2,4,-butanetriol, 4-methyl 2,4 pentanediol, 1,6,-hexanediol, 2,5,-hexanediol, erythritol, xylitol, arabitol, adonitol, sorbitol, mannitol, galactitol, inositol, and mixtures thereof.
Claim 10
Dependent Claim
46 words
A method in accordance with claim 1 wherein said alkali metal salt of said condensation reaction product contains from about 5 to about 15 percent by weight, dry basis, of phosphorus and from about 10 to about 30 percent by weight, dry basis, of alkali metal.
Claim 11
Dependent Claim
21 words
A method in accordance with claim 1 wherein said alkali metal is selected from the group consisting of potassium and sodium.
Claim 12
Dependent Claim
13 words
A method in accordance with claim 1 wherein said alkali metal is potassium.
Claim 13
Dependent Claim
39 words
A method in accordance with claim 1 wherein said stabilizer is added to said fatty acid at a level of from about 0.005 to about 0.05 percent by weight dry basis, based on the weight of the fatty acid.
Claim 14
Dependent Claim
80 words
Stabilized fatty acids comprising a fatty acid having a chain length of C 6 to C 24 and an effective amount sufficient to inhibit oxidation of a stabilizer, said stabilizer being an alkali metal salt of an organic phosphate ester, said ester being the condensation reaction product of an alcohol and a phosphorus compound, said phosphorus compound being in the pentavalent state during said condensation reaction, said alcohol being selected from the group consisting of poly-alkylene alcohols and hydrocarbyl polyols.
Claim 15
Dependent Claim
80 words
Stabilized fatty acids comprising a fatty acid having a chain length of C 6 to C 24 and an effective amount sufficient to inhibit oxidation of a stabilizer, said stabilizer being an alkali metal salt of an organic phosphate ester, said ester being the condensation reaction product of an alcohol and a phosphorus compound, said phosphorus compound being in the pentavalent state during said condensation reaction, said alcohol being selected from the group consisting of poly-alkylene alcohols and hydrocarbyl polyols.
Claim 16
Dependent Claim
42 words
Stabilized fatty acids in accordance with claim 13 wherein said phosphorus compound is selected from the group consisting of polyphosphoric acid, phosphorus oxychloride, phosphorus pentoxide and inorganic phosphorus salts selected from the group consisting of potassium monohydrogen phosphate and potassium dihydrogen phosphate.
Claim 17
Dependent Claim
82 words
Stabilized fatty acids in accordance with claim 13 wherein said polyalkylene alcohol is selected from the group consisting of alcohol ethers which have the formula R.sub.1 --OR.sub.2 --.sub.X OH where R 1 is selected from the group consisting of hydrogen, C 1 to C 4 straight or branched chain alkyl, phenyl, cresyl, ethyl-phenyl and mixtures thereof, and R 2 is selected from the group consisting of ethylene, propylene, isopropylene, butylene and mixtures thereof and X is a number from 1 to 30.
Claim 18
Dependent Claim
17 words
Stabilized fatty acids in accordance with claim 15 wherein X is a number from 1 to 10.
Claim 19
Dependent Claim
17 words
Stabilized fatty acids in accordance with claim 15 wherein X is a number from 1 to 6.
Claim 20
Dependent Claim
59 words
Stabilized fatty acids in accordance with claim 13 wherein said polyalkylene alcohol is selected from the group consisting of di-, tri-, tetra- and penta-ethylene glycol mono-phenyl ether, di-, tri-, tetra- and penta-ethylene glycol mono-cresyl ether, di-, tri-, tetra-, and penta-ethylene glycol mono-(ethyl-phenyl) ether, the propylene, isopropylene and butylene equivalents of the foregoing ethylene glycol phenyl ethers and mixtures thereof.
Claim 21
Dependent Claim
23 words
Stabilized fatty acids in accordance with claim 13 wherein said polyols have a carbon chain length of C 2 to C 6 .
Claim 22
Dependent Claim
44 words
Stabilized fatty acids in accordance with claim 13 wherein said polyols are selected from the group consisting of ethylene glycol, propylene glycol, glycerol, pentaerythritol, 1,5-pentanediol, 1,3-butanediol, 1,4-butanediol, 2,3,-butanediol, 1,2,4,-butanetriol, 4-methyl 2,4-pentanediol, 1,6-hexanediol, 2,5,-hexanediol, erythritol, xylitol, arabitol, adonitol, sorbitol, mannitol, galactitol, inositol, and mixtures thereof.
Claim 23
Dependent Claim
47 words
Stabilized fatty acids in accordance with claim 13 wherein said alkali metal salt of said condensation reaction product contains from about 5 to about 15 percent by weight, dry basis, of phosphorus and from about 10 to about 30 percent by weight, dry basis, of alkali metal.
Claim 24
Dependent Claim
22 words
Stabilized fatty acids in accordance with claim 13 wherein said alkali metal is selected from the group consisting of potassium and sodium.
Claim 25
Dependent Claim
14 words
Stabilized fatty acids in accordance with claim 13 wherein said alkali metal is potassium.
Claim 26
Dependent Claim
36 words
Stabilized fatty acids in accordance with claim 13 wherein said stabilizer is present at a level of from about 0.005 to about 0.05 percent by weight, dry basis, based on the weight of the fatty acid.
References Cited (Backward Citations)
US2926093A
Cited
US3812220A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-05-25 | 1979-11-24 | 1980-05-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-05-25 | 1983-11-24 | 1984-05-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-05-25 | 1987-11-24 | 1988-05-25 | $7700.00 | Window Closed / Lapsed |