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US3959093A Expired / Lapsed US ⏱️ 0.0 years remaining

Aluminum hydrates and salts of carboxylic acids

Assignee: Individual
•
Filing: 1974-05-13
•
Granted: 1976-05-25
•
Expires: 1994-05-13
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Abstract

Abstract Aluminum salts of a carboxylic acid selected from the group consisting of ascorbic acid, acetic acid, and citric acid are formed by contacting the carboxylic acid with activated aluminum. The activated aluminum is formed by combining highly pure aluminum with another metal which has an affinity for hydrogen in the presence of a proton source. Typically, the other metal can be gallium and the proton source can be hydrochloric acid. Included in the aluminum salts which can be formed are polymeric aluminum salts.

Inventors

  • 👤 George G. Merkl

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 19:12
CPC Classifications
C; C07; C07F; C07F5/00; C07F5/06; C07F5/069

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 76 words
A method of preparing an aluminum-carboxylic acid compound which comprises: reacting by contacting, in the presence of water: a. activated aluminum comprising high purity metallic aluminum permeated with a metal selected from mercury, indium, gallium and alloys of indium and gallium; with b. a carboxylic acid selected from acetic acid, ascorbic acid and citric acid; whereby the aluminum of said activated aluminum is consumed in reaction with said carboxylic acid, thereby forming said aluminum-carboxylic acid compound.
Claim 2
Independent Claim 76 words
A method of preparing an aluminum-carboxylic acid compound which comprises: reacting by contacting, in the presence of water: a. activated aluminum comprising high purity metallic aluminum permeated with a metal selected from mercury, indium, gallium and alloys of indium and gallium; with b. a carboxylic acid selected from acetic acid, ascorbic acid and citric acid; whereby the aluminum of said activated aluminum is consumed in reaction with said carboxylic acid, thereby forming said aluminum-carboxylic acid compound.
Claim 3
Dependent Claim 18 words
The method of claim 1, wherein said aluminum has a purity of at least about 99.99% by weight.
Claim 4
Dependent Claim 34 words
The method of claim 1, wherein said activated aluminum and carboxylic acid are reacted in the presence of an excess of water, based upon the water of crystallization of the formed aluminum-carboxylic acid compound.
Claim 5
Dependent Claim 16 words
The method of claim 3, wherein the reaction is carried out at room temperature or below.
Claim 6
Dependent Claim 16 words
The method of claim 3, wherein the pH of the reaction medium is less than 4.2.
Claim 7
Dependent Claim 28 words
The method of claim 1, wherein the activated aluminum comprises highly pure aluminum permeated with from 1 to 3% by weight of an alloy of indium and gallium.

References Cited (Backward Citations)

US535464A Cited
US1427011A Cited
US1863254A Cited
US2042019A Cited
US2275211A Cited
US3578439A Cited
US3574607A Cited
US3856841A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-05-25 1979-11-24 1980-05-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-05-25 1983-11-24 1984-05-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-05-25 1987-11-24 1988-05-25 $7700.00 Window Closed / Lapsed

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