Liquid crystal compositions and devices

Claim 2

A liquid crystal composition having a nematic range of at least ±50°C of room temperature comprising five compounds wherein three of the compounds are different members of the homologous series having the general formula ##SPC2## wherein n is an integer from 0 to 3 and m is an integer from 0 to 5, each member being present in an amount ranging from 4 to 80 percent by weight based on the total weight of the three members, and the other two compounds are p-methoxybenzylidene-p'-n-butylaniline and p-ethoxybenzylidene-p'-n-butylaniline, each of the two other compounds being present in an amount ranging from 30 to 70 percent by weight based on the total weight of the two compounds, and wherein the total weight of the three members of the homologous series represents from 40 to 70 percent of the total weight of the composition and the total weight of two other compounds represents from 30 to 60 percent of the total weight of the composition.

Claim 3

The composition of claim 1 wherein the total weight of the three members of the homologous series represents from 50 to 70 percent of the total weight of the composition, and the total weight of the other two of the five compounds represents from 30 to 50 percent of the total weight of the composition.

Claim 4

The composition of claim 2 wherein each of the two other compounds are present in an amount ranging from 40 to 60 percent by weight based on the total weight of the two compounds.

Claim 5

The composition of claim 3 wherein m is an integer from 0 to 3.

Claim 6

The composition of claim 4 wherein the total weight of the three members of the homologous series represents from 55 to 65 percent of the total weight of the composition, and the total weight of the other two of the five compounds represents from 35 to 45 percent of the total weight of the composition.

Claim 7

The composition of claim 5 wherein each of the other two compounds are present in an amount ranging from 45 to 55 percent by weight based on the total weight of the two compounds.

Claim 8

The composition of claim 6 wherein the three members of the homologous series are the member wherein n is 0 and m is 0, the member wherein n is 3 and m is 0, and the member wherein n is 0 and m is 2.

Claim 9

The composition of claim 7 wherein the three members are present in the relative proportions indicated in FIG. 1.

Claim 10

The composition of claim 1 including about 0.050 to 0.2 percent by weight of p-methoxybenzylidene-p'-aminophenol and about 0.005 to 0.02 percent by weight of a quaternary ammonium salt having the formula RR'R 2 "N +X - wherein R is an alkyl group having 10 to 24 carbon atoms, R' is methyl or ethyl, R" is methyl, or R' and R" together form a pyridine ring, and X - is an anion derived from a simple acid.

Claim 11

The composition of claim 8 including about 0.050 to 0.2 percent by weight of p-methoxybenzylidene-p'-aminophenol and about 0.005 to 0.02 percent by weight of a quaternary ammonium salt having the formula RR'R 2 "N +X - wherein R is an alkyl group having 10 to 24 carbon atoms, R' is methyl or ethyl, R" is methyl, or R' and R" together form a pyridine ring, and X - is an anion derived from a simple acid.

Claim 12

In an electro-optical display device comprising a layer of a nematic liquid crystal composition between two substrates, one substrate being optically transmissive and having an electrically conductive coating on one face, the other substrate having an electrically conductive coating on one face and positioned such that the coatings are adjacent and substantially equidistantly spaced, and means for creating an electric field between selected portions of the coatings, the improvement wherein the liquid crystal composition has a nematic range of at least ± 50°C of room temperature and comprises five compounds wherein three of the compounds are different members of the homologous series having the general formula ##SPC3## wherein n is an integer from 0 to 3 and n is an integer from 0 to 5, each member being present in an amount ranging from 4 to 80 percent by weight based on the total weight of the three members, and the other two compounds are p-methoxybenzylidene-p'-nbutylaniline and p-ethoxybenzylidene-p'-n-butylaniline, each of the two other compounds being present in an amount ranging from 30 to 70 percent by weight based on the total weight of the two compounds, and wherein the total weight of the three members of the homologous series represents from 40 to 70 percent of the total weight of the composition and the total weight of two other compounds represents from 30 to 60 percent of the total weight of the composition.

Claim 13

In an electro-optical display device comprising a layer of a nematic liquid crystal composition between two substrates, one substrate being optically transmissive and having an electrically conductive coating on one face, the other substrate having an electrically conductive coating on one face and positioned such that the coatings are adjacent and substantially equidistantly spaced, and means for creating an electric field between selected portions of the coatings, the improvement wherein the liquid crystal composition has a nematic range of at least ± 50°C of room temperature and comprises five compounds wherein three of the compounds are different members of the homologous series having the general formula ##SPC3## wherein n is an integer from 0 to 3 and n is an integer from 0 to 5, each member being present in an amount ranging from 4 to 80 percent by weight based on the total weight of the three members, and the other two compounds are p-methoxybenzylidene-p'-nbutylaniline and p-ethoxybenzylidene-p'-n-butylaniline, each of the two other compounds being present in an amount ranging from 30 to 70 percent by weight based on the total weight of the two compounds, and wherein the total weight of the three members of the homologous series represents from 40 to 70 percent of the total weight of the composition and the total weight of two other compounds represents from 30 to 60 percent of the total weight of the composition.

Claim 14

The device of claim 11 wherein the total weight of the three members of the homologous series represents from 50 to 70 percent of the total weight of the composition, and the total weight of the other two of the five compounds represents from 30 to 50 percent of the total weight of the composition.

Claim 15

The device of claim 12 wherein each of the two other compounds are present in an amount ranging from 40 to 60 percent by weight based on the total weight of the two compounds.

Claim 16

The device of claim 13 wherein m is an integer from 0 to 3.

Claim 17

The device of claim 14 wherein the total weight of the three members of the homologous series represents from 55 to 65 percent of the total weight of the composition, and the total weight of the other two of the five compounds represent from 35 to 45 percent of the total weight of the composition.

Claim 18

The device of claim 15 wherein each of the other two compounds are present in an amount ranging from 45 to 55 percent by weight based on the total weight of the two compounds.

Claim 19

The device of claim 16 wherein the three members of the homologous series are the member wherein n is 0 and m is 0, the member wherein n is 3 and m is 0, and the member wherein n is 0 and m is 2.

Claim 20

The device of claim 17 wherein the three members are present in the relative proportions indicated in FIG. 1.

Claim 21

The device of claim 11 wherein the liquid crystal composition includes about 0.050 to 0.2 percent by weight of p-methoxybenzylidene-p'-aminophenol and about 0.005 to 0.02 percent by weight of a quaternary ammonium salt having the formula RR'R 2 "N +X - wherein R is an alkyl group having 10 to 24 carbon atoms, R' is methyl or ethyl, R" is methyl, or R' and R" together form a pyridine ring, and X - is an anion derived from a simple acid.

Claim 22

The device of claim 18 wherein the liquid crystal composition includes about 0.050 to 0.2 percent by weight of p-methoxybenzylidene-p'-aminophenol and about 0.005 to 0.02 percent by weight of a quaternary ammonium salt having the formula RR'R 2 "N +X - wherein R is an alkyl group having 10 to 24 carbon atoms, R' is methyl or ethyl, R" is methyl, or R' and R" together form a pyridine ring, and X - is an anion derived from a simple acid.