US3956149A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Nitrogen-containing esters and lubricants containing same
Assignee: Lubrizol Corp
•
Filing: 1971-10-06
•
Granted: 1976-05-11
•
Expires: 1991-10-06
Abstract
Abstract This invention is directed to a nitrogen-containing ester of a carboxy-interpolymer having a reduced specific viscosity ranging from about 0.05 to 2.0. The carboxy-interpolymers, from which the nitrogen-containing esters are obtained, are derived from at least one monomer selected from the class consisting of aliphatic olefins and styrene and at least one monomer comprising an unsaturated carboxylic acid, the anhydride or ester thereof. The nitrogen-containing ester may be characterized as having in the polymeric structure carboxylic-ester groups derived from a high molecular weight alcohol having at least 7 aliphatic carbon atoms and carbonyl-polyamino groups derived from hydrazine or a hydrocarbon-substituted hydrazine. The nitrogen-containing ester may be used alone or in combination with other additives in small but effective amounts in various oleaginous materials including lubricants and fuels.
Inventors
- 👤 Lester E. Coleman
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 23:20
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/22; C10L1/234; C10L1/236; C10L1/2364; C08; C08F; C08F8/00; C08F8/30; C10M; C10M145/00; C10M145/02; C10M145/10; C10M145/16; C10M149/00; C10M149/02; C10M149/06; C10M2203/00; C10M2203/06; C10M2205/00; C10M2205/02; C10M2205/026; C10M2207/00; C10M2207/28; C10M2207/281; C10M2207/282; C10M2207/283; C10M2207/286; C10M2207/34; C10M2207/40; C10M2207/402; C10M2207/404; C10M2209/00; C10M2209/02; C10M2209/10; C10M2209/103; C10M2209/104; C10M2209/105; C10M2209/108; C10M2209/109; C10M2209/11; C10M2209/111; C10M2211/00; C10M2211/06; C10M2211/08; C10M2213/00; C10M2213/02; C10M2213/06; C10M2213/062; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/042; C10M2215/08; C10M2215/082; C10M2215/24; C10M2215/26; C10M2215/28; C10M2217/00; C10M2217/02; C10M2217/022; C10M2217/024; C10M2217/06; C10M2219/00; C10M2219/02; C10M2219/022; C10M2219/024; C10M2219/04; C10M2219/044; C10M2219/046; C10M2219/06; C10M2219/062; C10M2219/066; C10M2219/068; C10M2219/08; C10M2219/082; C10M2219/083; C10M2219/087; C10M2219/088; C10M2219/089; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/041; C10M2223/042; C10M2223/045; C10M2223/06; C10M2223/065; C10M2223/12; C10M2225/00; C10M2225/02; C10M2225/04; C10M2225/041; C10M2227/00; C10M2227/02; C10M2227/04; C10M2227/06; C10M2227/061; C10M2229/00; C10M2229/04; C10M2229/041; C10M2229/042; C10M2229/043; C10M2229/044; C10N; C10N2010/00; C10N2010/02; C10N2010/04; C10N2020/00; C10N2020/01; C10N2030/00; C10N2030/12; C10N2040/00; C10N2040/08; C10N2040/20; C10N2040/25; C10N2040/252; C10N2040/253; C10N2040/255; C10N2040/26
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
183 words
A lubricant or fuel composition comprising a major proportion of a lubricating oil or a normally liquid fuel and a minor proportion of an additive sufficient to impart viscosity index and dispersant properties to the composition, said additive being a nitrogen-containing ester of a carboxy-interpolymer having a reduced specific viscosity ranging from about 0.05 to about 2.0, said interpolymer being derived from the interpolymerization of at least one monomer selected from the group consisting of aliphatic olefins having from 2 to about 8 aliphatic carbon atoms and styrene, and at least one monomer selected from the group consisting of an α,β-unsaturated aliphatic carboxylic acid, the anhydride or an ester thereof; and said interpolymer having (A) pendant carboxylic-ester groups derived from the esterification of the carboxy groups of the interpolymer with at least one high molecular weight alcohol having at least 7 aliphatic carbon atoms, and (B) pendant carbonylpolyamino groups derived from the reaction of the carboxy groups of the interpolymer with hydrazine or a hydrocarbon-substituted hydrazine; wherein the molar ratio of (A):(B) is in the range of from about 2:1 to about 50:1.
Claim 2
Dependent Claim
183 words
A lubricant or fuel composition comprising a major proportion of a lubricating oil or a normally liquid fuel and a minor proportion of an additive sufficient to impart viscosity index and dispersant properties to the composition, said additive being a nitrogen-containing ester of a carboxy-interpolymer having a reduced specific viscosity ranging from about 0.05 to about 2.0, said interpolymer being derived from the interpolymerization of at least one monomer selected from the group consisting of aliphatic olefins having from 2 to about 8 aliphatic carbon atoms and styrene, and at least one monomer selected from the group consisting of an α,β-unsaturated aliphatic carboxylic acid, the anhydride or an ester thereof; and said interpolymer having (A) pendant carboxylic-ester groups derived from the esterification of the carboxy groups of the interpolymer with at least one high molecular weight alcohol having at least 7 aliphatic carbon atoms, and (B) pendant carbonylpolyamino groups derived from the reaction of the carboxy groups of the interpolymer with hydrazine or a hydrocarbon-substituted hydrazine; wherein the molar ratio of (A):(B) is in the range of from about 2:1 to about 50:1.
Claim 3
Dependent Claim
33 words
The lubricant or fuel composition of claim 1, wherein the molar ratio of the carboxylic-ester groups (A) to the carbonyl-polyamino groups (B) is in the range of from about 3:1 to about 20:1.
Claim 4
Dependent Claim
35 words
The lubricant or fuel composition of claim 1, wherein the carboxy-interpolymer is derived from styrene and maleic acid or the anhydride thereof, and has a reduced specific viscosity of from about 0.3 to about 1.0.
Claim 5
Dependent Claim
39 words
The lubricant or fuel composition of claim 1, wherein the carboxy-ester groups are derived from a high molecular weight alcohol having from 7 to about 40 aliphatic carbon atoms and the carbonyl-polyamino groups are derived from a N,N-dihydrocarbon-substituted hydrazine.
Claim 6
Dependent Claim
16 words
The lubricant or fuel composition of claim 1, wherein the carbonyl-polyamino groups are derived from hydrazine.
Claim 7
Dependent Claim
47 words
The lubricant or fuel composition of claim 1, wherein the carboxy-interpolymer is derived from the interpolymerization of about 1.0 molar proportion of styrene, about 1.0 molar proportion of maleic acid or anhydride, and from about 0 to about 0.3 molar proportion of at least one vinyl monomer.
Claim 8
Dependent Claim
15 words
The lubricant or fuel composition of claim 6, wherein the vinyl monomer comprises vinyl acetate.
Claim 9
Dependent Claim
29 words
The lubricant or fuel composition of claim 1, wherein the carboxy-ester groups are derived from a high molecular weight alcohol having from 7 to about 24 aliphatic carbon atoms.
Claim 10
Dependent Claim
27 words
The lubricant or fuel composition of claim 1, wherein the carboxy-interpolymer is derived from a low molecular weight aliphatic olefin and maleic acid or the anhydride thereof.
Claim 11
Dependent Claim
22 words
The lubricant or fuel composition of claim 1, wherein the carboxy-interpolymer is derived from styrene and maleic acid or the anhydride thereof.
Claim 12
Dependent Claim
74 words
The lubricant or fuel composition of claim 1, wherein the nitrogen-containing ester was prepared by esterifying at least about 50 mole percent of the carboxy groups of the carboxy-interpolymer with a high molecular weight alcohol having at least 7 aliphatic carbon atoms to obtain a partially esterified carboxy-interpolymer and subsequently reacting said partially esterified carboxy-interpolymer with an amount of hydrazine or a hydrocarbon-substituted hydrazine sufficient to neutralize the unesterified carboxy groups of the interpolymer.
Claim 13
Dependent Claim
31 words
The lubricant or fuel composition of claim 11, wherein the nitrogen-containing ester has from about 50 to 98 mole percent of the carboxy groups esterified with the high molecular weight alcohol.
Claim 14
Dependent Claim
29 words
The lubricant or fuel composition of claim 1, wherein the nitrogen-containing ester of the carboxy-interpolymer is present in an amount ranging from about 0.001% to about 25% by weight.
Claim 15
Dependent Claim
154 words
A lubricant or fuel composition comprising a major proportion of lubricating oil or normally liquid fuel and a minor proportion of an additive sufficient to impart viscosity index and dispersant properties to the composition, said additive being a nitrogen-containing ester of a styrene-maleic acid interpolymer having a reduced specific viscosity ranging from about 0.05 to about 2.0, the interpolymer being substantially free of carboxylic-acid groups and having (A) pendant carboxylic-ester groups derived from the esterification of the carboxy groups of the interpolymer with at least one high molecular weight alcohol having from 7 to about 24 carbon atoms, and (B) pendant carbonylpolyamino groups derived from the reaction of the carboxy groups of the interpolymer with hydrazine or a hydrocarbon-substituted hydrazine; wherein the molar ratio of (A):(B) is in the range of from about 2:1 to about 50:1, and the carboxylic-acid groups are present in the range of from about 0 to 2 molar percent.
Claim 16
Dependent Claim
154 words
A lubricant or fuel composition comprising a major proportion of lubricating oil or normally liquid fuel and a minor proportion of an additive sufficient to impart viscosity index and dispersant properties to the composition, said additive being a nitrogen-containing ester of a styrene-maleic acid interpolymer having a reduced specific viscosity ranging from about 0.05 to about 2.0, the interpolymer being substantially free of carboxylic-acid groups and having (A) pendant carboxylic-ester groups derived from the esterification of the carboxy groups of the interpolymer with at least one high molecular weight alcohol having from 7 to about 24 carbon atoms, and (B) pendant carbonylpolyamino groups derived from the reaction of the carboxy groups of the interpolymer with hydrazine or a hydrocarbon-substituted hydrazine; wherein the molar ratio of (A):(B) is in the range of from about 2:1 to about 50:1, and the carboxylic-acid groups are present in the range of from about 0 to 2 molar percent.
Claim 17
Dependent Claim
21 words
The lubricant or fuel composition of claim 14, wherein the molar ratio of (A):(B) is from about 3:1 to about 20:1.
Claim 18
Dependent Claim
74 words
The lubricant or fuel composition of claim 14, wherein the carboxylic-ester groups are derived from the esterification of about 50 to 98 molar percent of the carboxy groups of the interpolymer with at least one high molecular weight alcohol having from 7 to about 24 aliphatic carbon atoms, and subsequently reacting the partially esterified interpolymer with an amount of hydrazine or a hydrocarbon-substituted hydrazine sufficient to neutralize the unesterified carboxy groups of the interpolymer.
Claim 19
Dependent Claim
29 words
The lubricant or fuel composition of claim 14, wherein the nitrogen-containing ester of the interpolymer is present in an amount ranging from about 0.001% to about 25% by weight.
Claim 20
Dependent Claim
117 words
A lubricant or fuel composition comprising a major proportion of lubricating oil or normally liquid fuel and from about 0.001% to about 25% by weight of a nitrogen-containing ester of a styrene-maleic acid interpolymer having a reduced specific viscosity ranging from about 0.05 to about 2.0, the interpolymer having (A) pendant carboxylic-ester groups derived from the esterification of the carboxy groups of the interpolymer with at least one alcohol having from 7 to about 24 aliphatic carbon atoms, and (B) pendant carbonyl-polyamino groups derived from the reaction of the carboxy groups of the interpolymer with hydrazine or a hydrocarbon-substituted hydrazine; wherein the molar ratio of (A):(B) is in the range of from about 3:1 to about 20:1.
Claim 21
Dependent Claim
117 words
A lubricant or fuel composition comprising a major proportion of lubricating oil or normally liquid fuel and from about 0.001% to about 25% by weight of a nitrogen-containing ester of a styrene-maleic acid interpolymer having a reduced specific viscosity ranging from about 0.05 to about 2.0, the interpolymer having (A) pendant carboxylic-ester groups derived from the esterification of the carboxy groups of the interpolymer with at least one alcohol having from 7 to about 24 aliphatic carbon atoms, and (B) pendant carbonyl-polyamino groups derived from the reaction of the carboxy groups of the interpolymer with hydrazine or a hydrocarbon-substituted hydrazine; wherein the molar ratio of (A):(B) is in the range of from about 3:1 to about 20:1.
Claim 22
Dependent Claim
27 words
The lubricating composition of claim 18, wherein the nitrogen-containing ester of the interpolymer is present in an amount ranging from about 1.0% to about 25% by weight.
Claim 23
Dependent Claim
27 words
The fuel composition of claim 18, wherein the nitrogen-containing ester of the interpolymer is present in an amount ranging from about 0.001% to about 1.0% by weight.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-05-11 | 1979-11-10 | 1980-05-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-05-11 | 1983-11-10 | 1984-05-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-05-11 | 1987-11-10 | 1988-05-11 | $7700.00 | Window Closed / Lapsed |