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US3955268A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of fabricating an electrolytic cell gas sensor

Assignee: Individual
•
Filing: 1974-09-13
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Granted: 1976-05-11
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Expires: 1994-09-13
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Abstract

Abstract A Solid State Electrolytic Cell Gas Sensor is presented which is capable of measuring various toxic or combustible gases in low concentrations (0-5 PPM) up to and including high concentrations such as 0-20 percent by volume. The sensor exhibits excellent specificity to the gas designated to be detected. The sensor causes the dissociation of the gases into charged species such as ions and complex ions and does not operate by changing its electro-conductivity in response to the adsorption of the gas. The sensor has an electrical signal which is a function of the type and concentration of gas and which is also a function of the collection of ions by transport process. The solid state material from which the sensor is fabricated is produced by the method of addition of one or more metal oxides to a non-metal oxide with a general formula of MxOy - NpOq. M can be a metal from the transition elements and N can be a non-metal of group III and IV from the periodic table. The sensor comprises a collector and a heater element made from a stable metal such as platinum. A material such as stannic oxide may be mixed with a material such as silica gel. The combination may be heated and dried and dissolved in an alcohol and water solution. The resulting combination is then coupled to the heater wire and to the collector wire and heated to form the finished sensor.

Inventors

  • 👤 Chen-Yen Chou
  • 👤 Su-Chin Chou

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 02:15
CPC Classifications
G; G01; G01N; G01N33/00; G01N33/0004; G01N33/0009; G01N33/0027; G01N27/00; G01N27/26; G01N27/403; G01N27/406; G01N27/4067; G01N27/407; G01N27/4073; G01N27/4074; H; H01; H01G; H01G9/00; H01G9/16; Y; Y10; Y10T; Y10T436/00; Y10T436/18; Y10T436/182; Y10T436/184; Y10T436/20; Y10T436/204998; Y10T436/205831

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 204 words
The method of fabricating a solid state electrolytic cell gas sensor head for detecting gases by dissociating the gases into species such as ions and complex ions and using either to generate an electrical signal, comprising: adding at least one metal oxide having a general formula MxOy, where M is a transition element metal, to a non-metal oxide having a general formula NpOq, where N is a non-metal selected from groups III and IV of the periodic table, and x, y, p and q are relatively small whole numbers; heating the mixture of MxOy - NpOq until dry and activated; adding a sufficient quantity of solvent to the mixture of MxOy - NpOq to form a paste; adding a small amount of platinum family oxide to the paste; coating a first quantity of the paste onto a fine, chemically inert, strong and ductile heating wire; inserting the coated heater wire into a space partially defined by a collector wire and then coating the assembly of the heater wire and the collector wire with the paste to form a bead with both wires therein; drying the paste; and baking the paste at at least one temperature in excess of 200°C to form the sensor head.
Claim 2
Independent Claim 204 words
The method of fabricating a solid state electrolytic cell gas sensor head for detecting gases by dissociating the gases into species such as ions and complex ions and using either to generate an electrical signal, comprising: adding at least one metal oxide having a general formula MxOy, where M is a transition element metal, to a non-metal oxide having a general formula NpOq, where N is a non-metal selected from groups III and IV of the periodic table, and x, y, p and q are relatively small whole numbers; heating the mixture of MxOy - NpOq until dry and activated; adding a sufficient quantity of solvent to the mixture of MxOy - NpOq to form a paste; adding a small amount of platinum family oxide to the paste; coating a first quantity of the paste onto a fine, chemically inert, strong and ductile heating wire; inserting the coated heater wire into a space partially defined by a collector wire and then coating the assembly of the heater wire and the collector wire with the paste to form a bead with both wires therein; drying the paste; and baking the paste at at least one temperature in excess of 200°C to form the sensor head.
Claim 3
Dependent Claim 55 words
The method of claim 1 wherein the metal oxide is stannic oxide, the non-metal oxide is silica gel made from sodium silicate, the stannic oxide and silica gel are mixed in the ratio of 6:1; and the mixture of stannic oxide and silica gel is dried and activated at a temperature between 200°C and 300°C.
Claim 4
Dependent Claim 44 words
The method of claim 1 wherein the solvent added to the mixture of MxOy - NpOq comprises two parts of alcohol and one part of water and the small amount of platinum family oxide added to the paste comprises 2 percent Pt 2 O.
Claim 5
Dependent Claim 90 words
The method of claim 1 wherein the heating wire comprises platinum family wire 2 mils in diameter and a 10 turn helix coil and the collector wire comprises platinum family wire 5 mils in diameter and a 6 turns helix coil and the heating wire is inserted inside the space defined by the coiled collector wire and the paste forms a bead completely covering a segment of the collector wire having the heating wire inserted therein and the space within the coils of the collector wire is filled with paste.
Claim 6
Dependent Claim 31 words
The invention of claim 1 wherein the heater element comprises 2 mils diameter, 10 turn coil platinum family wire and the collector comprises a plate fabricated from a platinum family foil.
Claim 7
Dependent Claim 46 words
The invention of claim 1 wherein the heater element comprises 2 mils diameter, 10 turn coil platinum family wire and the collector comprises a platinum family coiled wire having a segment of the coil adjacent the heating coil smashed down so as to form a plate.
Claim 8
Dependent Claim 46 words
The method of claim 1 wherein the bead is dried under infra-red light for 48 hours, then baked in an oven at 250°C for 4 hours, then baked in the oven at 450°C for 1 hour, then baked in the oven at 600°C for 1 hour.

References Cited (Backward Citations)

US3200011A Cited
US3564474A Cited
US3625756A Cited
US3644795A Cited
US3865550A Cited
US3732519A Cited
US3751968A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-05-11 1979-11-10 1980-05-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-05-11 1983-11-10 1984-05-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-05-11 1987-11-10 1988-05-11 $7700.00 Window Closed / Lapsed

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