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US3954900A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat hardening mixtures

Assignee: Cassella Farbwerke Mainkur AG
•
Filing: 1975-03-24
•
Granted: 1976-05-04
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Expires: 1995-03-24
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Abstract

Abstract High quality coatings and the like are formed from dispersions in a reactive liquid of finely divided solid isocyanated polyester resin having isocyanate groups part of which are masked but become unmasked upon heating and then react with the liquid. The liquid is essentially one or more highly etherified methylolated aminotriazine in which some of etherifying is with alkoxyethyl groups that provide relatively low viscosity and good reactivity.

Inventors

  • 👤 Wolfgang Schmalz
  • 👤 Walter Michel
  • 👤 Manfred Schon

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 11:36
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/70; C08G18/72; C08G18/80; C08G18/8061; C08G18/807; C08G18/8074; C08G18/28; C08G18/40; C08G18/54; C08G18/544; C09; C09D; C09D175/00; C09D175/04; C09D175/06

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 218 words
A heat-hardenable dispersion of a finely divided solid resin in liquid etherified methylolaminotriazine in which liquid the degree of methylolation averages at least about 50 percent, the degrees of etherification of the methylol groups averages at least about 70%, and about 20 to 80 mol percent of the etherifying groups are alkyl groups with up to 2 carbon atoms, the remaining etherifying groups being alkoxyethyl groups having alkoxy moieties with up to 4 carbon atoms; the resin being an uncured mixture of about 30 to about 45% by weight of a polyester condensate with an average molecular weight about 500 to about 6000, an acid number below about 20, an OH number about 400 to about 800 and a softening temperature about 80° to about 150°C, the balance of the resin being essentially a polyurethane-forming polyisocyanate at least about half of whose isocyanate groups are masked with a lactam-masking agent that unmasks on heating to curing temperature; the polyester condensate being essentially the polyester of (a) a mixture of isophthalic and terephthalic acids in which about 10 to about 90 mol percent is isophthalic acid, and (b) at least one saturated aliphatic polyol having 4 to 6 OH groups; and the resin being present in an amount from about 20 to about 500% by weight of the liquid.
Claim 2
Dependent Claim 218 words
A heat-hardenable dispersion of a finely divided solid resin in liquid etherified methylolaminotriazine in which liquid the degree of methylolation averages at least about 50 percent, the degrees of etherification of the methylol groups averages at least about 70%, and about 20 to 80 mol percent of the etherifying groups are alkyl groups with up to 2 carbon atoms, the remaining etherifying groups being alkoxyethyl groups having alkoxy moieties with up to 4 carbon atoms; the resin being an uncured mixture of about 30 to about 45% by weight of a polyester condensate with an average molecular weight about 500 to about 6000, an acid number below about 20, an OH number about 400 to about 800 and a softening temperature about 80° to about 150°C, the balance of the resin being essentially a polyurethane-forming polyisocyanate at least about half of whose isocyanate groups are masked with a lactam-masking agent that unmasks on heating to curing temperature; the polyester condensate being essentially the polyester of (a) a mixture of isophthalic and terephthalic acids in which about 10 to about 90 mol percent is isophthalic acid, and (b) at least one saturated aliphatic polyol having 4 to 6 OH groups; and the resin being present in an amount from about 20 to about 500% by weight of the liquid.
Claim 3
Dependent Claim 74 words
The combination of claim 1 in which the liquid is essentially a mixture of etherified methylolated triamino triazines and the polyester condensate is the polyester of the phthalic acids and the polyol as well as of at least one alkylene glycol whose hydroxyl groups are on non-adjacent carbons, the glycol content being not over about 30 mol percent of the total polyol, and the dispersion also contains an effective amount of a urethane-forming accelerator.
Claim 4
Dependent Claim 19 words
The combination of claim 1 in which the polyester has a molecular weight of about 1200 to about 2500.
Claim 5
Dependent Claim 19 words
The combination of claim 1 in which the polyester has an acid number of about 1 to about 5.
Claim 6
Dependent Claim 19 words
The combination of claim 2 in which the polyester has an OH number of about 600 to about 700.
Claim 7
Dependent Claim 12 words
The combination of claim 1 in which the masking is with epsilon-caprolactam.
Claim 8
Dependent Claim 11 words
The combination of claim 1 in which the polyol is pentaerythritol.
Claim 9
Dependent Claim 11 words
The combination of claim 2 in which the glycol is hexanediol-1,6.
Claim 10
Dependent Claim 24 words
The combination of claim 1 in which the urethane-forming polyisocyanate is selected from the class consisting of hexamethylene diisocyanate, methylcyclohexylene-2,4-diisocyanate, toluylene diisocyanate and 3-isocyanatomethyl-3,5,5-trimethylcyclohexylisocyanate.
Claim 11
Dependent Claim 25 words
The combination of claim 1 in which the resin is present in an amount from about 30 to about 250% by weight of the liquid.
Claim 12
Dependent Claim 15 words
The combination of claim 1 in which the liquid phase consists of etherified hexamethylol melamines.
Claim 13
Dependent Claim 15 words
The combination of claim 1 in which the liquid phase consists of etherified pentamethylol melamines.
Claim 14
Dependent Claim 18 words
The combination of claim 1 in which the methylolation degree of the liquid phase is at least 75%.
Claim 15
Dependent Claim 13 words
The combination of claim 2 in which the dispersion also includes dispersed pigment.

References Cited (Backward Citations)

US3597495A Cited
US3822240A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-05-04 1979-11-03 1980-05-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-05-04 1983-11-03 1984-05-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-05-04 1987-11-03 1988-05-04 $7700.00 Window Closed / Lapsed

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