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US3954594A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrochemical cell for decreasing the cyanide and heavy metal content of an aqueous solution

Assignee: Boeing North American Inc
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Filing: 1974-09-04
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Granted: 1976-05-04
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Expires: 1994-09-04
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Abstract

Abstract Apparatus and method are provided for concurrently decreasing the cyanide and heavy metal content of an aqueous solution, such as a waste water. The apparatus comprises an electrochemical cell provided with separate cathode and anode compartments. Each of the compartments contains a bed of electrically conductive particles. The compartments are separated by an electronically nonconductive foraminous member. In accordance with the method, an aqueous solution containing cyanide ion and at least one heavy metal in soluble form is passed sequentially through the beds of electrically conductive particles contained in each of two compartments of an electrochemical cell. A direct electric current is passed between the two compartments making one compartment cathodic and the other anodic. The heavy metal is deposited upon the particles in the cathodic compartment and the cyanide is oxidized in the anodic compartment. The aqueous solution having a substantially reduced cyanide and heavy metal content then is discharged from the electrochemical cell.

Inventors

  • 👤 Howard L. Recht

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 23:57
CPC Classifications
C; C02; C02F; C02F1/00; C02F1/46; C02F1/461; C02F1/46104; C02F1/46109; C02F1/46114; C02F1/467; C02F2101/00; C02F2101/10; C02F2101/16; C02F2101/18; Y; Y10; Y10S; Y10S588/00; Y10S588/90

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 210 words
An electrochemical cell for continuously and concurrently reducing the cyanide and heavy metal content of an aqueous solution containing the same, comprising: a. a cathode compartment having a bed of electrically conductive particles located therein and a first conduit means located adjacent to said bed of particles to provide liquid communication between said cathode compartment and the exterior of the cell; b. an anode compartment having a bed of electrically conductive particles located therein and a second conduit means located adjacent said bed to provide liquid communication between said anode compartment and the exterior of the cell; c. an electronically nonconductive substantially water impermeable foraminous member located intermediate and separating said cathode and anode compartments, said foraminous member having a plurality of openings, said openings having a median size within the range of from about 10.sup. -6 to 10.sup. -14 square centimeters, said member providing free passage of electrically charged ions between said cathode and anode compartments; d. a liquid passageway located in a spaced relation from said first and second conduit means to provide liquid communication between said cathode compartment and anode compartment; and e. electrical means connected to said anode compartment and cathode compartment for maintaining an applied potential to provide passage of a direct electric current therebetween.
Claim 2
Dependent Claim 210 words
An electrochemical cell for continuously and concurrently reducing the cyanide and heavy metal content of an aqueous solution containing the same, comprising: a. a cathode compartment having a bed of electrically conductive particles located therein and a first conduit means located adjacent to said bed of particles to provide liquid communication between said cathode compartment and the exterior of the cell; b. an anode compartment having a bed of electrically conductive particles located therein and a second conduit means located adjacent said bed to provide liquid communication between said anode compartment and the exterior of the cell; c. an electronically nonconductive substantially water impermeable foraminous member located intermediate and separating said cathode and anode compartments, said foraminous member having a plurality of openings, said openings having a median size within the range of from about 10.sup. -6 to 10.sup. -14 square centimeters, said member providing free passage of electrically charged ions between said cathode and anode compartments; d. a liquid passageway located in a spaced relation from said first and second conduit means to provide liquid communication between said cathode compartment and anode compartment; and e. electrical means connected to said anode compartment and cathode compartment for maintaining an applied potential to provide passage of a direct electric current therebetween.
Claim 3
Dependent Claim 17 words
The electrochemical cell of claim 1 wherein the particles located in said cathode compartment have tin surfaces.
Claim 4
Dependent Claim 17 words
The electrochemical cell of claim 2 wherein the particles located in said cathode compartment are particulate tin.
Claim 5
Dependent Claim 17 words
The electrochemical cell of claim 2 wherein the particles located in said cathode compartment are tin-plated substrates.
Claim 6
Dependent Claim 16 words
The electrochemical cell of claim 4 wherein the particles located in said anode compartment are graphite.
Claim 7
Dependent Claim 16 words
The electrochemical cell of claim 1 wherein the particles located in said anode compartment are graphite.
Claim 8
Dependent Claim 32 words
The electrochemical cell of claim 1 wherein said openings in the foraminous member have a median size within the range of from about 10 - 10 to 10 - 12 square centimeters.
Claim 9
Dependent Claim 18 words
The electrochemical cell of claim 7 wherein the particles located in said cathode compartment are particles of tin.
Claim 10
Dependent Claim 18 words
The electrochemical cell of claim 8 wherein the particles located in said anode compartment are particles of graphite.

References Cited (Backward Citations)

US2341356A Cited
US3827964A Cited
US3761369A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-05-04 1979-11-03 1980-05-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-05-04 1983-11-03 1984-05-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-05-04 1987-11-03 1988-05-04 $7700.00 Window Closed / Lapsed

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