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US3954487A Expired / Lapsed US ⏱️ 0.0 years remaining

Chemically hardened spectacle crown glass

Assignee: Schott AG
•
Filing: 1974-10-15
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Granted: 1976-05-04
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Expires: 1994-10-15
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Abstract

Abstract A chemically hardened optical crown glass having a refractive index n d of 1.5225-1,5235, a thermal expansion coefficient in the temperature range between 20° and 300° C. of 90 × 10 - 7 to 100 × 10 - 7 /°C., a dispersion γd of 54-60, a softening temperature of 690°-750° C., and a transformation temperature of 480°-550° C., produced by melting, shaping and cooling a batch consisting essentially of the following composition in parts by weight based on 100 parts of total composition: SiO 2 , 50.5-61.0; Al 2 O 3 , 7.0-17.5; B 2 O 3 , 2.0-6.1; Li 2 O, 0-1.0; Na 2 O, 12.0-15.0; K 2 O, 2.5-3.5; CaO, 0-4.1; BaO, 0-0.3; ZnO, 5.0-10.0; PbO, 0-0.5; TiO 2 , 0.1-0.9; As 2 O 3 , 0-0.5; and Sb 2 O 3 , 0-1.0; and thereafter subjected to an ion exchange in which large alkali metal ions are diffused into the glass in exchange for smaller alkali metal ions at a temperature below the upper cooling temperature which corresponds to a viscosity of 10 13 poises.

Inventors

  • 👤 Georg Gliemeroth
  • 👤 Lothar Meckel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 23:31
CPC Classifications
C; C03; C03C; C03C21/00; C03C21/001; C03C21/002; C03C3/00; C03C3/04; C03C3/076; C03C3/089; C03C3/091; C03C3/093; Y; Y10; Y10T; Y10T428/00; Y10T428/31; Y10T428/315

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 236 words
A chemically hardened optical crown glass having a sharp U-form tension profile, a refractive index n d of 1.5225-1.5235, a thermal expansion coefficient in the temperature range between 20° C. and 300° C. of 90 × 10.sup. -7 to 100 × 10.sup. -7 /° C., a dispersion γd of 54-60, a softening temperature of 690°-750° C., a transformation temperature of 480°-550° C., and a flexural tensile strength of at least 3000 kp/cm 2 produced by melting, shaping and cooling a batch consisting essentially of the following composition in parts by weight based on 100 parts of total composition wherein the sum of the alkali oxides in the composition amounts to 14.5- 18.0% by weight, and wherein the sum of CaO, BaO and ZnO is larger than 6.3 and smaller than 10% by weight: SiO.sub.2 50.5 - 61.0 Al.sub.2 O.sub.3 7.0 - 17.5 B.sub.2 O.sub.3 2.0 - 6.1 Li.sub.2 O 0 - 1.0 Na.sub.2 O 12.0 - 15.0 K.sub.2 O 2.5 - 3.5 CaO 0 - 4.1 BaO 0 - 0.3 ZnO 5.0 - 10.0 PbO 0 - 0.5 TiO.sub.2 0.1 - 0.9 As.sub.2 O.sub.3 0 - 0.5 Sb.sub.2 O.sub.3 0 - 1.0 and thereafter subjecting it to an ion exchange in which potassium, rubidium or cesium ions are diffused into the glass in exchange for smaller alkali metal ions at a temperature below the upper cooling temperature which corresponds to a viscosity of 10 13 poises.
Claim 2
Dependent Claim 236 words
A chemically hardened optical crown glass having a sharp U-form tension profile, a refractive index n d of 1.5225-1.5235, a thermal expansion coefficient in the temperature range between 20° C. and 300° C. of 90 × 10.sup. -7 to 100 × 10.sup. -7 /° C., a dispersion γd of 54-60, a softening temperature of 690°-750° C., a transformation temperature of 480°-550° C., and a flexural tensile strength of at least 3000 kp/cm 2 produced by melting, shaping and cooling a batch consisting essentially of the following composition in parts by weight based on 100 parts of total composition wherein the sum of the alkali oxides in the composition amounts to 14.5- 18.0% by weight, and wherein the sum of CaO, BaO and ZnO is larger than 6.3 and smaller than 10% by weight: SiO.sub.2 50.5 - 61.0 Al.sub.2 O.sub.3 7.0 - 17.5 B.sub.2 O.sub.3 2.0 - 6.1 Li.sub.2 O 0 - 1.0 Na.sub.2 O 12.0 - 15.0 K.sub.2 O 2.5 - 3.5 CaO 0 - 4.1 BaO 0 - 0.3 ZnO 5.0 - 10.0 PbO 0 - 0.5 TiO.sub.2 0.1 - 0.9 As.sub.2 O.sub.3 0 - 0.5 Sb.sub.2 O.sub.3 0 - 1.0 and thereafter subjecting it to an ion exchange in which potassium, rubidium or cesium ions are diffused into the glass in exchange for smaller alkali metal ions at a temperature below the upper cooling temperature which corresponds to a viscosity of 10 13 poises.
Claim 3
Dependent Claim 26 words
An optical crown glass according to claim 1 wherein said ion exchange is effected after the glass has been ground and polished to its final form.
Claim 4
Dependent Claim 15 words
An optical crown glass according to claim 2 wherein said diffused ions are potassium ions.
Claim 5
Dependent Claim 16 words
An optical crown glass according to claim 2 wherein said final form is an eyeglass lens.
Claim 6
Dependent Claim 15 words
An optical crown glass according to claim 4 wherein said diffused ions are potassium ions.
Claim 7
Dependent Claim 85 words
An optical crown glass according to claim 1, wherein said batch has the following composition in parts by weight based on 100 parts of total composition: SiO.sub.2 54.0 - 56.0 Al.sub.2 O.sub.3 10.0 - 16.5 B.sub.2 O.sub.3 2.0 - 3.5 Li.sub.2 O 0 - 1.0 Na.sub.2 O 12.0 - 15.0 K.sub.2 O 3.0 - 3.5 CaO 0 - 1.0 BaO 0 - 0.3 ZnO 8.0 - 10.0 PbO 0 - 0.5 TiO.sub.2 0.6 - 0.9 As.sub.2 O.sub.3 0 - 0.5 Sb.sub.2 O.sub.3 0 - 1.0.
Claim 8
Dependent Claim 60 words
A chemically hardened optical crown glass according to claim 1, consisting essentially of, in weight percent based on the total composition, 50.81%, SiO 2 ; 17.28% Al 2 O 3 ; 4.07% B 2 O 3 ; 14.33% Na 2 O; 3.25% K 2 O; 4.07% CaO; 0.81% TiO 2 ; 5.08% ZnO; and 0.30% As 2 O 3 .
Claim 9
Dependent Claim 60 words
A chemically hardened optical crown glass according to claim 1, consisting essentially of, in weight percent based on the total composition, 56.22% SiO 2 ; 12.11% Al 2 O 3 ; 4.04% B 2 O 3 ; 14.22% Na 2 O; 3.23% K 2 O; 4.01% CaO; 0.81% TiO 2 ; 5.08% ZnO; and 0.30% As 2 O 3 .
Claim 10
Dependent Claim 73 words
A glass consisting essentially of the following composition and in parts by weight based on 100 parts of total composition: SiO 2 , 50.5-61.0; Al 2 O 3 , 7.0-17.5; B 2 O 3 , 2.0-6.1; Bi 2 O, 0-1.0; Na 2 O, 12.0-15.0; K 2 O, 2.5-3.5; CaO, 0-4.1; BaO, 0-0.3; ZnO, 5.0-10.0; PbO, 0-0.5; TiO 2 , 0.1-0.9; As 2 O 3 , 0-0.5; and Sb 2 O 3 , 0-1.0.
Claim 11
Dependent Claim 73 words
A glass consisting essentially of the following composition and in parts by weight based on 100 parts of total composition: SiO 2 , 50.5-61.0; Al 2 O 3 , 7.0-17.5; B 2 O 3 , 2.0-6.1; Bi 2 O, 0-1.0; Na 2 O, 12.0-15.0; K 2 O, 2.5-3.5; CaO, 0-4.1; BaO, 0-0.3; ZnO, 5.0-10.0; PbO, 0-0.5; TiO 2 , 0.1-0.9; As 2 O 3 , 0-0.5; and Sb 2 O 3 , 0-1.0.
Claim 12
Dependent Claim 83 words
A glass composition according to claim 9, consisting essentially of the following components in parts by weight based on 100 parts of total composition: SiO.sub.2 54.0 - 56.0 Al.sub.2 O.sub.3 10.0 - 16.5 B.sub.2 O.sub.3 2.0 - 3.5 Li.sub.2 O 0 - 1.0 Na.sub.2 O 12.0 - 15.0 K.sub.2 O 3.0 - 3.5 CaO 0 - 1.0 BaO 0 - 0.3 ZnO 8.0 - 10.0 PbO 0 - 0.5 TiO.sub.2 0.6 - 0.9 As.sub.2 O.sub.3 0 - 0.5 Sb.sub.2 O.sub.3 0 - 1.0.

References Cited (Backward Citations)

GB812576A Cited
US3301649A Cited
US3357876A Cited
US3740242A Cited
US3524737A Cited
US3772135A Cited
US3790260A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-05-04 1979-11-03 1980-05-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-05-04 1983-11-03 1984-05-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-05-04 1987-11-03 1988-05-04 $7700.00 Window Closed / Lapsed

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