US3953576A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Maximizing conversion of nitrogen oxides in the treatment of combustion exhaust gases
Assignee: Mitsubishi Motors Corp
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Filing: 1974-02-13
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Granted: 1976-04-27
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Expires: 1994-02-13
Abstract
Abstract A three-catalyst process for maximizing the conversion of nitrogen oxides during the treatment of combustion exhaust gases is provided. This process comprises in sequence contacting combustion exhaust gas in a first zone with a nitrogen-oxide-reduction catalyst to form a nitrogen-oxide-reduced gas; introducing a first stream of secondary air into said nitrogen-oxide-reduced gas to form a first air-gas mixture; contacting said first air-gas mixture in a second zone with a catalyst for decreasing ammonia to form a gas containing decreased amounts of ammonia; introducing a second stream of secondary air into said gas containing decreased amounts of ammonia to form a second air-gas mixture; and contacting said second air-gas mixture in a third zone with an oxidation catalyst for the oxidation of carbon monoxide and hydrocarbons to form purified exhaust gas. The first stream of secondary air provides about 3 to about 8 volume percent air, based on the volume of primary air being employed in the combustion, while the second stream of secondary air is sufficient, when added to the oxygen remaining in the gas containing decreased amounts of ammonia, to provide substantially complete oxidation of the carbon monoxide and hydrocarbons in the gas containing decreased amounts of ammonia. The process may be employed to treat automobile exhaust gases.
Inventors
- 👤 Garbis H. Meguerian
- 👤 Yasuo Kaneko
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 21:23
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/92; B01D53/94; B01D53/9459; B01D53/9463; B01D53/9472; B01D53/9404; B01D53/9409; B01D53/9436; B01D53/944; B01D2255/00; B01D2255/10; B01D2255/102; B01D2255/1021; B01D2255/1025; B01D2255/20; B01D2255/207; B01D2255/20753; B01D2255/209; B01D2255/2092; Y; Y02; Y02A; Y02A50/00; Y02A50/20
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
279 words
A process for the purification of exhaust gas from the combustion of hydrocarbon materials to form a purified exhaust gas, which process comprises in sequence contacting said exhaust gas in a first zone with a nitrogen-oxide-reduction catalyst under reducing conditions to form a nitrogen-oxide-reduced gas containing ammonia; introducing a first stream of secondary air into said nitrogen-oxide-reduced gas to form a first air-gas mixture containing air in an amount that is sufficient to enable the ammonia in said first air-gas mixture to be decreased to a minimum level but insufficient to produce appreciable amounts of nitrogen oxides from said ammonia or to enable the hydrocarbons and carbon monoxide present in said first air-gas mixture to be appreciably oxidized, said first stream of secondary air providing about 3 volume percent to about 8 volume percent air, based on the volume of primary air being employed in said combustion; contacting said first air-gas mixture in a second zone with a catalyst for decreasing ammonia to form a gas containing decreased amounts of ammonia; introducing a second stream of secondary air into said gas containing decreased amounts of ammonia to form a second air-gas mixture, said second stream of secondary air being sufficient, when added to the oxygen remaining in said gas containing decreased amounts of ammonia, to provide substantially complete oxidation of the carbon monoxide and hydrocarbons in said gas containing decreased amounts of ammonia; and contacting said second air-gas mixture in a third zone with an oxidation catalyst for the oxidation of carbon monoxide and hydrocarbons to form said purified exhaust gas, said oxidation catalyst being a noble-metal catalyst that is suitable for the oxidation of carbon monoxide and hydrocarbons.
Claim 2
Dependent Claim
279 words
A process for the purification of exhaust gas from the combustion of hydrocarbon materials to form a purified exhaust gas, which process comprises in sequence contacting said exhaust gas in a first zone with a nitrogen-oxide-reduction catalyst under reducing conditions to form a nitrogen-oxide-reduced gas containing ammonia; introducing a first stream of secondary air into said nitrogen-oxide-reduced gas to form a first air-gas mixture containing air in an amount that is sufficient to enable the ammonia in said first air-gas mixture to be decreased to a minimum level but insufficient to produce appreciable amounts of nitrogen oxides from said ammonia or to enable the hydrocarbons and carbon monoxide present in said first air-gas mixture to be appreciably oxidized, said first stream of secondary air providing about 3 volume percent to about 8 volume percent air, based on the volume of primary air being employed in said combustion; contacting said first air-gas mixture in a second zone with a catalyst for decreasing ammonia to form a gas containing decreased amounts of ammonia; introducing a second stream of secondary air into said gas containing decreased amounts of ammonia to form a second air-gas mixture, said second stream of secondary air being sufficient, when added to the oxygen remaining in said gas containing decreased amounts of ammonia, to provide substantially complete oxidation of the carbon monoxide and hydrocarbons in said gas containing decreased amounts of ammonia; and contacting said second air-gas mixture in a third zone with an oxidation catalyst for the oxidation of carbon monoxide and hydrocarbons to form said purified exhaust gas, said oxidation catalyst being a noble-metal catalyst that is suitable for the oxidation of carbon monoxide and hydrocarbons.
Claim 3
Dependent Claim
18 words
The process of claim 1 wherein said exhaust gas is an exhaust gas from an internal combustion engine.
Claim 4
Dependent Claim
40 words
The process of claim 2 wherein said nitrogen-oxide-reduction catalyst comprises nickel and rhodium on a monolithic ceramic support, said catalyst for decreasing ammonia comprises nickel and rhodium on a monolithic ceramic support, and said oxidation catalyst comprises platinum on alumina.
Claim 5
Dependent Claim
270 words
In a process for the purification of exhaust gas from the combustion of hydrocarbon materials wherein said exhaust gas is contacted with a nitrogen-oxide-reduction catalyst in a first zone under reducing conditions to reduce nitrogen oxides and to form a nitrogen-oxide-reduced gas and subsequently said nitrogen-oxide-reduced gas is contacted with an oxidation catalyst in a final zone to oxidize carbon monoxide and hydrocarbons, the improvement which comprises introducing a first stream of secondary air providing about 3 volume percent to about 8 volume percent air, based upon the volume of primary air being employed in said combustion, into said nitrogen-oxide-reduced gas to form a first air-gas mixture, said first stream being present in an amount sufficient to enable the ammonia in said nitrogen-oxide-reduced gas to be decreased to a minimum level but insufficient to produce appreciable amounts of nitrogen oxides from ammonia or to enable the hydrocarbons and carbon monoxide in said nitrogen-oxide-reduced gas to be appreciably oxidized, contacting in an intermediate zone said first air-gas mixture with a catalyst for decreasing ammonia to form a gas containing decreased amounts of ammonia, introducing a second stream of secondary air into said gas containing decreased amounts of ammonia to form a second air-gas mixture, and subsequently passing said second air-gas mixture into said final zone, said catalyst for decreasing ammonia comprising nickel and rhodium on a monolithic ceramic support and said second stream of secondary air being sufficient, when added to the oxygen remaining in said gas containing decreased amounts of ammonia, to provide substantially complete oxidation of the carbon monoxide and hydrocarbons in said gas containing decreased amounts of ammonia.
Claim 6
Dependent Claim
270 words
In a process for the purification of exhaust gas from the combustion of hydrocarbon materials wherein said exhaust gas is contacted with a nitrogen-oxide-reduction catalyst in a first zone under reducing conditions to reduce nitrogen oxides and to form a nitrogen-oxide-reduced gas and subsequently said nitrogen-oxide-reduced gas is contacted with an oxidation catalyst in a final zone to oxidize carbon monoxide and hydrocarbons, the improvement which comprises introducing a first stream of secondary air providing about 3 volume percent to about 8 volume percent air, based upon the volume of primary air being employed in said combustion, into said nitrogen-oxide-reduced gas to form a first air-gas mixture, said first stream being present in an amount sufficient to enable the ammonia in said nitrogen-oxide-reduced gas to be decreased to a minimum level but insufficient to produce appreciable amounts of nitrogen oxides from ammonia or to enable the hydrocarbons and carbon monoxide in said nitrogen-oxide-reduced gas to be appreciably oxidized, contacting in an intermediate zone said first air-gas mixture with a catalyst for decreasing ammonia to form a gas containing decreased amounts of ammonia, introducing a second stream of secondary air into said gas containing decreased amounts of ammonia to form a second air-gas mixture, and subsequently passing said second air-gas mixture into said final zone, said catalyst for decreasing ammonia comprising nickel and rhodium on a monolithic ceramic support and said second stream of secondary air being sufficient, when added to the oxygen remaining in said gas containing decreased amounts of ammonia, to provide substantially complete oxidation of the carbon monoxide and hydrocarbons in said gas containing decreased amounts of ammonia.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-04-27 | 1979-10-27 | 1980-04-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-04-27 | 1983-10-27 | 1984-04-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-04-27 | 1987-10-27 | 1988-04-27 | $7700.00 | Window Closed / Lapsed |