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US3953348A Expired / Lapsed US ⏱️ 0.0 years remaining

Oil-soluble reaction products of intermediate (a) from a high molecular weight olefin polymer, acetonitrile, and chlorine with (b) a piperazine, and lubricant compositions containing the same

Assignee: Ethyl Corp
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Filing: 1975-03-03
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Granted: 1976-04-27
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Expires: 1995-03-03
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Abstract

Abstract Novel addition agents for lubricants, are obtained by reacting a high molecular weight olefin polymer, having an average molecular weight of at least about 600, with acetonitrile and a halogen, for example chlorine, in the presence of a catalyst, such as iodine, for example, to form the intermediate A which is then reacted with a piperazine or aminoalkyl-substituted piperazine.

Inventors

  • 👤 Richard J. Lee

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 22:46
CPC Classifications
C; C10; C10M; C10M1/00; C10M1/08; C08; C08F; C08F8/00; C08F8/30; C08F8/32; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/22; C10M2215/221; C10M2215/223; C10M2215/224; C10M2215/225; C10M2215/226; C10M2215/24; C10M2215/26; C10M2215/30; C10M2217/00; C10M2217/02; C10M2217/026; C10M2217/028; C10M2217/04; C10M2217/046; C10M2217/06

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 134 words
The oil-soluble product prepared by the process comprising, preparing intermediate A by reacting from about 0.3 moles to about 2.5 moles of a high molecular weight olefin polymer having an average molecular weight of at least about 600, with from about 0.5 moles to about 7.5 moles of acetonitrile and from about 0.4 moles to about 2.0 moles of chlorine or bromine in the presence of a catalytic amount of iodine in the absence of light at a temperature of from about 60° to about 160°F. and thereafter reacting intermediate A with piperazine or with (b) an N-aminoalkyl-substituted piperazine at a temperature of from about 200° to about 350°F. for about 1-6 hours, said amine being used in an amount to provide sufficient amine groups to replace the halogen atoms in said intermediate (A).
Claim 2
Dependent Claim 134 words
The oil-soluble product prepared by the process comprising, preparing intermediate A by reacting from about 0.3 moles to about 2.5 moles of a high molecular weight olefin polymer having an average molecular weight of at least about 600, with from about 0.5 moles to about 7.5 moles of acetonitrile and from about 0.4 moles to about 2.0 moles of chlorine or bromine in the presence of a catalytic amount of iodine in the absence of light at a temperature of from about 60° to about 160°F. and thereafter reacting intermediate A with piperazine or with (b) an N-aminoalkyl-substituted piperazine at a temperature of from about 200° to about 350°F. for about 1-6 hours, said amine being used in an amount to provide sufficient amine groups to replace the halogen atoms in said intermediate (A).
Claim 3
Dependent Claim 16 words
The oil-soluble product prepared by the process of claim 1, wherein the olefin polymer is polybutene.
Claim 4
Dependent Claim 15 words
The oil-soluble product prepared by the process of claim 1, wherein the olefin is polypropene.
Claim 5
Dependent Claim 15 words
The oil-soluble product prepared by the process of claim 1, wherein the amine is 1,4-bis(aminopropyl)piperazine.
Claim 6
Dependent Claim 28 words
A lubricant composition comprising a major amount of a normally liquid oleaginous lubricant, and from about 0.1 to about 10% of the oil-soluble product defined in claim 1.
Claim 7
Dependent Claim 28 words
A lubricant composition comprising a major amount of a normally liquid oleaginous lubricant, and from about 0.1 to about 10% of the oil-soluble product defined in claim 2.
Claim 8
Dependent Claim 28 words
A lubricant composition comprising a major amount of a normally liquid oleainous lubricant, and from about 0.1 to about 10% of the oil-soluble product defined in claim 4.

References Cited (Backward Citations)

US2505247A Cited
US3210371A Cited
US3360506A Cited
US3493545A Cited
US3356640A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-04-27 1979-10-27 1980-04-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-04-27 1983-10-27 1984-04-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-04-27 1987-10-27 1988-04-27 $7700.00 Window Closed / Lapsed

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