US3953348A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Oil-soluble reaction products of intermediate (a) from a high molecular weight olefin polymer, acetonitrile, and chlorine with (b) a piperazine, and lubricant compositions containing the same
Assignee: Ethyl Corp
•
Filing: 1975-03-03
•
Granted: 1976-04-27
•
Expires: 1995-03-03
Abstract
Abstract Novel addition agents for lubricants, are obtained by reacting a high molecular weight olefin polymer, having an average molecular weight of at least about 600, with acetonitrile and a halogen, for example chlorine, in the presence of a catalyst, such as iodine, for example, to form the intermediate A which is then reacted with a piperazine or aminoalkyl-substituted piperazine.
Inventors
- 👤 Richard J. Lee
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 22:46
CPC Classifications
C; C10; C10M; C10M1/00; C10M1/08; C08; C08F; C08F8/00; C08F8/30; C08F8/32; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/22; C10M2215/221; C10M2215/223; C10M2215/224; C10M2215/225; C10M2215/226; C10M2215/24; C10M2215/26; C10M2215/30; C10M2217/00; C10M2217/02; C10M2217/026; C10M2217/028; C10M2217/04; C10M2217/046; C10M2217/06
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
134 words
The oil-soluble product prepared by the process comprising, preparing intermediate A by reacting from about 0.3 moles to about 2.5 moles of a high molecular weight olefin polymer having an average molecular weight of at least about 600, with from about 0.5 moles to about 7.5 moles of acetonitrile and from about 0.4 moles to about 2.0 moles of chlorine or bromine in the presence of a catalytic amount of iodine in the absence of light at a temperature of from about 60° to about 160°F. and thereafter reacting intermediate A with piperazine or with (b) an N-aminoalkyl-substituted piperazine at a temperature of from about 200° to about 350°F. for about 1-6 hours, said amine being used in an amount to provide sufficient amine groups to replace the halogen atoms in said intermediate (A).
Claim 2
Dependent Claim
134 words
The oil-soluble product prepared by the process comprising, preparing intermediate A by reacting from about 0.3 moles to about 2.5 moles of a high molecular weight olefin polymer having an average molecular weight of at least about 600, with from about 0.5 moles to about 7.5 moles of acetonitrile and from about 0.4 moles to about 2.0 moles of chlorine or bromine in the presence of a catalytic amount of iodine in the absence of light at a temperature of from about 60° to about 160°F. and thereafter reacting intermediate A with piperazine or with (b) an N-aminoalkyl-substituted piperazine at a temperature of from about 200° to about 350°F. for about 1-6 hours, said amine being used in an amount to provide sufficient amine groups to replace the halogen atoms in said intermediate (A).
Claim 3
Dependent Claim
16 words
The oil-soluble product prepared by the process of claim 1, wherein the olefin polymer is polybutene.
Claim 4
Dependent Claim
15 words
The oil-soluble product prepared by the process of claim 1, wherein the olefin is polypropene.
Claim 5
Dependent Claim
15 words
The oil-soluble product prepared by the process of claim 1, wherein the amine is 1,4-bis(aminopropyl)piperazine.
Claim 6
Dependent Claim
28 words
A lubricant composition comprising a major amount of a normally liquid oleaginous lubricant, and from about 0.1 to about 10% of the oil-soluble product defined in claim 1.
Claim 7
Dependent Claim
28 words
A lubricant composition comprising a major amount of a normally liquid oleaginous lubricant, and from about 0.1 to about 10% of the oil-soluble product defined in claim 2.
Claim 8
Dependent Claim
28 words
A lubricant composition comprising a major amount of a normally liquid oleainous lubricant, and from about 0.1 to about 10% of the oil-soluble product defined in claim 4.
References Cited (Backward Citations)
US2505247A
Cited
US3210371A
Cited
US3360506A
Cited
US3493545A
Cited
US3356640A
Cited
US3450646A
Cited
US3514251A
Cited
US3488294A
Cited
US3631058A
Cited
US3766203A
Cited
US3821244A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-04-27 | 1979-10-27 | 1980-04-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-04-27 | 1983-10-27 | 1984-04-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-04-27 | 1987-10-27 | 1988-04-27 | $7700.00 | Window Closed / Lapsed |