Patent US3038378A successfully refreshed from Google Patents.
US3953218A
Expired / Lapsed
US
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Pigment dispersion
Assignee: Pms Consolidated
•
Filing: 1973-04-16
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Granted: 1976-04-27
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Expires: 1993-04-16
Abstract
Abstract Fatty acid amide coated pigments are obtained and used to formulate with thermoplastic or thermoset materials. The colors of the pigments are fully developed and extremely high pigment loadings are obtained. The coated pigments are formed by admixing the pigment with melted fatty acid amide; solidifying the material by cooling it; grinding the material; and separating out the fines. The coated pigment particles are compounded with thermoplastic or thermoset materials by low shear means, such as, injection molding. An improved form of the coated pigments can be obtained by admixing the melted fatty acid amide and the pigment; extruding the admixture to form a creamy mass; solidifying and forming the creamy mass by passing it through cold and forming rollers; grinding the resultant wafer-like material; and separating out the fines. Liquid compositions of fatty acid amide coated pigments can be obtained by admixing pigment particles and a fatty acid amide which is liquid at room temperature or by admixing a fatty acid amide, pigment particles and a non-solvent diluent which is liquid at room temperature.
Inventors
- 👤 Edward T. Pollard
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 20:56
CPC Classifications
C; C09; C09C; C09C3/00; C09C3/08; C09B; C09B67/00; C09B67/006; C01; C01P; C01P2004/00; C01P2004/10; C01P2004/12; C01P2004/20; C01P2004/30; C01P2004/32; C01P2004/38; C01P2004/50; C01P2004/60; C01P2004/61; C01P2004/62; C01P2004/80; C01P2006/00; C01P2006/60
Claims Analysis
Total Claims: 30
Claim 1
Independent Claim
324 words
The process of preparing coated pigment particles in a liquid form, for compounding with a thermoplastic, a thermoset and combinations thereof which comprises: (a) preparing a liquid heated admixture of a molten fatty acid amide, pigment particles and a non-solvent diluent, said pigment not being soluble in said thermoplastic, said thermoset and combinations thereof, said fatty acid amide being solid at room temperature, said non-solvent diluent being selected from the group consisting of (i) a non-solvent liquid fatty acid ester which is selected from the group consisting of ethyl formate, ethyl caprylate, ethyl propionate, ethyl butyrate, propyl acetate, butyl acetate, butyl formate and methyl butyrate, (ii) a liquid wetting-agent which is selected from the group consisting of a liquid sodium salt of an alcohol sulfate, a liquid amine salt of an alcohol sulfate, a liquid alcohol phosphate, a liquid aliphatic sulfonate, a liquid alkylaryl sulfonate, a liquid alcohol/ethylene oxide adduct, a liquid alkyl betaine - C type, a liquid alkyl betaine - N type, and a compound having the formula: ##EQU1## wherein R is alkyl and n is the number of moles of ethylene oxide, (iii) a non-solvent liquid vegetable oil which is selected from the group consisting of castor oil, olive oil, peanut oil, rape oil, corn oil, soybean oil, linseed oil, tung oil, and oiticica oil, (iv) a non-solvent liquid animal oil which is selected from the group consisting of lard oil, neat's foot oil, whale oil and fish oil, (v) a non-solvent liquid glycol which is selected from the group consisting of ethylene glycol, propylene glycol and 1,3-butylene glycol, (vi) glycerol, (vii) a mineral oil and (viii) combinations thereof, the amine radical or radicals in the fatty acid amide containing 0 to 36 carbon atoms, the fatty acid radical or radicals in the fatty acid amide containing 1 to 36 carbon atoms, and said fatty acid amide can be substituted by hydroxyl groups, and (b) cooling the admixture to room temperature.
Claim 2
Dependent Claim
324 words
The process of preparing coated pigment particles in a liquid form, for compounding with a thermoplastic, a thermoset and combinations thereof which comprises: (a) preparing a liquid heated admixture of a molten fatty acid amide, pigment particles and a non-solvent diluent, said pigment not being soluble in said thermoplastic, said thermoset and combinations thereof, said fatty acid amide being solid at room temperature, said non-solvent diluent being selected from the group consisting of (i) a non-solvent liquid fatty acid ester which is selected from the group consisting of ethyl formate, ethyl caprylate, ethyl propionate, ethyl butyrate, propyl acetate, butyl acetate, butyl formate and methyl butyrate, (ii) a liquid wetting-agent which is selected from the group consisting of a liquid sodium salt of an alcohol sulfate, a liquid amine salt of an alcohol sulfate, a liquid alcohol phosphate, a liquid aliphatic sulfonate, a liquid alkylaryl sulfonate, a liquid alcohol/ethylene oxide adduct, a liquid alkyl betaine - C type, a liquid alkyl betaine - N type, and a compound having the formula: ##EQU1## wherein R is alkyl and n is the number of moles of ethylene oxide, (iii) a non-solvent liquid vegetable oil which is selected from the group consisting of castor oil, olive oil, peanut oil, rape oil, corn oil, soybean oil, linseed oil, tung oil, and oiticica oil, (iv) a non-solvent liquid animal oil which is selected from the group consisting of lard oil, neat's foot oil, whale oil and fish oil, (v) a non-solvent liquid glycol which is selected from the group consisting of ethylene glycol, propylene glycol and 1,3-butylene glycol, (vi) glycerol, (vii) a mineral oil and (viii) combinations thereof, the amine radical or radicals in the fatty acid amide containing 0 to 36 carbon atoms, the fatty acid radical or radicals in the fatty acid amide containing 1 to 36 carbon atoms, and said fatty acid amide can be substituted by hydroxyl groups, and (b) cooling the admixture to room temperature.
Claim 3
Dependent Claim
14 words
The process of claim 1 wherein a paste results when said admixture is cooled.
Claim 4
Dependent Claim
43 words
The process of claim 1 which comprises: (i) preparing a heated liquid admixture of said melted fatty acid amide and said pigment particles; (ii) adding said non-solvent diluent to the fluid admixture; and (iii) cooling the admixture of step (ii), a paste resulting.
Claim 5
Dependent Claim
11 words
The process of claim 1 wherein the diluent is mineral oil.
Claim 6
Dependent Claim
15 words
The process of claim 1 wherein the fatty acid amide is hydroxystearic acid ethylene diamide.
Claim 7
Dependent Claim
64 words
The process of claim 1 which comprises: (i) admixing said pigment particles and said non-solvent diluent; (ii) heating the admixture of step (a) to a temperature at which said fatty acid amide is in the molten state; (iii) admixing said fatty acid specified in step (ii) with the heated admixture of step (i) and (iv) cooling the admixture of step (iii), a paste resulting.
Claim 8
Dependent Claim
17 words
The process of claim 6 wherein the admixture of step (iii) is cooled to about room temperature.
Claim 9
Dependent Claim
11 words
The process of claim 6 wherein said diluent is mineral oil.
Claim 10
Dependent Claim
308 words
The process of preparing coated pigment particles in a liquid form, for compounding with a thermoplastic, a thermoset and combinations thereof which consists of (a) preparing a heated liquid admixture of a molten fatty acid amide, pigment particles and a non-solvent diluent said fatty acid amide being solid at room temperature, said non-solvent diluent being selected from the group consisting of (i) a non-solvent liquid fatty acid ester which is selected from the group consisting of ethyl formate, ethyl caprylate, ethyl propionate, ethyl butyrate, propyl acetate, butyl acetate, butyl formate and methyl butyrate, (ii) a liquid wetting agent which is selected from the group consisting of a liquid sodium salt of al alcohol sulfate, a liquid amine salt of an alcohol sulfate, a liquid alcohol phosphate, a liquid aliphatic sulfonate, a liquid alkylaryl sulfonate, a liquid alcohol/ethylene oxide adduct, a liquid alkyl betaine-C type, a liquid alkyl betaine-N type and a compound having the formula: ##EQU2## wherein R is alkyl and n is the number of moles of ethylene oxide, (iii) a non-solvent liquid vegetable oil which is selected from the group consisting of castor oil, olive oil, peanut oil, rape oil, corn oil, soybean oil, linseed oil, tung oil, and oiticica oil, (iv) a non-solvent liquid animal oil which is selected from the group consisting of lard oil, neat's foot oil, whale oil and fish oil, (v) a non-solvent glycol which is selected from the group consisting of ethylene glycol, propylene glycol and 1,3-butylene glycol, (vi) glycerol, (vii) a mineral oil and (viii) combinations thereof, the amine radical or radicals in the fatty acid amide containing 0 to 36 carbon atoms, the fatty acid radical or radicals in the fatty acid amide containing 1 to 36 carbon atoms, and said fatty acid amide can be substituted by hydroxyl groups, and (b) cooling the admixture, a paste resulting.
Claim 11
Dependent Claim
308 words
The process of preparing coated pigment particles in a liquid form, for compounding with a thermoplastic, a thermoset and combinations thereof which consists of (a) preparing a heated liquid admixture of a molten fatty acid amide, pigment particles and a non-solvent diluent said fatty acid amide being solid at room temperature, said non-solvent diluent being selected from the group consisting of (i) a non-solvent liquid fatty acid ester which is selected from the group consisting of ethyl formate, ethyl caprylate, ethyl propionate, ethyl butyrate, propyl acetate, butyl acetate, butyl formate and methyl butyrate, (ii) a liquid wetting agent which is selected from the group consisting of a liquid sodium salt of al alcohol sulfate, a liquid amine salt of an alcohol sulfate, a liquid alcohol phosphate, a liquid aliphatic sulfonate, a liquid alkylaryl sulfonate, a liquid alcohol/ethylene oxide adduct, a liquid alkyl betaine-C type, a liquid alkyl betaine-N type and a compound having the formula: ##EQU2## wherein R is alkyl and n is the number of moles of ethylene oxide, (iii) a non-solvent liquid vegetable oil which is selected from the group consisting of castor oil, olive oil, peanut oil, rape oil, corn oil, soybean oil, linseed oil, tung oil, and oiticica oil, (iv) a non-solvent liquid animal oil which is selected from the group consisting of lard oil, neat's foot oil, whale oil and fish oil, (v) a non-solvent glycol which is selected from the group consisting of ethylene glycol, propylene glycol and 1,3-butylene glycol, (vi) glycerol, (vii) a mineral oil and (viii) combinations thereof, the amine radical or radicals in the fatty acid amide containing 0 to 36 carbon atoms, the fatty acid radical or radicals in the fatty acid amide containing 1 to 36 carbon atoms, and said fatty acid amide can be substituted by hydroxyl groups, and (b) cooling the admixture, a paste resulting.
Claim 12
Dependent Claim
287 words
The process of preparing coated pigment particles for compounding with a thermoplastic, a thermoset and combinations thereof which comprises admixing a non-solvent diluent with pigment particles which are encapsulated by a fatty acid amide, a paste forming, said non-solvent diluent being selected from the group consisting of (i) a non-solvent liquid fatty acid ester which is selected from the group consisting of ethyl formate, ethyl caprylate, ethyl propionate, ethyl butyrate, propyl acetate, butyl acetate butyl formate and methyl butyrate, (ii) a liquid wetting agent which is selected from the group consisting of a liquid sodium salt of an alcohol sulfate, a liquid amine salt of an alcohol sulfate, a liquid alcohol phosphate, a liquid aliphatic sulfonate, a liquid alkylaryl sulfonate, a liquid/ethylene oxide adduct, a liquid alkyl betaine-C type, a liquid alkyl betaine-N type and a compound having the formula: ##EQU3## wherein R is alkyl and n is the number of moles of ethylene oxide, (iii) a non-solvent liquid vegetable oil which is slected from the group consisting of castor oil, olive oil, peanut oil, rape oil, corn oil, soybean oil, linseed oil, tung oil and oiticica oil, (iv) a non-solvent liquid animal oil which is selected from the group consisting of lard oil, neat's foot oil, whale oil and fish oil, (v) a non-solvent liquid glycol which is selected from the group consisting of ethylene glycol, propylene glycol and 1,3-butylene glycol, (vi) glycerol, (vii) a mineral oil and (viii) combinations thereof, the amine radical or radicals in the fatty acid amide containing 0 to 36 carbon atoms, the fatty acid radical or radicals in the fatty acid amide containing 1 to 36 carbon atoms, and said fatty acid amide containing can be substituted by hydroxyl groups.
Claim 13
Dependent Claim
287 words
The process of preparing coated pigment particles for compounding with a thermoplastic, a thermoset and combinations thereof which comprises admixing a non-solvent diluent with pigment particles which are encapsulated by a fatty acid amide, a paste forming, said non-solvent diluent being selected from the group consisting of (i) a non-solvent liquid fatty acid ester which is selected from the group consisting of ethyl formate, ethyl caprylate, ethyl propionate, ethyl butyrate, propyl acetate, butyl acetate butyl formate and methyl butyrate, (ii) a liquid wetting agent which is selected from the group consisting of a liquid sodium salt of an alcohol sulfate, a liquid amine salt of an alcohol sulfate, a liquid alcohol phosphate, a liquid aliphatic sulfonate, a liquid alkylaryl sulfonate, a liquid/ethylene oxide adduct, a liquid alkyl betaine-C type, a liquid alkyl betaine-N type and a compound having the formula: ##EQU3## wherein R is alkyl and n is the number of moles of ethylene oxide, (iii) a non-solvent liquid vegetable oil which is slected from the group consisting of castor oil, olive oil, peanut oil, rape oil, corn oil, soybean oil, linseed oil, tung oil and oiticica oil, (iv) a non-solvent liquid animal oil which is selected from the group consisting of lard oil, neat's foot oil, whale oil and fish oil, (v) a non-solvent liquid glycol which is selected from the group consisting of ethylene glycol, propylene glycol and 1,3-butylene glycol, (vi) glycerol, (vii) a mineral oil and (viii) combinations thereof, the amine radical or radicals in the fatty acid amide containing 0 to 36 carbon atoms, the fatty acid radical or radicals in the fatty acid amide containing 1 to 36 carbon atoms, and said fatty acid amide containing can be substituted by hydroxyl groups.
Claim 14
Dependent Claim
14 words
The process of claim 10 wherein the admixing is done at about room temperature.
Claim 15
Dependent Claim
56 words
The process of claim 10 which comprises: (i) heating a non-solvent diluent to a temperature below that at which said fatty acid amide is in the molten state; (ii) admixing said heated non-solvent diluent with pigment particles which are encapsulated by said fatty acid amide; and (iii) cooling the admixture of step (ii) a paste forming.
Claim 16
Dependent Claim
17 words
The process of claim 12 wherein the admixture of step (ii) is cooled to about room temperature.
Claim 17
Dependent Claim
11 words
The process of claim 12 wherein said diluent is mineral oil.
Claim 18
Dependent Claim
15 words
The process of claim 12 wherein said fatty acid amide is hydroxystearic acid ethylene diamide.
Claim 19
Dependent Claim
108 words
The process of preparing coated pigment particles for compounding with a thermoplastic, a thermoset or combinations thereof which comprises preparing a liquid admixture of a partially amidized fatty acid amide which is liquid at room temperature and pigment particles, said partially amidized fatty acid amide being a partially amidized vegetable oil, partially amidized animal oil, partially amidized glycerides of fatty acids, partially amidized oleic acid, partially amidized linoleic acid or partially amidized ricinoleic acid, and said partially amidized fatty acid amide containing at least thirty percent of the theoretical amide linkages, but few enough amide linkages to keep said partially amidized fatty acid amide liquid at room temperature.
Claim 20
Dependent Claim
108 words
The process of preparing coated pigment particles for compounding with a thermoplastic, a thermoset or combinations thereof which comprises preparing a liquid admixture of a partially amidized fatty acid amide which is liquid at room temperature and pigment particles, said partially amidized fatty acid amide being a partially amidized vegetable oil, partially amidized animal oil, partially amidized glycerides of fatty acids, partially amidized oleic acid, partially amidized linoleic acid or partially amidized ricinoleic acid, and said partially amidized fatty acid amide containing at least thirty percent of the theoretical amide linkages, but few enough amide linkages to keep said partially amidized fatty acid amide liquid at room temperature.
Claim 21
Dependent Claim
126 words
The process of preparing coated pigment particles for dry compounding with thermoplastics, thermosets and combinations thereof which comprises; (a) preparing a fluid admixture of a melted fatty acid amide and pigment particles, said fatty acid amide being solid at room temperature, (b) cooling the admixture until it is in a solidified state, the pigment particles being substantially encapsulated by the fatty acid amide, (c) particulating the solidified admixture, the amine radical or radicals in the fatty acid amide containing 0 to 36 carbon atoms, the fatty acid radical or radicals in the fatty acid amide containing 1 to 36 carbon atoms, and said fatty acid amide can be substituted by hydroxyl groups, and (d) removing the fines and dust are removed from said particulated solidified admixture.
Claim 22
Dependent Claim
126 words
The process of preparing coated pigment particles for dry compounding with thermoplastics, thermosets and combinations thereof which comprises; (a) preparing a fluid admixture of a melted fatty acid amide and pigment particles, said fatty acid amide being solid at room temperature, (b) cooling the admixture until it is in a solidified state, the pigment particles being substantially encapsulated by the fatty acid amide, (c) particulating the solidified admixture, the amine radical or radicals in the fatty acid amide containing 0 to 36 carbon atoms, the fatty acid radical or radicals in the fatty acid amide containing 1 to 36 carbon atoms, and said fatty acid amide can be substituted by hydroxyl groups, and (d) removing the fines and dust are removed from said particulated solidified admixture.
Claim 23
Dependent Claim
17 words
The process of claim 17 wherein the fines and dust are removed from the particulated solidified admixture.
Claim 24
Dependent Claim
23 words
The process of claim 17 wherein cooling step (b) is achieved by letting fluid admixture (a) solidify by cooling to about room temperature.
Claim 25
Dependent Claim
16 words
The process of claim 17 wherein the particulation of the solidified admixture is achieved by grinding.
Claim 26
Dependent Claim
155 words
The process of preparing coated pigment particles for dry compounding with thermoplastics, thermosets and combinations thereof which comprises: (a) preparing a fluid admixture consisting of a least one melted fatty acid amide and pigment particles, the amine radical or radicals in the fatty acid amide containing 0 to 36 carbon atoms, the fatty acid radical or radicals in the fatty acid amide containing 1 to 36 carbon atoms, and said fatty acid amide can be substituted by hydroxyl groups; (b) passing the fluid admixture consisting of at least one fatty acid amide and pigment particles through a heated low-shear mixer; (c) cooling the admixture consisting of at least one fatty acid amide and pigment particles until it is in a solidified state, by passing the extruded fluid admixture through cooled rollers, whereby solid wafer-like flakes are formed, the pigment particles being substantially encapsulated by the fatty acid amide; and (d) particulating the solid wafer-like flakes.
Claim 27
Dependent Claim
155 words
The process of preparing coated pigment particles for dry compounding with thermoplastics, thermosets and combinations thereof which comprises: (a) preparing a fluid admixture consisting of a least one melted fatty acid amide and pigment particles, the amine radical or radicals in the fatty acid amide containing 0 to 36 carbon atoms, the fatty acid radical or radicals in the fatty acid amide containing 1 to 36 carbon atoms, and said fatty acid amide can be substituted by hydroxyl groups; (b) passing the fluid admixture consisting of at least one fatty acid amide and pigment particles through a heated low-shear mixer; (c) cooling the admixture consisting of at least one fatty acid amide and pigment particles until it is in a solidified state, by passing the extruded fluid admixture through cooled rollers, whereby solid wafer-like flakes are formed, the pigment particles being substantially encapsulated by the fatty acid amide; and (d) particulating the solid wafer-like flakes.
Claim 28
Dependent Claim
17 words
The process of claim 21 wherein the cooled rollers have a surface temperature of less than 0°C.
Claim 29
Dependent Claim
86 words
The composition which consists of a fluid admixture of a fatty acid amide which is liquid at room temperature and pigment particles, said fatty acid amide being partially amidized vegetable oil, partially amidized animal oil, partially amidized glycerides of fatty acids, partially amidized oleic acid, partially linoleic acid or partially amidized ricinoleic acid, and said partially amidized fatty acid amide containing at least thirty percent of the theoretical amide linkages, but few enough linkages to keep said partially amidized fatty acid amide liquid at room temperature.
Claim 30
Dependent Claim
86 words
The composition which consists of a fluid admixture of a fatty acid amide which is liquid at room temperature and pigment particles, said fatty acid amide being partially amidized vegetable oil, partially amidized animal oil, partially amidized glycerides of fatty acids, partially amidized oleic acid, partially linoleic acid or partially amidized ricinoleic acid, and said partially amidized fatty acid amide containing at least thirty percent of the theoretical amide linkages, but few enough linkages to keep said partially amidized fatty acid amide liquid at room temperature.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-04-27 | 1979-10-27 | 1980-04-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-04-27 | 1983-10-27 | 1984-04-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-04-27 | 1987-10-27 | 1988-04-27 | $7700.00 | Window Closed / Lapsed |