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US3953214A Expired / Lapsed US ⏱️ 0.0 years remaining

Photopolymerizable screen printing inks and use thereof

Assignee: MacDermid Inc
•
Filing: 1974-05-24
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Granted: 1976-04-27
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Expires: 1994-05-24
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Abstract

Abstract Photopolymerizable screen printing inks comprising a hydroxyalkyl acrylate-type monomeric material, a polyester binder and a free-radical initiating system, such inks having a viscosity of from 5,000 to 200,000 centipoises, an acid number of from 0 to 120 and a thixotropic index of from 1 to 4. The process of using such inks to treat substrates, such as in making printed circuits, which includes the steps of screen printing the photopolymerizable ink on the substrate; exposing the ink to actinic radiation to cure the ink and to form a resist; and permanently modifying the exposed areas on the substrate. The resist may thereafter be removed by dissolving in aqueous dilute alkali or an organic solvent.

Inventors

  • 👤 Melvin A. Lipson
  • 👤 Dale W. Knoth

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 14:35
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/28; H; H05; H05K; H05K3/00; H05K3/0073; H05K3/0076; H05K3/02; H05K3/06; H05K3/061; H05K3/064; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/106; Y10S430/109; Y10S430/114; Y10S430/117

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 91 words
A photopolymerizable screen printing ink which comprises: A. 25 to 50% by weight of a photopolymerizable monomeric material containing at least 20 weight percent hydroxyalkyl acrylate or methacrylate; B. 20 to 60% by weight of a polyester binder having a molecular weight of from 500 to 50,000; C. 5 to 10% by weight of a free radical generating addition polymerizing initiating system; said photopolymerizable composition having a viscosity of from 5,000 to 200,000 centipoises, an acid number of from 0 to 120, and a thixotropic index of from 1.00 to 4.00.
Claim 2
Dependent Claim 91 words
A photopolymerizable screen printing ink which comprises: A. 25 to 50% by weight of a photopolymerizable monomeric material containing at least 20 weight percent hydroxyalkyl acrylate or methacrylate; B. 20 to 60% by weight of a polyester binder having a molecular weight of from 500 to 50,000; C. 5 to 10% by weight of a free radical generating addition polymerizing initiating system; said photopolymerizable composition having a viscosity of from 5,000 to 200,000 centipoises, an acid number of from 0 to 120, and a thixotropic index of from 1.00 to 4.00.
Claim 3
Dependent Claim 20 words
The screen printing ink of claim 1 wherein the photopolymerizable monomeric material consists essentially of a hydroxyalkyl acrylate or methacrylate.
Claim 4
Dependent Claim 21 words
The screen printing ink of claim 1 wherein the polyester binder is a condensation product of propylene glycol and phthalic anhydride.
Claim 5
Dependent Claim 29 words
The screen printing ink of claim 1 wherein the polyester binder is a condensation product of propylene glycol and a 1 to 1 mixture of maleic and isophthalic acids.
Claim 6
Dependent Claim 15 words
The screen printing ink of claim 1 wherein the initiating system contains a benzoin ether.
Claim 7
Dependent Claim 34 words
The screen printing ink of claim 1 wherein the ink contains up to ten parts by weight, based on 100 parts of ink, of a carboxylic acid containing from 2 to 36 carbon atoms.
Claim 8
Dependent Claim 30 words
The screen printing ink of claim 1 wherein the ink contains a maximum of 50 weight percent of a polyfunctional acrylate or methacrylate as part of the photopolymerizable monomeric material.

References Cited (Backward Citations)

US2791504A Cited
US3255006A Cited
US3695877A Cited
US3753720A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-04-27 1979-10-27 1980-04-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-04-27 1983-10-27 1984-04-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-04-27 1987-10-27 1988-04-27 $7700.00 Window Closed / Lapsed

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