US3950447A
Expired / Lapsed
US
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Method for carrying out simultaneously the catalytic reactions involving hydrogen evolution and consumption
Assignee: Individual
•
Filing: 1971-04-30
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Granted: 1976-04-13
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Expires: 1991-04-30
Abstract
Abstract A method for carrying out simultaneously the catalytic reactions involving the evolution and consumption of hydrogen, which comprises conducting the reactions in a reaction space divided by a partition made from a material that is selectively permeable to hydrogen only and serves as a catalyst.
Inventors
- 👤 Vladimir Mikhailovich Gryaznov
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 02:22
CPC Classifications
B; B01; B01D; B01D67/00; B01D67/0039; B01D67/0069; B01D53/00; B01D53/22; B01D71/00; B01D71/02; B01D71/022; B01D71/0223; B01D71/02231; B01J; B01J23/00; B01J23/38; B01J23/40; B01J23/44; B01J37/00; B01J37/34; C; C07; C07C; C07C4/00; C07C4/08; C07C4/12; C07C4/14; C07C4/18; C07C5/00; C07C5/02; C07C5/10; C07C5/32; C07C5/321; C07C5/324; C07C5/325; C07C5/327; C07C5/333; C07C5/3335; C07C5/3337; C07C5/367; C07C5/42; C07C5/50; C07C5/52; B01D2325/00; B01D2325/10; C07C2523/00; C07C2523/38; C07C2523/40; C07C2523/44; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/52
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
161 words
A method for simultaneously carrying out a catalytic reaction wherein hydrogen is evolved and a catalytic reaction wherein hydrogen is consumed, said method comprising conducting each of said reactions in separate reaction zones isolated from one another by a membrane partition made of a catalytic material consisting essentially of palladium or alloys thereof and selectively permeable to hydrogen only, wherein in one reaction zone hydrogen is evolved from the material fed to said reaction zone, and wherein in the other reaction zone, the hydrogen is combined with the material fed to said other reaction zone, the hydrogen evolved in the first reaction zone passing through the partition which is selectively permeable thereto, said material being fed to the other reaction zone being capable of undergoing hydrogenation or hydrodealkylation, and maintaining the temperature in said reaction zones in the range of from 300° to 500°C to effect reaction in both zones, the palladium partition serving as the catalytic material in both zones.
Claim 2
Independent Claim
161 words
A method for simultaneously carrying out a catalytic reaction wherein hydrogen is evolved and a catalytic reaction wherein hydrogen is consumed, said method comprising conducting each of said reactions in separate reaction zones isolated from one another by a membrane partition made of a catalytic material consisting essentially of palladium or alloys thereof and selectively permeable to hydrogen only, wherein in one reaction zone hydrogen is evolved from the material fed to said reaction zone, and wherein in the other reaction zone, the hydrogen is combined with the material fed to said other reaction zone, the hydrogen evolved in the first reaction zone passing through the partition which is selectively permeable thereto, said material being fed to the other reaction zone being capable of undergoing hydrogenation or hydrodealkylation, and maintaining the temperature in said reaction zones in the range of from 300° to 500°C to effect reaction in both zones, the palladium partition serving as the catalytic material in both zones.
Claim 3
Dependent Claim
17 words
A method according to claim 1, wherein the partition is made of palladium coated with palladium black.
Claim 4
Dependent Claim
34 words
A method according to claim 1, wherein the material from which hydrogen is evolved consists of naphthenes, and the material which adds hydrogen consists of aromatic hydrocarbons which are to be subjected to hydrodealkylation.
Claim 5
Dependent Claim
36 words
A method according to claim 1, wherein the material from which hydrogen is evolved consists of olefins, and the material which adds hydrogen consists of aromatic hydrocarbons which are to be subjected to hydrogenation or hydrodealkylation.
Claim 6
Dependent Claim
24 words
A method according to claim 3 wherein the material from which hydrogen is evolved is cyclohexane and the material which adds hydrogen is xylene.
Claim 7
Dependent Claim
11 words
A method according to claim 5 wherein the temperature is 430°C.
Claim 8
Dependent Claim
24 words
A method according to claim 4 wherein the material from which hydrogen is evolved is trans-butene-2 and the material which adds hydrogen is toluene.
Claim 9
Dependent Claim
11 words
A method according to claim 7 wherein the temperature is 370°-430°C.
Claim 10
Dependent Claim
24 words
A method according to claim 4 wherein the material from which hydrogen is evolved is trans-butene-2 and the material which adds hydrogen is benzene.
Claim 11
Dependent Claim
11 words
A method according to claim 9 wherein the temperature is 380°-410°C.
Claim 12
Dependent Claim
19 words
A method according to claim 1 wherein in said one reaction zone dehydrogenation of naphthenes or olefins is effected.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-04-13 | 1979-10-13 | 1980-04-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-04-13 | 1983-10-13 | 1984-04-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-04-13 | 1987-10-13 | 1988-04-13 | $7700.00 | Window Closed / Lapsed |