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US3950419A Expired / Lapsed US ⏱️ 0.0 years remaining

Aromatic carboxylic acid esters and amides as fixing agents

Assignee: Sandoz AG
•
Filing: 1973-10-09
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Granted: 1976-04-13
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Expires: 1993-10-09
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Abstract

Abstract The present invention relates to methods of dyeing and printing of textile materials and specifically to the use of fixing agents in such methods. In particular, the present invention relates to the use of aromatic carboxylic acid esters and amides as fixing agents in the dyeing and printing of textile materials.

Inventors

  • 👤 Hans-Peter Baumann
  • 👤 Hans-Georg Karmann

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 01:36
CPC Classifications
D; D06; D06P; D06P1/00; D06P1/44; D06P1/64; D06P1/642; D06P1/649; D06P1/6495; D06P1/60; D06P1/607; D06P1/6073; D06P1/613; D06P1/6136; D06P1/651; D06P1/65106; D06P1/65125; D06P3/00; D06P5/00; D06P5/02; D06P5/04; D06P5/06; Y; Y10; Y10S; Y10S8/00; Y10S8/93

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 535 words
A compound of the formula, ##SPC18## wherein Y 1 and Y 2 are, independently, ethylene, 1,2-propylene, 1,3-propylene, 1,2-butylene or phenylethylene, with the proviso that a. only the group Y 1 or Y 2 which is bound to X can be 1,3-propylene, and b. each (Y 1 -O) or (Y 2 -O) chain contains no more than 2 phenylethylene groups, R 4 " is hydrogen, --CO 2 M, --OR 6 or a group --CO--X--(Y 1 O) m .sbsb.1 --R 1 , R 5 " is hydrogen, --CO 2 M or a group --CO--X--(Y 1 O) m .sbsb.1 --R 1 , M is a charge equivalent of a cation, R 6 is hydrogen, phenyl, phenylalkyl (C 7 -C 22 ), phenyl or phenylalkyl (C 7 -C 22 ) substituted by --OH, alkyl or halogen and having up to 22 carbon atoms in the aggregate thereof, alkyl (C 1 -C 22 ), cycloalkyl (C 5 -C 7 ), alkyl (C 1 -C 15 ) cycloalkyl (C 5 -C 7 ), cycloalkyl (C 5 -C 7 ) alkyl (C 1 -C 15 ) cycloalkyl (C 5 -C 7 ) alkyl (C 1 -C 15 ) or a group --(Y 2 --O) m .sbsb.2 --R 2 , X is --O-- or --NR--, R is one of the significances of R 6 , R 1 and R 2 are, independently, hydrogen, phenyl, phenylalkyl (C 7 -C 22 ), phenyl or phenylalkyl substituted on the phenyl nucleus by --OH, alkyl or halogen and having up to 22 carbon atoms in the aggregate thereof, alkyl (C 1 -C 22 ), cycloalkyl (C 5 -C 7 ), alkyl (C 1 -C 15 ) cycloalkyl (C 5 -C 7 ), cycloalkyl (C 5 -C 7 ) alkyl (C 1 -C 15 ), alkyl (C 1 -C 15 ) cycloalkyl (C 5 -C 7 ) alkyl (C 1 -C 15 ), or a group ##SPC19## R 3 is hydrogen, halogen, alkyl (C 1 -C 22 ), cycloalkyl (C 5 -C 7 ), cycloalkyl (C 5 -C 7 ) alkyl (C 1 -C 15 ), alkyl (C 1 -C 15 ) cycloalkyl (C 5 -C 7 ), alkyl (C 1 -C 15 ) cycloalkyl (C 5 -C 7 ) alkyl (C 1 -C 15 ), --CN, --COOR 6 , --SO 3 R 6 , --OR 6 , --NHR 6 or --N(R 6 ) 2 , --CO 2 M, --SO 3 M or a group --CO--X--(Y 1 O) m .sbsb.1 --R 1 , with the proviso that when R 4 " or R 5 " is a group --CO--X--(Y 1 O) m .sbsb.1 --R 1 , then R 1 is hydrogen, or when R 4 is a group O--(Y 2 --O) m .sbsb.2 --R 2 , then R 2 is hydrogen, m 1 and m 2 are integers 1 to 100 , the sum of all the integers m 1 and m 2 being 1 to 100, and z 1 and z 2 are integers 1 to 100 , the sum of all the integers z 1 and z 2 being 5 to 100, and when relevant, the sum of all the integers z 1 , z 2 , m 1 and m 2 being 6 to 100.
Claim 2
Dependent Claim 535 words
A compound of the formula, ##SPC18## wherein Y 1 and Y 2 are, independently, ethylene, 1,2-propylene, 1,3-propylene, 1,2-butylene or phenylethylene, with the proviso that a. only the group Y 1 or Y 2 which is bound to X can be 1,3-propylene, and b. each (Y 1 -O) or (Y 2 -O) chain contains no more than 2 phenylethylene groups, R 4 " is hydrogen, --CO 2 M, --OR 6 or a group --CO--X--(Y 1 O) m .sbsb.1 --R 1 , R 5 " is hydrogen, --CO 2 M or a group --CO--X--(Y 1 O) m .sbsb.1 --R 1 , M is a charge equivalent of a cation, R 6 is hydrogen, phenyl, phenylalkyl (C 7 -C 22 ), phenyl or phenylalkyl (C 7 -C 22 ) substituted by --OH, alkyl or halogen and having up to 22 carbon atoms in the aggregate thereof, alkyl (C 1 -C 22 ), cycloalkyl (C 5 -C 7 ), alkyl (C 1 -C 15 ) cycloalkyl (C 5 -C 7 ), cycloalkyl (C 5 -C 7 ) alkyl (C 1 -C 15 ) cycloalkyl (C 5 -C 7 ) alkyl (C 1 -C 15 ) or a group --(Y 2 --O) m .sbsb.2 --R 2 , X is --O-- or --NR--, R is one of the significances of R 6 , R 1 and R 2 are, independently, hydrogen, phenyl, phenylalkyl (C 7 -C 22 ), phenyl or phenylalkyl substituted on the phenyl nucleus by --OH, alkyl or halogen and having up to 22 carbon atoms in the aggregate thereof, alkyl (C 1 -C 22 ), cycloalkyl (C 5 -C 7 ), alkyl (C 1 -C 15 ) cycloalkyl (C 5 -C 7 ), cycloalkyl (C 5 -C 7 ) alkyl (C 1 -C 15 ), alkyl (C 1 -C 15 ) cycloalkyl (C 5 -C 7 ) alkyl (C 1 -C 15 ), or a group ##SPC19## R 3 is hydrogen, halogen, alkyl (C 1 -C 22 ), cycloalkyl (C 5 -C 7 ), cycloalkyl (C 5 -C 7 ) alkyl (C 1 -C 15 ), alkyl (C 1 -C 15 ) cycloalkyl (C 5 -C 7 ), alkyl (C 1 -C 15 ) cycloalkyl (C 5 -C 7 ) alkyl (C 1 -C 15 ), --CN, --COOR 6 , --SO 3 R 6 , --OR 6 , --NHR 6 or --N(R 6 ) 2 , --CO 2 M, --SO 3 M or a group --CO--X--(Y 1 O) m .sbsb.1 --R 1 , with the proviso that when R 4 " or R 5 " is a group --CO--X--(Y 1 O) m .sbsb.1 --R 1 , then R 1 is hydrogen, or when R 4 is a group O--(Y 2 --O) m .sbsb.2 --R 2 , then R 2 is hydrogen, m 1 and m 2 are integers 1 to 100 , the sum of all the integers m 1 and m 2 being 1 to 100, and z 1 and z 2 are integers 1 to 100 , the sum of all the integers z 1 and z 2 being 5 to 100, and when relevant, the sum of all the integers z 1 , z 2 , m 1 and m 2 being 6 to 100.
Claim 3
Dependent Claim 168 words
A compound of claim 1 of the formula, ##SPC20## wherein Y 1 ' and Y 2 ' are, independently, ethylene, 1,2-propylene or 1,2-butylene, R 4 '" is hydrogen, CO 2 M or OR 6 ', R 5 '" is hydrogen or CO 2 M, m is as defined in Claim 1, R 6 ' is hydrogen or a group --(Y 2 '--O) m .sbsb.2 R 2 ', R 2 ' is hydrogen or alkyl (C 1 -C 4 ), m 2 ' is an integer 1 to 50, with the proviso that when R 4 '" is a group --O--(Y 2 '--O) m .sbsb.2 R 2 ', then R 2 ' is hydrogen, and z 1 ' and z 2 ' are each an integer 1 to 50, the sum of all the integers z 1 ' and z 2 ' being 5 to 50, and when relevant, the sum of all the integers z 1 ', z 2 ' and m 2 ' being 6 to 100.
Claim 4
Dependent Claim 70 words
A compound of claim 2 of the formula, ##SPC21## wherein R 4 '" and R 5 '" are as defined in claim 2, R 7 is hydrogen or methyl, and z 1 ", z 2 ", z 3 " and z 4 " are each an integer 1 to 37, the sum of z 1 ", z 2 ", z 3 " and z 4 " being 5 to 40.
Claim 5
Dependent Claim 59 words
A compound of claim 3 of the formula, ##SPC22## wherein R 7 is as defined in claim 11, and z 1 '", z 2 '", z 3 '" and z 4 '" are each an integer 1 to 17, the sum of z 1 '", z 2 '", z 3 '" and z 4 '" being 5 to 20.
Claim 6
Dependent Claim 54 words
A compound of the formula ##SPC23## wherein R 7 is as defined in claim 4, and n 1 ", n 2 ", n 3 " and n 4 " are integers 1 to 3, the sum of n 1 ", n 2 ", n 3 " and n 4 " being 4 to 6.
Claim 7
Dependent Claim 40 words
A compound of the formula ##SPC24## wherein n 1 '",n 2 '",n 3 '" and n 4 '" are integers of 1 to 5, ther sum of n 1 '",n 2 '", n 3 '" and n 4 '" being
Claim 8
Dependent Claim 40 words
A compound of the formula ##SPC24## wherein n 1 '",n 2 '",n 3 '" and n 4 '" are integers of 1 to 5, ther sum of n 1 '",n 2 '", n 3 '" and n 4 '" being
Claim 9
Dependent Claim 38 words
A compound of the formula ##SPC25## wherein n 1 IV , n 2 IV , n 3 IV and n 4 IV are integers 1 to 3, the sum of n 1 IV , n 2 IV ,
Claim 10
Dependent Claim 38 words
A compound of the formula ##SPC25## wherein n 1 IV , n 2 IV , n 3 IV and n 4 IV are integers 1 to 3, the sum of n 1 IV , n 2 IV ,
Claim 11
Dependent Claim 13 words
A compound of claim 1, wherein Y 1 and Y 2 are different.

References Cited (Backward Citations)

FR3201M Cited
US3448150A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-04-13 1979-10-13 1980-04-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-04-13 1983-10-13 1984-04-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-04-13 1987-10-13 1988-04-13 $7700.00 Window Closed / Lapsed

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