US3950286A
Expired / Lapsed
US
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Coating process and composition
Assignee: Allnex Austria GmbH
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Filing: 1970-07-16
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Granted: 1976-04-13
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Expires: 1990-07-16
Abstract
Abstract A process of making water-soluble coating compositions is described characterized in that (A) an adduct of an alpha-beta ethylenically unsaturated dicarboxylic acid or anhydride with olefinic, unaltered or polymerized, oil fatty acids, or mixtures of such acids with other unsaturated carboxylic acids or natural esters thereof, or hydroxy-free polyol esters thereof; (B) a polyhydroxy compound; and (C) a water-insoluble, hardenable phenol-aldehyde condensation product of a phenol substituted in the ortho- or para-position with an alkyl radical having at least three carbon atoms, are combined at an elevated temperature to form a homogeneous resinous body; and the resin thereafter made water-soluble through the addition of a water-soluble nitrogen base. The water-soluble coating compositions are particularly useful for electrodeposition providing films having improved surface characteristics and corrosion resistance.
Inventors
- 👤 Herbert Hoenel
- 👤 Heinrich Lackner
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 09:22
CPC Classifications
C; C08; C08L; C08L67/00; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/52; C08G63/54; C08G63/553; C09; C09D; C09D167/00; C09D167/08; C09D5/00; C09D5/44; C09D5/4484; Y; Y10; Y10S; Y10S524/00; Y10S524/901
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
132 words
A process for producing water-soluble coating compositions by A. combining at elevated temperatures I. an adduct of maleic anhydride with an olefinic unsaturated compound of the group consisting of vegetable and animal fatty acis, tall oil fatty acid, rosin acids, their hydroxy-free esters with polyols and mixtures thereof; Ii. a polyhydroxy compound of the group consisting of trimethylol propane, pentaerythritol, propylene glycol, and butylene glycol, and partial esters thereof with fatty acids; and Iii. a water-insoluble, heat-hardenable phenol-formaldehyde condensation product, in the resol state, of a phenol substituted in the ortho or para position by a radical with at least 3 carbon atoms and being a member of the groups of alkyl phenols and aryl phenols; and B. at least partially neutralizing the reaction product of (A) with a water-soluble nitrogen base.
Claim 2
Dependent Claim
132 words
A process for producing water-soluble coating compositions by A. combining at elevated temperatures I. an adduct of maleic anhydride with an olefinic unsaturated compound of the group consisting of vegetable and animal fatty acis, tall oil fatty acid, rosin acids, their hydroxy-free esters with polyols and mixtures thereof; Ii. a polyhydroxy compound of the group consisting of trimethylol propane, pentaerythritol, propylene glycol, and butylene glycol, and partial esters thereof with fatty acids; and Iii. a water-insoluble, heat-hardenable phenol-formaldehyde condensation product, in the resol state, of a phenol substituted in the ortho or para position by a radical with at least 3 carbon atoms and being a member of the groups of alkyl phenols and aryl phenols; and B. at least partially neutralizing the reaction product of (A) with a water-soluble nitrogen base.
Claim 3
Dependent Claim
24 words
Process according to claim 1 characterized in that components (I), (II), and (III) are heated together until a homogeneous but ungelled product is obtained.
Claim 4
Dependent Claim
31 words
Process according to claim 1 characterized in that the reaction mixture of component (I) includes the triglycerides, and said triglycerides are re-esterified by heating at temperatures of between 150° and 180°C.
Claim 5
Dependent Claim
26 words
Process according to claim 1 characterized in that any anhydride groups of component (I) are hydrolyzed before component (I) is reacted with components (II) and (III).
Claim 6
Dependent Claim
25 words
Process according to claim 1 characterized in that the polyhydroxy compound (II) is a partial ester of unsaturated oil fatty acids and said polyhydric alcohols.
Claim 7
Dependent Claim
26 words
Process according to claim 5 characterized in that components (II) and (III) are heated together to temperatures above 180°C. before reaction with component (I) takes place.
Claim 8
Dependent Claim
27 words
Process according to claim 4 characterized in that the hydrolyzed anhydride groups of component (I) are partially esterified with the reaction product of components (II) and (III).
Claim 9
Dependent Claim
21 words
Process according to claim 1 characterized in that component (I) is produced substantially of dehydrated castor oil or its fatty acids.
Claim 10
Dependent Claim
21 words
Process according to claim 1 characterized in that component (I) is freed from unreacted alpha-beta ethylenically unsaturated dicarboxylic acid or anhydride.
Claim 11
Dependent Claim
19 words
Process according to claim 1 characterized in that components (I), (II), and (III) are free from electrolytes, particularly chlorides.
Claim 12
Dependent Claim
124 words
A water-soluble resinous coating composition comprising a water-soluble nitrogen base soap of the reaction product obtained by heating at elevated temperatures I. an adduct of maleic anhydride with an olefinic unsaturated compound of the group consisting of vegetable and animal fatty acids, tall oil fatty acid, rosin acids, their hydroxy-free esters with polyols and mixtures thereof; Ii. a polyhydroxy compound of the group consisting of trimethylol propane, pentaerythritol, propylene glycol, and butylene glycol, and partial esters thereof with fatty acids; and Iii. a water-insoluble, heat-hardenable phenol-formaldehyde condensation product, in the resol state, of a phenol substituted in the ortho or para position by a radical with at least 3 carbon atoms and being a member of the groups of alkyl phenols and aryl phenols.
Claim 13
Dependent Claim
124 words
A water-soluble resinous coating composition comprising a water-soluble nitrogen base soap of the reaction product obtained by heating at elevated temperatures I. an adduct of maleic anhydride with an olefinic unsaturated compound of the group consisting of vegetable and animal fatty acids, tall oil fatty acid, rosin acids, their hydroxy-free esters with polyols and mixtures thereof; Ii. a polyhydroxy compound of the group consisting of trimethylol propane, pentaerythritol, propylene glycol, and butylene glycol, and partial esters thereof with fatty acids; and Iii. a water-insoluble, heat-hardenable phenol-formaldehyde condensation product, in the resol state, of a phenol substituted in the ortho or para position by a radical with at least 3 carbon atoms and being a member of the groups of alkyl phenols and aryl phenols.
Claim 14
Dependent Claim
10 words
Composition of claim 11 wherein the phenol-aldehyde-condensation product is alkali-soluble.
Claim 15
Dependent Claim
21 words
Composition of claim 11 wherein the polyhydroxy compound (II) is a partial ester of unsaturated oil fatty acids and polyhydric alcohols.
Claim 16
Dependent Claim
18 words
Composition of claim 11 wherein component (I) is produced substantially of dehydrated castor oil or its fatty acids.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-04-13 | 1979-10-13 | 1980-04-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-04-13 | 1983-10-13 | 1984-04-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-04-13 | 1987-10-13 | 1988-04-13 | $7700.00 | Window Closed / Lapsed |