US3948761A
Expired / Lapsed
US
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Isomerization of aliphatic hydrocarbons
Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1974-02-25
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Granted: 1976-04-06
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Expires: 1994-02-25
Abstract
Abstract Acyclic and alicyclic aliphatic hydrocarbons are isomerized by contacting the same with hydrogen in the presence of a difficultly reduceable metal halide in combination with at least a molar equivalent of hydrogen halide. The preferred catalyst system is tantalum pentafluoride, niobium pentafluoride or their mixtures in combination with at least a five-fold molar excess of hydrogen fluoride.
Inventors
- 👤 Michael Siskin
- 👤 Joseph J. Porcelli
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 04:31
CPC Classifications
C; C07; C07C; C07C5/00; C07C5/22; C07C5/27; C07C5/2702; C07C5/271; C07C5/2718; C07C5/2721; B; B01; B01J; B01J27/00; B01J27/06; B01J27/08; C07C2527/00; C07C2527/06; C07C2527/08; C07C2527/10; C07C2527/11; C07C2527/12; C07C2527/1206; C07C2527/125; C07C2527/126; C07C2527/132; C07C2527/133; C07C2527/135
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
188 words
An isomerization process comprising: contacting in a reaction zone and at substantially liquid phase catalyst isomerization conditions including a temperature varying between about 0° and 150°C; a feed stock comprising a component selected from the group consisting of a saturated acyclic hydrocarbon having at least four carbon atoms, a saturated alicyclic hydrocarbon having at least five carbon atoms and mixtures thereof, said feed stock additionally containing a component selected from the group consisting of at least about 1 wppm, based on said feed stock, of sulfur compounds, at least about 0.001 wt. %, based on said feed stock, of an unsaturated hydrocarbon compound or mixtures thereof; hydrogen at a partial pressure of at least about 5 psig and a catalyst system comprising a metal halide selected from the group consisting of gallium bromides and chlorides and the chlorides, bromides and fluorides of niobium, tantalum, molybdenum or tungsten in combination with at least an equal molar amount, based on the metal halide, of a hydrogen halide selected from hydrogen fluoride, hydrogen chloride, and hydrogen bromide, at least a portion of said metal halide being dissolved in said hydrogen halide.
Claim 2
Dependent Claim
188 words
An isomerization process comprising: contacting in a reaction zone and at substantially liquid phase catalyst isomerization conditions including a temperature varying between about 0° and 150°C; a feed stock comprising a component selected from the group consisting of a saturated acyclic hydrocarbon having at least four carbon atoms, a saturated alicyclic hydrocarbon having at least five carbon atoms and mixtures thereof, said feed stock additionally containing a component selected from the group consisting of at least about 1 wppm, based on said feed stock, of sulfur compounds, at least about 0.001 wt. %, based on said feed stock, of an unsaturated hydrocarbon compound or mixtures thereof; hydrogen at a partial pressure of at least about 5 psig and a catalyst system comprising a metal halide selected from the group consisting of gallium bromides and chlorides and the chlorides, bromides and fluorides of niobium, tantalum, molybdenum or tungsten in combination with at least an equal molar amount, based on the metal halide, of a hydrogen halide selected from hydrogen fluoride, hydrogen chloride, and hydrogen bromide, at least a portion of said metal halide being dissolved in said hydrogen halide.
Claim 3
Dependent Claim
24 words
The process of claim 1 wherein the molar ratio of hydrogen halide to metal halide present in said reaction zone is at least 2:1.
Claim 4
Dependent Claim
19 words
The process of claim 1 wherein said isomerization is conducted at a temperature varying from about 25° to 60°C.
Claim 5
Dependent Claim
20 words
The process of claim 1 wherein the metal halide is a metal fluoride and the hydrogen halide is hydrogen fluoride.
Claim 6
Dependent Claim
17 words
The process of claim 4 wherein the metal fluoride is tantalum pentafluoride, niobium pentafluoride or mixtures thereof.
Claim 7
Dependent Claim
24 words
The process of claim 5 wherein the molar ratio of hydrogen fluoride to metal fluoride present in the reaction zone is at least 2:1.
Claim 8
Dependent Claim
170 words
An isomerization process comprising: contacting, in a reaction zone, and at substantially liquid phase catalyst isomerization conditions including an isomerization temperature varying between about 25°C. and 60°C.; a feed stock comprising a component selected from the group consisting of a saturated acyclic hydrocarbon having from 4 to 10 carbon atoms, a saturated alicyclic hydrocarbon having from 5 to 15 carbon atoms or mixtures thereof, said feed stock additionally containing a component selected from the group consisting of at least about 1 wppm, based on said feed stock, of sulfur compounds, at least about 0.001 wt. %, based on said feed stock, of an unsaturated hydrocarbon feed stock, and mixtures thereof; hydrogen at partial pressures varying from about 25 to 2,000 psig, and a catalyst system comprising tantalum pentafluoride, niobium pentafluoride or mixtures thereof in combination with hydrogen fluoride, the molar ratio of hydrogen fluoride to metal fluoride present in the reaction zone being at least 2:1, at least a portion of said metal fluoride being dissolved in said hydrogen fluoride.
Claim 9
Dependent Claim
170 words
An isomerization process comprising: contacting, in a reaction zone, and at substantially liquid phase catalyst isomerization conditions including an isomerization temperature varying between about 25°C. and 60°C.; a feed stock comprising a component selected from the group consisting of a saturated acyclic hydrocarbon having from 4 to 10 carbon atoms, a saturated alicyclic hydrocarbon having from 5 to 15 carbon atoms or mixtures thereof, said feed stock additionally containing a component selected from the group consisting of at least about 1 wppm, based on said feed stock, of sulfur compounds, at least about 0.001 wt. %, based on said feed stock, of an unsaturated hydrocarbon feed stock, and mixtures thereof; hydrogen at partial pressures varying from about 25 to 2,000 psig, and a catalyst system comprising tantalum pentafluoride, niobium pentafluoride or mixtures thereof in combination with hydrogen fluoride, the molar ratio of hydrogen fluoride to metal fluoride present in the reaction zone being at least 2:1, at least a portion of said metal fluoride being dissolved in said hydrogen fluoride.
Claim 10
Dependent Claim
18 words
The process of claim 7 wherein the feed stock contains from about 1 to 10,000 wppm sulfur compounds.
Claim 11
Dependent Claim
19 words
The process of claim 7 wherein the feed stock contains from about 0.001 to 10 wt. % unsaturated constituents.
Claim 12
Dependent Claim
23 words
The process of claim 9 wherein the unsaturated constituent is an aromatic present in an amount of about 0.01 to 10 wt. %.
Claim 13
Dependent Claim
25 words
The process of claim 7 wherein the molar ratio of hydrogen fluoride to metal fluoride present in the reaction zone is at least about 5:1.
Claim 14
Dependent Claim
180 words
An isomerization process comprising contacting, in a reaction zone, and at substantially liquid phase catalyst isomerization conditions including a temperature varying between about 0°C. and 150°C.: a feed stock comprising a component selected from the group consisting of a saturated acyclic hydrocarbon having at least 4 carbon atoms, a saturated alicyclic hydrocarbon having at least 5 carbon atoms and mixtures thereof, said feed stock having not been subjected to any prior treatments for the substantial removal of olefinic compounds including benzene and said feed stock additionally containing at least about 0.001 wt. % olefinic constituents; hydrogen at partial pressures varying from about 5 to 2,000 psig, and a catalyst system comprising a metal halide selected from the group consisting of gallium bromides and chlorides and the chlorides, bromides and fluorides of tantalum, niobium, molybdenum or tungsten in combination with at least an equal molar amount, based on metal halide, of a hydrogen halide selected from the group consisting of hydrogen fluoride, hydrogen chloride and hydrogen bromide, at least a portion of said metal halide being dissolved in said hydrogen halide.
Claim 15
Dependent Claim
180 words
An isomerization process comprising contacting, in a reaction zone, and at substantially liquid phase catalyst isomerization conditions including a temperature varying between about 0°C. and 150°C.: a feed stock comprising a component selected from the group consisting of a saturated acyclic hydrocarbon having at least 4 carbon atoms, a saturated alicyclic hydrocarbon having at least 5 carbon atoms and mixtures thereof, said feed stock having not been subjected to any prior treatments for the substantial removal of olefinic compounds including benzene and said feed stock additionally containing at least about 0.001 wt. % olefinic constituents; hydrogen at partial pressures varying from about 5 to 2,000 psig, and a catalyst system comprising a metal halide selected from the group consisting of gallium bromides and chlorides and the chlorides, bromides and fluorides of tantalum, niobium, molybdenum or tungsten in combination with at least an equal molar amount, based on metal halide, of a hydrogen halide selected from the group consisting of hydrogen fluoride, hydrogen chloride and hydrogen bromide, at least a portion of said metal halide being dissolved in said hydrogen halide.
Claim 16
Dependent Claim
20 words
The process of claim 12 wherein said isomerization is conducted at a temperature varying from about 25°C to about 60°C.
Claim 17
Dependent Claim
35 words
The process of claim 12 wherein said metal halide is a metal fluoride and said hydrogen halide is hydrogen fluoride and the molar ratio of hydrogen fluoride to metal fluoride is at least about 2:1.
Claim 18
Dependent Claim
24 words
The process of claim 12 wherein said metal halide is tantalum pentafluoride, niobium pentafluoride or mixtures thereof and said hydrogen halide is hydrogen fluoride.
Claim 19
Dependent Claim
16 words
The process of claim 12 wherein said feedstock contains from 0.01 to 10 wt. % benzene.
Claim 20
Dependent Claim
20 words
The process of claim 13 wherein said feed stock contains from 0.01 to 2 wt. % of an olefinic compound.
Claim 21
Dependent Claim
19 words
The process of claim 12 wherein said metal halide is aluminum chloride and said hydrogen halide is hydrogen chloride.
Claim 22
Dependent Claim
16 words
The process of claim 12 wherein the hydrogen pressure varies from about 25 to 400 psig.
Claim 23
Dependent Claim
10 words
The process of claim 10 wherein the aromatic is benzene.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-04-06 | 1979-10-06 | 1980-04-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-04-06 | 1983-10-06 | 1984-04-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-04-06 | 1987-10-06 | 1988-04-06 | $7700.00 | Window Closed / Lapsed |