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US3947615A Expired / Lapsed US ⏱️ 0.0 years remaining

Preparation of moulding compositions

Assignee: FREEMAN CHEMICALS Ltd 5 CIVIC WAY ELLESMERE PORT SOUTH WIRRAL L65 4AH
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Filing: 1974-05-22
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Granted: 1976-03-30
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Expires: 1994-05-22
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Abstract

Abstract Sheet moulding compound (S.M.C.) is made by impregnating glass fibre with hot polyester resin matrix containing a soluble gelling agent, e.g. sodium or potassium stearate which causes the matrix to gel on cooling.

Inventors

  • 👤 David Philip Fry

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 22:36
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/09; C08K5/098; C08J; C08J5/00; C08J5/24; C08J5/241; C08J5/244; C08J5/249; C08J2351/00; C08J2351/08; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2938; Y10T428/2964; Y10T442/00; Y10T442/20; Y10T442/2861

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 159 words
A process for the preparation of an unsaturated polyester resin based sheet or rovings moulding compound, consisting essentially of the steps of heating a liquid unsaturated polyester resin system consisting essentially of an unsaturated polyester, a copolymerisable monomer, a polymerisation initiator and a gelling agent for said unsaturated polyester resin system to an elevated temperature at which the unsaturated resin system does not form a gel but below that at which cross linking of the system occurs, said gelling agent being soluble in said mixture of unsaturated polyester and copolymerisable monomer at said elevated temperature and being capable of initiating formation of a high viscosity gel when said solution is cooled from said elevated temperature to below 30°C., impregnating a fibrous reinforcement with said liquid unsaturated polyester resin system while said resin system is at said elevated temperature, and subsequently cooling the resultant moulding compound to a temperature at which the liquid unsaturated polyester resin system forms a gel.
Claim 2
Dependent Claim 159 words
A process for the preparation of an unsaturated polyester resin based sheet or rovings moulding compound, consisting essentially of the steps of heating a liquid unsaturated polyester resin system consisting essentially of an unsaturated polyester, a copolymerisable monomer, a polymerisation initiator and a gelling agent for said unsaturated polyester resin system to an elevated temperature at which the unsaturated resin system does not form a gel but below that at which cross linking of the system occurs, said gelling agent being soluble in said mixture of unsaturated polyester and copolymerisable monomer at said elevated temperature and being capable of initiating formation of a high viscosity gel when said solution is cooled from said elevated temperature to below 30°C., impregnating a fibrous reinforcement with said liquid unsaturated polyester resin system while said resin system is at said elevated temperature, and subsequently cooling the resultant moulding compound to a temperature at which the liquid unsaturated polyester resin system forms a gel.
Claim 3
Dependent Claim 16 words
A process as claimed in claim 1, wherein the gelling agent is sodium or potassium stearate.
Claim 4
Dependent Claim 25 words
A process as claimed in claim 1, wherein the liquid unsaturated polyester resin system is heated to a temperature in the range 50° to 70°C.
Claim 5
Dependent Claim 22 words
A process as claimed in claim 1, wherein the liquid unsaturated polyester resin system contains a small amount of a polar material.
Claim 6
Dependent Claim 17 words
A process as claimed in claim 1, wherein the polymerisation initiator has a decomposition temperature above 75°C.
Claim 7
Dependent Claim 20 words
A process as claimed in claim 1, wherein the fibrous reinforcement is glass fibre in the form of a mat.
Claim 8
Dependent Claim 23 words
A process as claimed in claim 1 wherein the fibrous reinforcement is glass fibre in the form of loose chopped strands or rovings.
Claim 9
Dependent Claim 23 words
A process as claimed in claim 1, wherein the liquid unsaturated polyester resin system contains a saturated liquid polyester as shrink control agent.
Claim 10
Dependent Claim 35 words
A process according to claim 1, wherein said gelling agent is selected from the group consisting of the sodium salts of palmitic, stearic, behenic and hydroxy stearic acids and the potassium salt of stearic acid.
Claim 11
Dependent Claim 169 words
A process for the preparation of an unsaturated polyester resin based sheet or rovings moulding compound, consisting essentially of the steps of heating a liquid unsaturated polyester resin system consisting essentially of an unsaturated polyester, a copolymerisable monomer, a polymerisation initiator and a gelling agent for said unsaturated polyester resin system to an elevated temperature at which the unsaturated resin system does not form a gel in the range of from 50° to 70°C. but below that at which cross linking of the system occurs, said gelling agent being soluble in said mixture of unsaturated polyester and copolymerisable monomer at said elevated temperature and being capable of initiating formation of a high viscosity gel when said solution is cooled from said elevated temperature to below 30°C., impregnating a fibrous reinforcement with said liquid unsaturated polyester resin system while said resin system is at said elevated temperature, and subsequently cooling the resultant moulding compound to a temperature below 40°C. at which the liquid unsaturated polyester resin system forms a gel.
Claim 12
Dependent Claim 169 words
A process for the preparation of an unsaturated polyester resin based sheet or rovings moulding compound, consisting essentially of the steps of heating a liquid unsaturated polyester resin system consisting essentially of an unsaturated polyester, a copolymerisable monomer, a polymerisation initiator and a gelling agent for said unsaturated polyester resin system to an elevated temperature at which the unsaturated resin system does not form a gel in the range of from 50° to 70°C. but below that at which cross linking of the system occurs, said gelling agent being soluble in said mixture of unsaturated polyester and copolymerisable monomer at said elevated temperature and being capable of initiating formation of a high viscosity gel when said solution is cooled from said elevated temperature to below 30°C., impregnating a fibrous reinforcement with said liquid unsaturated polyester resin system while said resin system is at said elevated temperature, and subsequently cooling the resultant moulding compound to a temperature below 40°C. at which the liquid unsaturated polyester resin system forms a gel.
Claim 13
Dependent Claim 35 words
A process according to claim 10, wherein said gelling agent is selected from the group consisting of the sodium salts of palmitic, stearic, behenic and hydroxy stearic acids and the potassium salt of stearic acid.

References Cited (Backward Citations)

US3288735A Cited
US3219604A Cited
US3396128A Cited
US3557042A Cited
US3539479A Cited
US3536642A Cited
US3795717A Cited
US3846164A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-03-30 1979-09-29 1980-03-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-03-30 1983-09-29 1984-03-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-03-30 1987-09-29 1988-03-30 $7700.00 Window Closed / Lapsed

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