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US3946079A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of condensing ketones

Assignee: Tokuyama Corp
•
Filing: 1971-01-07
•
Granted: 1976-03-23
•
Expires: 1991-01-07
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Abstract

Abstract A process of producing ketone condensation products which comprises condensing at a temperature of from 60° to 300°C. a ketone having 3-19 carbon atoms in the presence of, as a catalyst, at least one metal phosphate selected from titanium phosphate, zirconium phosphate, hafnium phosphate, and tin phosphate; dimeric condensation or trimeric condensation can be achieved depending upon the reaction conditions.

Inventors

  • 👤 Yukio Mizutani
  • 👤 Yusuke Izumi
  • 👤 Yoshiaki Watanabe

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 11:05
CPC Classifications
B; B01; B01J; B01J27/00; B01J27/14; B01J27/16; B01J27/18; B01J27/1802; B01J27/1813; C; C07; C07C; C07C45/00; C07C45/61; C07C45/67; C07C45/68; C07C45/72; C07C45/74; C07C49/00; C07C49/20; C07C49/203

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 99 words
A process of producing unsaturated ketone condensation products which comprises condensing at a temperature of from 60° to 300°C., a ketone of 3-19 carbon atoms having the following formula ##EQU5## wherein R 1 is either alkyl, cycloalkyl, aryl, aralkyl, alkaryl or alkenyl, and R 2 and R 3 , which may be the same or different are each hydrogen, alkyl, cycloalkyl, aryl, aralkyl, alkaryl or alkenyl, said process being carried out in the presence of a catalyst consisting of at least one metal phosphate selected from the group consisting of titanium phosphate, zirconium phosphate, hafnium phosphate, and tin phosphate.
Claim 2
Dependent Claim 99 words
A process of producing unsaturated ketone condensation products which comprises condensing at a temperature of from 60° to 300°C., a ketone of 3-19 carbon atoms having the following formula ##EQU5## wherein R 1 is either alkyl, cycloalkyl, aryl, aralkyl, alkaryl or alkenyl, and R 2 and R 3 , which may be the same or different are each hydrogen, alkyl, cycloalkyl, aryl, aralkyl, alkaryl or alkenyl, said process being carried out in the presence of a catalyst consisting of at least one metal phosphate selected from the group consisting of titanium phosphate, zirconium phosphate, hafnium phosphate, and tin phosphate.
Claim 3
Dependent Claim 25 words
The method of claim 1 wherein dimeric condensation products are selectively formed by carrying out the condensation reaction at a temperature of 60° to 160°C.
Claim 4
Dependent Claim 22 words
The method of claim 1 wherein dimeric condensation products are selectively produced by carrying out the condensation reaction in the liquid phase.
Claim 5
Dependent Claim 24 words
The method of claim 1 wherein said ketone is selected from the group consisting of acetone, diethylketone, methyl ethyl ketone, methylisobutylketone, and mixtures thereof.

References Cited (Backward Citations)

US2288306A Cited
US2309650A Cited
US3098100A Cited
US3153068A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-03-23 1979-09-22 1980-03-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-03-23 1983-09-22 1984-03-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-03-23 1987-09-22 1988-03-23 $7700.00 Window Closed / Lapsed

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