US3945914A
Expired / Lapsed
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Process for "sulfur reduction of an oxidized hydrocarbon by forming a metal-sulfur-containing compound"
Assignee: Atlantic Richfield Co
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Filing: 1974-08-23
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Granted: 1976-03-23
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Expires: 1994-08-23
Abstract
Abstract A process for reducing the sulfur content of hydrocarbon material by oxidizing the sulfur impurities contained in the hydrocarbon material, contacting the oxidized sulfur-containing hydrocarbon material with at least one of certain metal containing components at conditions to form a metal, sulfur-containing compound and recovering a hydrocarbon material of reduced sulfur content.
Inventors
- 👤 Jin Sun Yoo
- 👤 Andrew P. Voss
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 11:37
CPC Classifications
C; C10; C10G; C10G53/00; C10G53/02; C10G53/14
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
122 words
A process for producing a hydrocarbon material of reduced sulfur content which comprises: 1. contacting a sulfur-containing hydrocarbon material with an oxidant to preferentially oxidize at least a portion of the sulfur and form an oxidized sulfur-containing hydrocarbon material, a major amount of said sulfur-containing hydrocarbon material boils above about 550°F.; 2. contacting said oxidized sulfur-containing hydrocarbon material with at least one metal or metal-containing compound at a temperature within the range from about 500°F. to about 1350°F., to form a metal-sulfur-containing compound, said metal or metal-containing compound comprising a metal selected from the group consisting of nickel, molybdenum, cobalt, tungsten, zinc, vanadium, copper, manganese, mercury and mixtures thereof; and 3. recovering a hydrocarbon material from step (2) of reduced sulfur content.
Claim 2
Dependent Claim
122 words
A process for producing a hydrocarbon material of reduced sulfur content which comprises: 1. contacting a sulfur-containing hydrocarbon material with an oxidant to preferentially oxidize at least a portion of the sulfur and form an oxidized sulfur-containing hydrocarbon material, a major amount of said sulfur-containing hydrocarbon material boils above about 550°F.; 2. contacting said oxidized sulfur-containing hydrocarbon material with at least one metal or metal-containing compound at a temperature within the range from about 500°F. to about 1350°F., to form a metal-sulfur-containing compound, said metal or metal-containing compound comprising a metal selected from the group consisting of nickel, molybdenum, cobalt, tungsten, zinc, vanadium, copper, manganese, mercury and mixtures thereof; and 3. recovering a hydrocarbon material from step (2) of reduced sulfur content.
Claim 3
Dependent Claim
48 words
The method of claim 1 wherein said metal or metal-containing compound is present in an amount to provide at least about 0.1 equivalent of said metal capable of chemically combining with sulfur at the conditions of step (2) per equivalent of sulfur in said oxidized sulfur-containing hydrocarbon material.
Claim 4
Dependent Claim
112 words
The process of claim 2 wherein said oxidant is selected from the group consisting of organic peroxides, organic hydroperoxides, organic peracids and mixtures thereof containing from 1 to about 30 carbon atoms per active oxygen atom and is present during said contacting in an amount to provide from about 0.5 to about 10 atoms of active oxygen per atom of sulfur in said sulfur-containing material and said step (1) contacting occurs in the presence of an oxidation catalyst comprising a metal in an amount effective to promote the oxidation of sulfur, said metal being selected from the group consisting of Group IVB metals, Group VB metals, Group VIB metals and mixtures thereof.
Claim 5
Dependent Claim
24 words
The method of claim 3 wherein said contacting of step (2) occurs at a temperature within the range from about 650°F. to about 1000°F.
Claim 6
Dependent Claim
25 words
The process of claim 4 wherein said contacting of step (2) occurs over a period of time from about 5 minutes to about 20 hours.
Claim 7
Dependent Claim
47 words
The process of claim 5 wherein said oxidation catalyst comprises a metal selected from the group consisting of titanium, zirconium, vanadium, tantalum, chromium, molybdenum, tungsten and mixtures thereof and is present in an amount of at least about 5 ppm. by weight of said sulfur-containing hydrocarbon material.
Claim 8
Dependent Claim
65 words
The process of claim 6 wherein said metal or metal-containing compound comprises a metal selected from the group consisting of molybdenum, cobalt, tungsten, vanadium and mixtures thereof, and is present in an amount from about 0.5 to about 15 equivalent of said metal capable of chemically combining with sulfur at the conditions of step (2) per equivalent of sulfur in said oxidized sulfur-containing hydrocarbon material.
Claim 9
Dependent Claim
11 words
The process of claim 7 wherein said oxidation catalyst comprises molybdenum.
Claim 10
Dependent Claim
13 words
The process of claim 7 wherein said metal or metal-containing compound comprises molybdenum.
Claim 11
Dependent Claim
68 words
The process of claim 8 wherein said oxidation catalyst is prepared by a method which comprises interacting molybdenum metal with a compound selected from the group consisting of organic hydroperoxide, organic peroxide, hydrogen peroxide and mixtures thereof in the presence of at least one saturated alcohol having from one to four carbon atoms per molecule at conditions such that at least a portion of said molybdenum is solubilized.
Claim 12
Dependent Claim
70 words
The process of claim 10 wherein said metal or metal-containing compound is prepared by a method which comprises interacting molybdenum metal with a compound selected from the group consisting of organic hydroperoxide, organic peroxide, hydrogen peroxide and mixtures thereof in the presence of at leaast one saturated alcohol having from one to four carbon atoms per molecule at conditions such that at least a portion of said molybdenum is solubilized.
Claim 13
Dependent Claim
68 words
The process of claim 9 wherein said oxidation catalyst is prepared by a method which comprises interacting molybdenum metal with a compound selected from the group consisting of organic hydroperoxide, organic peroxide, hydrogen peroxide and mixtures thereof in the presence of at least one saturated alcohol having from one to four carbon atoms per molecule at conditions such that at least a portion of said molybdenum is solubilized.
Claim 14
Dependent Claim
70 words
The process of claim 12 wherein said metal or metal-containing compound is prepared by a method which comprises interacting molybdenum metal with a compound selected from the group consisting of organic hydroperoxide, organic peroxide, hydrogen peroxide and mixtures thereof in the presence of at least one saturated alcohol having from one to four carbon atoms per molecule at conditions such that at least a portion of said molybdenum is solubilized.
Claim 15
Dependent Claim
38 words
The process of claim 13 wherein said contacting of step (2) occurs at a temperature within the range from about 700°F. to about 850°F. and for a period of time from about 30 minutes to about 2 hours.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-03-23 | 1979-09-22 | 1980-03-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-03-23 | 1983-09-22 | 1984-03-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-03-23 | 1987-09-22 | 1988-03-23 | $7700.00 | Window Closed / Lapsed |