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US3944329A Expired / Lapsed US ⏱️ 0.0 years remaining

Faraday rotator device including lithia-silicate glass articles containing Tb2 O3 and methods of using same

Assignee: OI Glass Inc
•
Filing: 1974-09-16
•
Granted: 1976-03-16
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Expires: 1994-09-16
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Abstract

Abstract There is disclosed a Faraday rotator device suitable for radiation phase shifters, isolators and shutters, that operate in the visible and infrared regions of the electromagnetic spectrum. The device includes (1) means for supplying polarized, electromagnetic radiation, (2) a lithia-silica-terbia glass article capable of effecting Faraday rotation when subjected to a magnetic field, and (3) means for inducing a magnetic field within the glass article, the glass generally comprising about 61-80 mole percent SiO2, 15-27.5 mole percent Li2O, 3-9 mole percent Tb2O3, and optionally, up to about 3 mole percent of R2O3, such as Al2O3 or B2O3-and optionally, minor amounts of Na2O, K2O or CaO, providing the sum of Li2O + Na2O + K2O + CaO is not substantially greater than about 32.5 mole percent.

Inventors

  • 👤 Haynes A. Lee, Jr.
  • 👤 Charles F. Rapp

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 13:01
CPC Classifications
G; G02; G02F; G02F1/00; G02F1/0009; G02F1/0036; C; C03; C03C; C03C3/00; C03C3/04; C03C3/076; C03C3/095; C03C4/00; Y; Y10; Y10S; Y10S501/00; Y10S501/90

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 155 words
A Faraday rotator device comprising 1. means for supplying polarized electromagnetic radiation, 2. a glass article capable of effecting Faraday rotation when subjected to a magnetic field, and 3. magnetic means for inducing a magnetic field in the glass article for rotating the polarized electromagnetic radiation within the glass, said glass article having a high Verdet constant, having good light transmission, having good melt properties, having a high damage threshold, having good forming properties including a relatively wide working temperature at approximately log 4 viscosity, being relatively seed-free and being easily homogenized, said glass having a composition approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61-80 Li.sub.2 O 15-27.5 Na.sub.2 O 0-10 K.sub.2 O 0-5 CaO 0-5 Al.sub.2 O.sub.3 0-3 B.sub.2 O.sub.3 0-3 La.sub.2 O.sub.3 0-3 Tb.sub.2 O.sub.3 3-9 ______________________________________ wherein the sum of Li 2 O + Na 2 O + K 2 O + CaO is no greater than about 32.5 mole percent.
Claim 2
Dependent Claim 155 words
A Faraday rotator device comprising 1. means for supplying polarized electromagnetic radiation, 2. a glass article capable of effecting Faraday rotation when subjected to a magnetic field, and 3. magnetic means for inducing a magnetic field in the glass article for rotating the polarized electromagnetic radiation within the glass, said glass article having a high Verdet constant, having good light transmission, having good melt properties, having a high damage threshold, having good forming properties including a relatively wide working temperature at approximately log 4 viscosity, being relatively seed-free and being easily homogenized, said glass having a composition approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61-80 Li.sub.2 O 15-27.5 Na.sub.2 O 0-10 K.sub.2 O 0-5 CaO 0-5 Al.sub.2 O.sub.3 0-3 B.sub.2 O.sub.3 0-3 La.sub.2 O.sub.3 0-3 Tb.sub.2 O.sub.3 3-9 ______________________________________ wherein the sum of Li 2 O + Na 2 O + K 2 O + CaO is no greater than about 32.5 mole percent.
Claim 3
Dependent Claim 45 words
A device as defined in claim 1 in which the composition of the glass is approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61-71 Li.sub.2 O 20-27.5 Na.sub.2 O 0-5 K.sub.2 O 0-3 CaO 0-3 Al.sub.2 O.sub.3 0-3 B.sub.2 O.sub.3 0-3 Tb.sub.2 O.sub.3 7-9. ______________________________________
Claim 4
Dependent Claim 32 words
A device as defined in claim 1 in which the glass composition is approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61 Li.sub.2 O 27.5 Al.sub.2 O.sub.3 2.5 Tb.sub.2 O.sub.3 9. ______________________________________
Claim 5
Independent Claim 128 words
A method for effecting Faraday rotation of polarized electromagnetic radiation in a glass article, the method including the steps of 1. providing polarized electromagnetic radiation, 2. inducing a magnetic field within a glass article for effecting Faraday rotation of the polarized electromagnetic radiation within the glass article, in which the glass article has a glass composition approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61-80 Li.sub.2 O 15-27.5 Na.sub.2 O 0-10 K.sub.2 O 0-5 CaO 0-5 Al.sub.2 O.sub.3 0-3 B.sub.2 O.sub.3 0-3 La.sub.2 O.sub.3 0-3 Tb.sub.2 O.sub.3 3-9 ______________________________________ wherein the sum of Li 2 O + Na 2 O + K 2 O + CaO is no greater than about 32.5 mole percent, and 3. rotating the polarized electromagnetic radiation as it travels through the glass article.
Claim 6
Independent Claim 128 words
A method for effecting Faraday rotation of polarized electromagnetic radiation in a glass article, the method including the steps of 1. providing polarized electromagnetic radiation, 2. inducing a magnetic field within a glass article for effecting Faraday rotation of the polarized electromagnetic radiation within the glass article, in which the glass article has a glass composition approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61-80 Li.sub.2 O 15-27.5 Na.sub.2 O 0-10 K.sub.2 O 0-5 CaO 0-5 Al.sub.2 O.sub.3 0-3 B.sub.2 O.sub.3 0-3 La.sub.2 O.sub.3 0-3 Tb.sub.2 O.sub.3 3-9 ______________________________________ wherein the sum of Li 2 O + Na 2 O + K 2 O + CaO is no greater than about 32.5 mole percent, and 3. rotating the polarized electromagnetic radiation as it travels through the glass article.
Claim 7
Dependent Claim 43 words
A method as defined in claim 4 in which the glass composition is approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61-71 Li.sub.2 O 20-27.5 Na.sub.2 O 0-5 K.sub.2 O 0-3 CaO 0-3 Al.sub.2 O.sub.3 0-3 B.sub.2 O.sub.3 0-3 Tb.sub.2 O.sub.3 7-9. ______________________________________
Claim 8
Dependent Claim 34 words
A method as defined in claim 4 in which the glass article has a composition approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61 Li.sub.2 O 27.5 Al.sub.2 O.sub.3 2.5 Tb.sub.2 O.sub.3 9. ______________________________________
Claim 9
Dependent Claim 105 words
The new use for a glass article in which the glass has a composition approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61-80 Li.sub.2 O 15-27.5 Na.sub.2 O 0-10 K.sub.2 O 0-5 CaO 0-5 Al.sub.2 O.sub.3 0-3 B.sub.2 O.sub.3 0-3 La.sub.2 O.sub.3 0-3 Tb.sub.2 O.sub.3 3-9 ______________________________________ wherein the sum of Li 2 O + Na 2 O + K 2 O + CaO is no greater than about 32.5 mole percent, the new use comprising the steps of 1. placing the glass article in a magnetic field, and 2. directing polarized electromagnetic radiation into the glass article for effecting Faraday rotation of the radiation.
Claim 10
Dependent Claim 105 words
The new use for a glass article in which the glass has a composition approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61-80 Li.sub.2 O 15-27.5 Na.sub.2 O 0-10 K.sub.2 O 0-5 CaO 0-5 Al.sub.2 O.sub.3 0-3 B.sub.2 O.sub.3 0-3 La.sub.2 O.sub.3 0-3 Tb.sub.2 O.sub.3 3-9 ______________________________________ wherein the sum of Li 2 O + Na 2 O + K 2 O + CaO is no greater than about 32.5 mole percent, the new use comprising the steps of 1. placing the glass article in a magnetic field, and 2. directing polarized electromagnetic radiation into the glass article for effecting Faraday rotation of the radiation.
Claim 11
Dependent Claim 16 words
The new use as defined in claim 7 in which the electromagnetic radiation is plane polarized.
Claim 12
Dependent Claim 16 words
The new use as defined in claim 7 in which the electromagnetic radiation is circularly polarized.
Claim 13
Dependent Claim 16 words
The new use as defined in claim 7 in which the electromagnetic radiation is eliptically polarized.
Claim 14
Dependent Claim 172 words
A Faraday rotator device comprising a source of light for providing a monochromatic light beam, light polarizing means for polarizing the monochromatic light beam to provide a monochromatic polarized light beam, a glass article capable of effecting Faraday rotation of the monochromatic polarized light beam when subjected to a magnetic field, and magnetic means for inducing a magnetic field for rotating the polarized monochromatic light beam within the glass article, said glass article having a high Verdet constant, good light transmission, good melt properties, high damage threshold, good forming properties including a relatively wide working temperature at approximately log 4 viscosity, being relatively seed-free and being easily homogenized, the glass having a composition approximately as follows INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61-80 Li.sub.2 O 15- 27.5 Na.sub.2 O 0-10 K.sub.2 O 0-5 CaO 0-5 Al.sub.2 O.sub.3 0-3 B.sub.2 O.sub.3 0-3 La.sub.2 O.sub.3 0-3 Tb.sub.2 O.sub.3 3-9. ______________________________________ wherein the sum of Li 2 O + Na 2 O + K 2 O + CaO is no greater than about 32.5 mole percent.
Claim 15
Dependent Claim 172 words
A Faraday rotator device comprising a source of light for providing a monochromatic light beam, light polarizing means for polarizing the monochromatic light beam to provide a monochromatic polarized light beam, a glass article capable of effecting Faraday rotation of the monochromatic polarized light beam when subjected to a magnetic field, and magnetic means for inducing a magnetic field for rotating the polarized monochromatic light beam within the glass article, said glass article having a high Verdet constant, good light transmission, good melt properties, high damage threshold, good forming properties including a relatively wide working temperature at approximately log 4 viscosity, being relatively seed-free and being easily homogenized, the glass having a composition approximately as follows INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61-80 Li.sub.2 O 15- 27.5 Na.sub.2 O 0-10 K.sub.2 O 0-5 CaO 0-5 Al.sub.2 O.sub.3 0-3 B.sub.2 O.sub.3 0-3 La.sub.2 O.sub.3 0-3 Tb.sub.2 O.sub.3 3-9. ______________________________________ wherein the sum of Li 2 O + Na 2 O + K 2 O + CaO is no greater than about 32.5 mole percent.
Claim 16
Dependent Claim 28 words
A device as defined in claim 11 in which there is provided analyzing means for analyzing the rotated polarized monochromatic light beam that travels through the glass article.
Claim 17
Dependent Claim 30 words
A device as defined in claim 12 in which the glass composition has the following approximate formulation: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 63.5 Li.sub.2 O 27.5 Tb.sub.2 O.sub.3 9. ______________________________________
Claim 18
Dependent Claim 33 words
A device as defined in claim 1 in which the glass has the approximate composition as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61 Li.sub.2 O 27.5 Al.sub.2 O.sub.3 2.5 Tb.sub.2 O.sub.3 9. ______________________________________
Claim 19
Dependent Claim 30 words
A device as defined in claim 1 in which the glass has a composition approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61-80 Li.sub.2 O 15-27.5 Tb.sub.2 O.sub.3 3-9. ______________________________________
Claim 20
Dependent Claim 33 words
A device as defined in claim 1 in which the glass has a composition approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61- 71 Li.sub.2 O 20- 27.5 Tb.sub.2 O.sub.3 7- 9. ______________________________________
Claim 21
Dependent Claim 30 words
A device as defined in claim 1 in which the glass has a composition approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 63.5 Li.sub.2 O 27.5 Tb.sub.2 O.sub.3 9. ______________________________________
Claim 22
Dependent Claim 30 words
A method as defined in claim 4 in which the glass has a composition approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61-80 Li.sub.2 O 15-27.5 Tb.sub.2 O.sub.3 3-9. ______________________________________
Claim 23
Dependent Claim 30 words
A method as defined in claim 4 in which the glass has a composition approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61-71 Li.sub.2 O 20-27.5 Tb.sub.2 O.sub.3 7-9. ______________________________________
Claim 24
Dependent Claim 30 words
A method as defined in claim 4 in which the glass has a composition approximately as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 63.5 Li.sub.2 O 27.5 Tb.sub.2 O.sub.3 9. ______________________________________
Claim 25
Dependent Claim 34 words
The new use as defined in claim 7 in which the glass has the approximate composition as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 61 Li.sub.2 O 27.5 Al.sub.2 O.sub.3 2.5 Tb.sub.2 O.sub.3 9. ______________________________________
Claim 26
Dependent Claim 31 words
The new use as defined in claim 7 in which the glass has the approximate composition as follows: INGREDIENTS MOLE PERCENT ______________________________________ SiO.sub.2 63.5 Li.sub.2 O 27.5 Tb.sub.2 O.sub.3 9. ______________________________________

References Cited (Backward Citations)

US3166673A Cited
US3318652A Cited
US3471408A Cited
US3471409A Cited
US3578927A Cited
US3663474A Cited
US3640890A Cited
US3640891A Cited
US3654172A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-03-16 1979-09-15 1980-03-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-03-16 1983-09-15 1984-03-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-03-16 1987-09-15 1988-03-16 $7700.00 Window Closed / Lapsed

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