US3941859A
Expired / Lapsed
US
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Thermoplastic polymer blends of EPDM polymer, polyethylene and ethylene-vinyl acetate copolymer
Assignee: Goodrich Corp
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Filing: 1974-08-02
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Granted: 1976-03-02
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Expires: 1994-08-02
Abstract
Abstract EPDM polymers having a high degree of unstretched crystallinity are physically blended with polyethylene and an ethylene-vinyl acetate copolymer to form thermoplastic polymer blends. The blends exhibit superior tensile strength, better than that predicted from the individual effects of the polymeric components alone. No curing or crosslinking agents are used. The thermoplastic blends are useful to prepare liners, tubing, molded products, and the like.
Inventors
- 👤 Martin Batiuk
- 👤 Richard M. Herman
- 👤 James C. Healy
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 13:56
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/06; C08L23/08; C08L23/0846; C08L23/0853; C08L23/16; C08L2205/00; C08L2205/03
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
138 words
A thermoplastic polymer blend comprising (1) an EPDM polymer consisting essentially of interpolymerized units of about 65 percent to about 85 percent by weight of ethylene, about 5 percent to about 35 percent by weight of propylene, and about 0.2 percent to about 10 percent by weight of a diene monomer; said EPDM polymer having a weight percent unstretched crystallinity of from about 10 percent to about 20 percent by weight of the polymer and a melt endotherm value of about 6 to about 10 calories per gram, (2) from about 5 parts to about 400 parts by weight per 100 parts by weight of the EPDM polymer of a polyethylene polymer, and (3) from about 5 parts to about 300 parts by weight per 100 parts by weight of the EPDM polymer, of an ethylene-vinyl acetate copolymer.
Claim 2
Dependent Claim
138 words
A thermoplastic polymer blend comprising (1) an EPDM polymer consisting essentially of interpolymerized units of about 65 percent to about 85 percent by weight of ethylene, about 5 percent to about 35 percent by weight of propylene, and about 0.2 percent to about 10 percent by weight of a diene monomer; said EPDM polymer having a weight percent unstretched crystallinity of from about 10 percent to about 20 percent by weight of the polymer and a melt endotherm value of about 6 to about 10 calories per gram, (2) from about 5 parts to about 400 parts by weight per 100 parts by weight of the EPDM polymer of a polyethylene polymer, and (3) from about 5 parts to about 300 parts by weight per 100 parts by weight of the EPDM polymer, of an ethylene-vinyl acetate copolymer.
Claim 3
Dependent Claim
66 words
A thermoplastic polymer blend of claim 1 wherein the EPDM polymer consists essentially of interpolymerized units of from about 70 percent to about 80 percent by weight of ethylene, about 15 percent to about 29 percent by weight of propylene, and about 1 percent to about 5 percent by weight of a nonconjugated diene monomer containing from 5 to about 25 carbon atoms in the monomer.
Claim 4
Dependent Claim
54 words
A thermoplastic polymer blend of claim 2 wherein the polyethylene polymer is present in from about 10 parts to about 200 parts by weight and the ethylene vinyl acetate copolymer is present in from about 10 parts to about 150 parts by weight, both based on 100 parts by weight of the EPDM polymer.
Claim 5
Dependent Claim
63 words
A thermoplastic polymer blend of claim 3 wherein the ethylene-vinyl acetate copolymer consists essentially of interpolymerized units of from about 70 percent to about 85 percent by weight of ethylene and about 15 percent to about 30 percent by weight of vinyl acetate, and the melt index of the copolymer is from about 1 gram/10 minutes to about 10 grams/10 minutes at 190°C.
Claim 6
Dependent Claim
25 words
A thermoplastic polymer blend of claim 4 wherein the polyethylene polymer is a low density polyethylene polymer having a density of below about 0.94 grams/cc.
Claim 7
Dependent Claim
20 words
A thermoplastic polymer blend of claim 5 wherein the nonconjugated diene monomer in the EPDM polymer is an alkenyl norbornene.
Claim 8
Dependent Claim
33 words
A thermoplastic polymer blend of claim 6 wherein the EPDM polymer consists essentially of interpolymerized units of ethylene, propylene, and 5-ethylidene-2-norbornene monomer and the polyethylene polymer has a density of about 0.92 grams/cc.
Claim 9
Dependent Claim
68 words
A thermoplastic polymer blend of claim 7 comprising (1) 100 parts by weight of an EPDM polymer consisting essentially of interpolymerized units of about 73 percent by weight of ethylene, about 23 percent by weight of propylene, and about 4 percent by weight of 5- ethylidene-2-norbornene, (2) 10 parts by weight of an ethylene-vinyl acetate copolymer, and (3) 10 parts by weight of a low density polyethylene polymer.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-03-02 | 1979-09-01 | 1980-03-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-03-02 | 1983-09-01 | 1984-03-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-03-02 | 1987-09-01 | 1988-03-02 | $7700.00 | Window Closed / Lapsed |