Abstract The present invention provides oil-soluble, polymeric surface-active agents which are polyimide-amine salts of styrene-maleic anhydride copolymers having pendant tertiary amine groups containing a salt-forming tertiary nitrogen atom neutralized to the extent of at least about 75 percent with mono-carboxylic acids for instance having an aliphatic chain of at least about 8 carbon atoms. The salts of this invention exhibit the property of lowering the surface tension at oil-water interfaces. The polyimide-amine salts can also contain mixed imides resulting from the reaction of dialkylaminoalkylamines and monoalkyl amines or mixed imide-amides resulting from the reaction of dialkylaminoalkylamines and dialkylamines. This invention also provides oil compositions containing mineral oil and the oil-soluble, polymeric surface-active polyimide-amine salts, with or without water. These compositions are useful, for instance, as hydraulic fluids, jet fuels, electrolyte-containing oils, anti-wear lubricating oils, diesel fuels, and gasolines.
Polyamide amine salts of a styrene-maleic anhydride copolymer; said styrene-maleic anhydride copolymer consisting essentially of a molar ratio of polymerized styrene to polymerized maleic anhydride of 0.1:1 to 5:1 and having an average molecular weight of 400 to 5,000, and said copolymer being imidized to the extent of at least 65 per cent of its anhydride groups with a dialkylaminoalkylamine containing tertiary amine groups of the formula ##EQU2## wherein R is alkylene of 2 to 30 carbon atoms and R' is alkyl of 1 to 5 carbon atoms, and wherein the tertiary amine groups of said dialkylaminoalkylamine are at least 75 per cent neutralized with a monocarboxylic acid having an aliphatic carbon to carbon chain of 8 to 36 carbon atoms.
Claim 2
Dependent Claim
121 words
Polyamide amine salts of a styrene-maleic anhydride copolymer; said styrene-maleic anhydride copolymer consisting essentially of a molar ratio of polymerized styrene to polymerized maleic anhydride of 0.1:1 to 5:1 and having an average molecular weight of 400 to 5,000, and said copolymer being imidized to the extent of at least 65 per cent of its anhydride groups with a dialkylaminoalkylamine containing tertiary amine groups of the formula ##EQU2## wherein R is alkylene of 2 to 30 carbon atoms and R' is alkyl of 1 to 5 carbon atoms, and wherein the tertiary amine groups of said dialkylaminoalkylamine are at least 75 per cent neutralized with a monocarboxylic acid having an aliphatic carbon to carbon chain of 8 to 36 carbon atoms.
Claim 3
Dependent Claim
23 words
The product of claim 1 wherein the styrene-maleic anhydride copolymer is further imidated up to 35 percent with a long chain alkyl-primary amine.
Claim 4
Dependent Claim
11 words
The product of claim 2 wherein the alkyl-primary amine is octadecylamine.
Claim 5
Dependent Claim
22 words
The product of claim 1 wherein the styrene-maleic anhydride copolymer is amidated to the extent of 35 percent with a dialky-secondary amine.
Claim 6
Dependent Claim
14 words
The product of claim 4 wherein the dialky-secondary amine is hydrogenated tallow secondary diamine.
Claim 7
Dependent Claim
12 words
The product of claim 1 wherein the monocarboxylic acid is stearic acid.
Claim 8
Dependent Claim
12 words
The product of claim 1 wherein the monocarboxylic acid is lauric acid.
Claim 9
Dependent Claim
12 words
The product of claim 1 wherein the monocarboxylic acid is behenic acid.
Claim 10
Dependent Claim
18 words
The salts of claim 1 wherein the dialkylaminoalkylamine is dimethylamine propylamine and the monocarboxylic acid is stearic acid.